(Z)-1,3-Dichlorpropen
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(Z)-1,3-Dichlorpropen Eigenschaften
- Schmelzpunkt:
- -50 °C
- Siedepunkt:
- 104 °C(lit.)
- Dichte
- 1.225 g/mL at 25 °C(lit.)
- Dampfdruck
- 111.6 at 50 °C, 687.8 at 100 °C (Wilding et al., 2002)
- Brechungsindex
- n
20/D 1.4675(lit.)
- Flammpunkt:
- 75 °F
- storage temp.
- 0-6°C
- L?slichkeit
- Chloroform (Soluble), Methanol (Slightly)
- Aggregatzustand
- Oil
- Farbe
- Colourless
- Wasserl?slichkeit
- 1.071g/L(30 ºC)
- Merck
- 14,3075
- Henry's Law Constant
- 1.23 x 10-3 atm?m3/molat 20 °C, 2.77 at 40 °C (static headspace-GC, Kim et al., 2003)
- Expositionsgrenzwerte
- ACGIH TLV: TWA 1 ppm for cis and trans isomers (adopted).
- Stabilit?t:
- Stable. Flammable. Incompatible with strong oxidizing agents, aluminium and its alloys, active metals, halogens, some metal salts. May be light sensitive.
- LogP
- 1.82 at 20℃ and pH5.83-7.78
- Oberfl?chenspannung
- 69.6mN/m at 976.8mg/L and 20.2℃
- CAS Datenbank
- 10061-01-5(CAS DataBase Reference)
- NIST chemische Informationen
- 1-Propene, 1,3-dichloro-, (Z)-(10061-01-5)
- EPA chemische Informationen
- cis-1,3-Dichloropropene (10061-01-5)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher | T,N,F | ||
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R-S?tze: | 10-20/21-25-36/37/38-43-50/53-52/53-39/23/24/25-23/24/25-11-65-24/25-20 | ||
S-S?tze: | 36/37-45-60-61-16-7 | ||
RIDADR | UN 2047 3/PG 2 | ||
WGK Germany | 3 | ||
RTECS-Nr. | UC8325000 | ||
HazardClass | 3.2 | ||
PackingGroup | III | ||
Giftige Stoffe Daten | 10061-01-5(Hazardous Substances Data) | ||
Toxizit?t | LC50 (96-hour) for bluegill sunfish 7.1 mg/L and rainbow trout 7.1 mg/L (Worthing and Hance, 1991); acute oral LD50 of the isomeric mixture for male and female rats is 713 and 470 mg/kg, respectively (Verschueren, 1983). |
Bildanzeige (GHS) |
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Sicherheit |
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(Z)-1,3-Dichlorpropen Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R10:Entzündlich.R20/21:Gesundheitssch?dlich beim Einatmen und bei Berührung mit der Haut.
R25:Giftig beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R43:Sensibilisierung durch Hautkontakt m?glich.
R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
R52/53:Sch?dlich für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R11:Leichtentzündlich.
S-S?tze Betriebsanweisung:
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
S16:Von Zündquellen fernhalten - Nicht rauchen.
S7:Beh?lter dicht geschlossen halten.
Chemische Eigenschaften
colourless to amber liquidPhysikalische Eigenschaften
Clear, colorless to amber-colored liquid with a pungent and irritating, chloroform-like odor. Evaporates quickly when spilled. The average least detectable odor threshold concentration in water at 60 °C for mixed isomers of 1,3-dichloropropylene was 0.12 mg/L (Alexander et al., 1982).Verwenden
The isomeric mixture is used as a soil fumigant and a nematocide.Definition
ChEBI: The (Z)-isomer of 1,3-dichloropropene.Allgemeine Beschreibung
Colorless to amber liquid with a sweetish odor.Air & Water Reaktionen
Highly flammable. Insoluble in water.Reaktivit?t anzeigen
CIS-1,3-DICHLOROPROPENE may be sensitive to light. Reacts with aluminum, aluminum alloys, other active metals and some metal salts and halogens. Can react vigorously with oxidizing materials.Brandgefahr
Flash point data for CIS-1,3-DICHLOROPROPENE are not available, however literature sources indicate that CIS-1,3-DICHLOROPROPENE is flammable.Sicherheitsprofil
Confirmed carcinogen with experimental neoplastigenic data. Human mutation data reported. A dangerous fire hazard when exposed to heat, flame, or oxidzers. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS , ALIPHATIC .m?gliche Exposition
Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.Environmental Fate
Biological. cis-1,3-Dichloropropylene was reported to hydrolyze to 3-chloro-2-propen- 1-ol and can be biologically oxidized to 3-chloropropenoic acid, which is further oxidized to formylacetic acid. Decarboxylation of this compound yields carbon dioxide (Connors et al., 1990). The isomeric mixture showed significant degradation with gradual adaptation in a static-culture flask-screening test (settled domestic wastewater inoculum) conducted at 25°C. At concentrations of 5 and 10 mg/L, percent losses after 4 weeks of incubation were 85 and 84, respectively. Ten days into the incubation study, 7–19% was lost due to volatilization (Tabak et al., 1981).Soil. Hydrolyzes in wet soil forming cis-3-chloroallyl alcohol (Castro and Belser, 1966).
Chemical/Physical. Hydrolyzes in distilled water at 25°C forming 2-chloro-3-propenol and hydrochloric acid. The half-life was 1 day (Milano et al., 1988; Kollig, 1993). Chloroacetaldehyde, formyl chloride and chloroacetic acid were formed from the ozonation of dichloropropylene at about 23°C and 730 mmHg. Chloroacetaldehyde and formyl chloride also formed from the reaction of dichloropropylene with hydroxyl radicals (Tuazon et al., 1984).
The evaporation half-life of cis-1,3-dichloropropylene (1 mg/L) from water at 25°C using a shallow-pitch propeller stirrer at 200 rpm at an average depth of 6.5 cm is 29.6 minutes (Dilling, 1977).
Emits chlorinated acids when incinerated. Incomplete combustion may release toxic phosgene (Sittig, 1985).
Versand/Shipping
UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.Inkompatibilit?ten
Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.Waste disposal
Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.(Z)-1,3-Dichlorpropen Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(Z)-1,3-Dichlorpropen Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 156)Lieferanten
Firmenname | Telefon | Land | Produktkatalog | Edge Rate | |
---|---|---|---|---|---|
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-+86-371-66670886 |
info@dakenam.com | China | 19805 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 |
sales@conier.com | China | 49732 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
factory@coreychem.com | China | 29808 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 |
sales@tnjchem.com | China | 34563 | 58 |
ANHUI WITOP BIOTECH CO., LTD | +8615255079626 |
eric@witopchemical.com | China | 23541 | 58 |
AFINE CHEMICALS LIMITED | +86-0571-85134551 |
sales@afinechem.com | China | 15395 | 58 |
Yangzhou Model Electronic Materials Co., Ltd. | +8613761402923 |
sales@modeltemol.com | CHINA | 571 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | +86-0571-88938639 +8617705817739 |
info@dycnchem.com | China | 52849 | 58 |
Alfa Chemistry | |
Info@alfa-chemistry.com | United States | 24072 | 58 |
10061-01-5((Z)-1,3-Dichlorpropen)Verwandte Suche:
2,3-Dichlorpropen
1,2-Dichlorpropen
Di-allat (ISO)
1,3-Dichlorpropen
1,1-Dichlorpropen
1,1,3-Trichlorpropen
Perchlorbutadien
1,1,2,3-Tetrachlor-1-propen
Hexachlorpropen
(Z)-1,3-Dichlorpropen
2,3,3-Trichloracryloylchlorid
- cis-dcp
- Propene, 1,3-dichloro-, (Z)-
- CIS-3-CHLOROALLYL CHLORIDE
- CIS-1,3-DICHLORO-1-PROPENE
- CIS-1,3-DICHLOROPROPENE
- cis-1,3-Dichloropropene (1mg/ml in methanol)
- 1 3-DICHLOROPROPENE (ISOMERIC) 2000MG &
- 1,3-DICHLOROPROPENE,(ISOMERIC), 2000MG, NEAT
- CIS-1 3-DICHLOROPROPENE NEAT STANDARD &
- CIS-1,3-DICHLOROPROPENE, 100MG, NEAT
- cis-1,3-dichloropropene (technical)
- 1,3-CIS-DICHLOROPROPENE
- 1,3-DICHLOROPROPENE(CIS)
- CIS-1,3-CHLOROPROPENE
- 1,3-Dichlorpropen (cis u. trans)
- cis-1,3-dichloropropenesingle*componentstandard
- cis-1,3-Dichloropropylene
- cis-1,3-Dichloropropene 
- cis-1,3-Dichloropropene Standard
- cis-1,3-Dichloropropene (1mg/ml in Methanol) [for Water Analysis]
- Dichloropropene, cis-1,3-
- cis-1,3-Dichloropropene solution
- (1Z)-1,3-Dichloropropene
- (Z)-1,3-Dichloropropylene
- (Z)-3-Chloroallyl chloride
- (Z)-γ-Chloroallyl chloride
- (1Z)-1,3-Dichloro-1-propene
- (Z)-1,3-Dichloropropene
- 3-dichloro-(z)-1-propen
- 3-dichloro-(z)-propen
- 1-Propene,1,3-dichloro-, (1Z)-
- cis-1,3-DichloropropyleneSolution,2,000mg/L,1ml
- cis-1,3-Dichloropropene>
- (z)-1,3-dichloro-1-propene
- cis-1,3-Dichloropropene
- 10061-01-5
- 10061015
- ClCH2CHCHCl
- Standard Solution of Volatile Organic Compounds for Water & Soil Analysis
- Standard Solutions (VOC)
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- Analytical Chemistry
- Standard Solution of Volatile Organic Compounds for Water & Soil Analysis
- Standard Solutions (VOC)