(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
CAS-Nr.
192139-90-5
Englisch Name:
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
Synonyma:
RuCl(p-cymene)[(S,S)-Ts-DPEN];RuCl[(S,S)- Tsdpen](p-cyMene);(S,S)-N-(p-ToL;)-1,2-diphenyL;ethanediamine(chL;-N-(p-Toluenesulfonyl);oro)(p-cymene)ruthenium(II);-1,2-diphenylethanediamine(chloro);[RuCl(η6-p-cyMene)(H2NC(Ph)C(Ph)NTs)];RuCl(p-cyMene)[(S,S)-Ts-DPEN], 16% Ru, Product of UMicore
CBNumber:
CB91569347
Summenformel:
C31H30ClN2O2RuS
Molgewicht:
631.17
MOL-Datei:
192139-90-5.mol
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Eigenschaften
Schmelzpunkt:
>175 °C
alpha
178o (C=0.5 IN CHLOROFORM)
storage temp.
2-8°C
L?slichkeit
soluble in Chloroform, DCM, Ethyl Acetate
Aggregatzustand
solid
Farbe
yellow to dark brown
Optische Aktivit?t
[α]20/D +178°, c = 0.5 in chloroform
Sensitive
air sensitive
InChIKey
DCJKLKCGNMDXFR-MNPNNRAMNA-M
SMILES
[Cl-][Ru+2]123456(N[C@@H](C7C=CC=CC=7)[C@H](C7C=CC=CC=7)[N-]1S(C1C=CC(C)=CC=1)(=O)=O)C1(C)C2=C3C4(C(C)C)=C5C6=1 |&1:3,10,r|
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Chemische Eigenschaften,Einsatz,Produktion Methoden
Chemische Eigenschaften
Solid
Verwenden
Catalyst involved in: ? Asymmetric transfer hydrogenation of imines and ketones ? Intramolecular asymmetric reductive amination ? Tandem hydroformylation / hydrogenation of terminal olefins Reactant involved in studies of thermal decomposition of arenerut
Allgemeine Beschreibung
RuCl(
p -cymene)[(
S ,
S )-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium, which can be used for the asymmetric transfer hydrogenation of a variety of imines.
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 182)Lieferanten
China 165
India 6
Japan 1
Switzerland 1
Ukraine 1
United States 8
Global 182
192139-90-5()Verwandte Suche:
-1,2-diphenylethanediamine(chloro)
-N-(p-Toluenesulfonyl)
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
Chloro{[(1S,2S)-(+)-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
[N-[(1S,2S)-2-(Amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-n)-1-methyl-4-(1-methylethyl)benzene]ruthenium
Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p- cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)
Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%
Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(S,S)-Tsdpen](p-cymene)
Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II)
Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(S,S)-Tsdpen](p-cyMene)
[RuCl(η6-p-cyMene)(H2NC(Ph)C(Ph)NTs)]
Chloro{[(1S,2S)-(+)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(S,S)-Tsdpen](p-cyMene)
RuCl(p-cyMene)[(S,S)-Ts-DPEN], 16% Ru, Product of UMicore
[(η-6-CyMene)[(S,S)-1,2-diphenyl-N-tosyl-1,2-ethanediaMinato]rutheniuM] chloride]
Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](p-cymene)
RuCl(p-cymene)[(S,S)-Ts-DPEN]
Chloro{[(1S,2S)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
[(1S,2S)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide,chlororuthenium(1+),1-methyl-4-propan-2-ylbenzene
[N-[(1S,2S)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-4-(1-
Ruthenium,[N-[(1S,2S)-2-(amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-
(S,S)-N-(p-ToL
ethanediamine(chL
oro)(p-cymene)ruthenium(II)
)-1,2-diphenyL
Chloro(p-cymene)[(S,S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)
[(S,S)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(p-cymene)ruthenium(II)
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) ISO 9001:2015 REACH
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro...
[(1S,2S)-2-amino-1,2-diphenyl-ethyl]-(p-tolylsulfonyl)azanide
RuCl(p-cymene)[(S,S)-Ts-DPEN]
RuCl[(S,S)- Tsdpen](p-cyMene)
[((S,S)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)( p -cymene)ruthenium(II)
RuCl[(S,S)-Tsdpen](p-cymene)/Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
((S,S)-2-Amino-1,2-Diphenylethyl)[(4-Tolyl)Sulfonyl]Amido](P-Cymene)Ruthenium (II)Chloride
N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]ruthenium (ACI)
192139-90-5
C32H44ClN2O2RuS
organometallic complex
Ru