Diphenyl-2,4,6-trimethylphenylsulfonium p-Toluenesulfonate
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- CAS-Nr.
- 347841-51-4
- Englisch Name:
- Diphenyl-2,4,6-trimethylphenylsulfonium p-Toluenesulfonate
- Synonyma:
- Diphenyl-2,4,6-trimethylphenylsulfonium tosylate;DIPHENYL-2,4,6-TRIMETHYLPHENYLSULFONIUM P-TOLUENESULFONATE
- CBNumber:
- CB8732921
- Summenformel:
- C28H28O3S2
- Molgewicht:
- 476.65
- MOL-Datei:
- Mol file
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Diphenyl-2,4,6-trimethylphenylsulfonium p-Toluenesulfonate Eigenschaften
- InChI
- InChI=1S/C21H21S.C7H8O3S/c1-16-14-17(2)21(18(3)15-16)22(19-10-6-4-7-11-19)20-12-8-5-9-13-20;1-6-2-4-7(5-3-6)11(8,9)10/h4-15H,1-3H3;2-5H,1H3,(H,8,9,10)/q+1;/p-1
- InChIKey
- CZSCUCRXCBAAGX-UHFFFAOYSA-M
- SMILES
- [S+](C1=CC=CC=C1)(C1=CC=CC=C1)C1C(C)=CC(C)=CC=1C.C1(S([O-])(=O)=O)=CC=C(C)C=C1
Sicherheit
Diphenyl-2,4,6-trimethylphenylsulfonium p-Toluenesulfonate Chemische Eigenschaften,Einsatz,Produktion Methoden
Verwenden
Diphenyl-2,4,6-trimethylphenylsulfonium p-Toluenesulfonate is used as an intermediate in organic synthesis.
Synthese
In aqueous methanol solution was dissolved 18.8 g (44 mmole) of diphenyl-2,4,6-trimethylphenylsulfonium trifluoromethanesulfonate and passed through an activated strong base type anion exchange resin. To the eluting solution was added 10.0 g (53 mmole) of p-toluenesulfonic acid monohydrate, followed by allowing a reaction to take place at room temperature for 1 hour with stirring. After the reaction, the solvent was removed, and the residue was dissolved in 200 ml of methylene chloride, washed with water three times and concentrated under reduced pressure to give 17.2 g (Yield: 91 %) of diphenyl-2,4,6-trimethylphenylsulfonium p-toluenesulfonate as white crystal.
Diphenyl-2,4,6-trimethylphenylsulfonium p-Toluenesulfonate Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Diphenyl-2,4,6-trimethylphenylsulfonium p-Toluenesulfonate Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 18)Lieferanten
- DIPHENYL-2,4,6-TRIMETHYLPHENYLSULFONIUM P-TOLUENESULFONATE
- Diphenyl-2,4,6-trimethylphenylsulfonium tosylate
- 347841-51-4
