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(1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol

(+)-ISOPINOCAMPHEOL Struktur
27779-29-9
CAS-Nr.
27779-29-9
Bezeichnung:
(1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol
Englisch Name:
(+)-ISOPINOCAMPHEOL
Synonyma:
Nsc167499;3-PINANOL;(+)-ISOPINOCAMPHEOL;(+)-Isopinocampheol;ISOPINOCAMPHEOL, (+)-;3-Pinanol, stereoisomer;ISOPINOCAMPHEOL, (-)-(SG);(1S,2S,3S,5R)-(+)-IsopinocaMpheol 98%;(1s,2s,3s,5r)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol;(1S,3R,4R,5R)-4,6,6-trimethylbicyclo[3.1.1]heptan-3-ol
CBNumber:
CB8441753
Summenformel:
C10H18O
Molgewicht:
154.25
MOL-Datei:
27779-29-9.mol

(1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol Eigenschaften

Schmelzpunkt:
52-55 °C
Siedepunkt:
219 °C(lit.)
Dichte
0.8389 (rough estimate)
Brechungsindex
1.4710 (estimate)
Flammpunkt:
93 °C
pka
15.35±0.60(Predicted)
Aggregatzustand
solid
Optische Aktivit?t
[α]20/D +35.1°, c =20 in ethanol
LogP
2.805 (est)

Sicherheit

WGK Germany  3

(1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol Chemische Eigenschaften,Einsatz,Produktion Methoden

Verwenden

(1S,2S,3S,5R)-(+)-Isopinocampheol may be used in the preparation of
  • thermotropic chiral nematic side-chain copolymers
  • ortho-(diphenylphosphino)phenylphosphonous acid di[(1S,2S,3S,5R)-2,6,6-trimethyl-bicyclo[3.1.1]-hept-3-yl]ester, a phosphino-phosphonite ligand
  • O,O′bis[(1S,2S,3S,5R)2,6,6-trimethylbicyclo[3.1.1]hept-3-yl] dithiophosphoric acid, a bioactive compound with antifungal effect

Allgemeine Beschreibung

(1S,2S,3S,5R)-(+)-Isopinocampheol is a chiral terpenol.

l?uterung methode

Dissolve it in Et2O, dry over MgSO4, filter, evaporate, then recrystallise it from pet ether. Also recrystallise it from aqueous EtOH and distil it in a vacuum. [Kergomard & Geneix Bull Soc Chim Fr 394 1958, Zweifel & Brown J Am Chem Soc 86 393 1964.] The 3,4-dinitrobenzoyl derivative has m 100-101o, the phenylcarbamoyl derivative has m 137-138o and the acid -phthalate has m 125-126o. [Beilstein 6 III 282, 283.]

(1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

(1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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27779-29-9((1α,2β,3α,5α)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol)Verwandte Suche:

  • ISOPINOCAMPHEOL, (+)-
  • (1s,2s,3s,5r)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-ol
  • ISOPINOCAMPHEOL, (-)-(SG)
  • (1S,2S,3S,5R)-3-Pinanol, 3-Pinanol, (1S,2S,3S,5R)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol
  • (1S,2S,3S,5R)-3-Pinanol, (1S,2S,3S,5R)-2,6,6-Trimethylbicyclo[3.1.1]heptan-3-ol
  • Bicyclo[3.1.1]heptan-3-ol, 2,6,6-trimethyl-, (1.alpha.,2.beta.,3.alpha.,5.alpha.)-
  • Nsc167499
  • (1S,2S,3S,5R)-(+)-IsopinocaMpheol 98%
  • 3-PINANOL
  • 3-Pinanol, stereoisomer
  • (+)-ISOPINOCAMPHEOL
  • (1S,3R,4R,5R)-4,6,6-trimethylbicyclo[3.1.1]heptan-3-ol
  • Bicyclo[3.1.1]heptan-3-ol, 2,6,6-trimethyl-, (1R,2R,3R,5S)-rel-
  • (+)-Isopinocampheol
  • 27779-29-9
  • Alcohols
  • Organic Building Blocks
  • Asymmetric Synthesis
  • Chiral Building Blocks
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