Chlordecon (ISO)
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Chlordecon (ISO) Eigenschaften
- Schmelzpunkt:
- 350℃ (DEC.)
- Siedepunkt:
- 450.5±45.0 °C(Predicted)
- Dichte
- 2.27
- Dampfdruck
- 2.25 x 10-7 mmHg at 25 °C (Kilzer et al., 1979)
- Flammpunkt:
- >100 °C
- storage temp.
- 0-6°C
- L?slichkeit
- Soluble in acetic acid, alcohols, and ketones (Windholz et al., 1983)
- Aggregatzustand
- Tan to white crystalline solid
- Wasserl?slichkeit
- (mg/L):
7.600 at 24 °C (shake flask-nephelometry, Hollifield, 1979)
2.7 at 20–25 °C (Kilzer et al., 1979)
- Merck
- 13,2098
- Henry's Law Constant
- (x 10-2 atm?m3/mol): 3.11 at 25 °C (approximate - calculated from experimentally determined water solubility and vapor pressure values)
- Expositionsgrenzwerte
- NIOSH REL: TWA 1 mg/m3.
- IARC
- 2B (Vol. 20, Sup 7) 1987
- EPA chemische Informationen
- Chlordecone (143-50-0)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher | T,N | ||
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R-S?tze: | 24/25-40-50/53 | ||
S-S?tze: | 22-36/37-45-60-61 | ||
RIDADR | 2761 | ||
OEB | E | ||
OEL | TWA: 0.001 mg/m3 | ||
RTECS-Nr. | PC8575000 | ||
HazardClass | 6.1(b) | ||
PackingGroup | III | ||
Giftige Stoffe Daten | 143-50-0(Hazardous Substances Data) | ||
Toxizit?t | LD50 orally in rats: 125 mg/kg (Gaines) |
Bildanzeige (GHS) |
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Chlordecon (ISO) Chemische Eigenschaften,Einsatz,Produktion Methoden
ERSCHEINUNGSBILD
WEISSE KRISTALLE.CHEMISCHE GEFAHREN
Beim Verbrennen Bildung von Chlord?mpfen und Chlorwasserstoff. Zersetzung bei Kontakt mit S?uren unter Bildung giftiger Rauche.ARBEITSPLATZGRENZWERTE
TLV nicht festgelegt (ACGIH 2005).MAK: Krebserzeugend Kategorie 3B; (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den K?rper über die Haut, durch Verschlucken und durch Inhalation.INHALATIONSGEFAHREN
Verdampfung bei 20°C vernachl?ssigbar; eine gesundheitssch?dliche Partikelkonzentration in der Luft kann jedoch beim Dispergieren schnell erreicht werden.WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION:M?glich sind Auswirkungen auf Zentralnervensystem und Leber mit nachfolgenden Funktionsst?rungen und Lebersch?den. Die Auswirkungen treten u.U. verz?gert ein.
WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION
Wiederholter oder andauernder Hautkontakt kann Dermatitis hervorrufen. M?glich sind Auswirkungen auf das endokrine System. M?glicherweise krebserzeugend für den Menschen. Fruchtbarkeitssch?digend oder entwicklungssch?digend.LECKAGE
Verschüttetes Material in Beh?ltern sammeln; falls erforderlich durch Anfeuchten Staubentwicklung verhindern. Reste sorgf?ltig sammeln. An sicheren Ort bringen. NICHT in die Umwelt gelangen lassen. Pers?nliche Schutzausrüstung: Atemschutzger?t, P3-Filter für giftige Partikel.R-S?tze Betriebsanweisung:
R24/25:Giftig bei Berührung mit der Haut und beim Verschlucken.R40:Verdacht auf krebserzeugende Wirkung.
R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Beschreibung
Chemically, kepone is a chlorinated polycyclic insecticide and fungicide. Chlordecone was used as an insecticide for leaf-eating insects, ants, and cockroaches; as a larvicide for flies; and for control of insects that attack structures. Chlordecone was also used on bananas, nonbearing citrus trees, tobacco, ornamental shrubs, lawns, turf, and flowers. The dry powder is readily absorbed through the skin and respiratory tract. Occupational workers handling kepone without appropriate workplace safety dress and PPE suffered chemical poisoning. The symptoms included, tremors, jerky eye movements, memory loss, headaches, slurred speech, unsteadiness, lack of coordination, loss of weight, rash, enlarged liver, decreased libido, sterility, chest pain, and arthralgia (sharp pain, extending along a nerve or group of nerves, experienced in a joint and/or joints). Chlordecone was first introduced as a pesticide in 1958 and was used until 1978, when its use in the United States was discontinued (NCI 1976, IARC 1979, HSDB 2009).Chemische Eigenschaften
Kerosene is a white to pale yellow, flammable liquid that has wide use in household and industrial activities. For instance, in heating, as cooking fuel, in cleaning, degreasing, as a solvent, for paints, enamels, polishes, varnishes, and in asphalt coating.Physikalische Eigenschaften
Colorless to tan, odorless, noncombustible, crystalline solidVerwenden
Chlordecone, a chlorinated dicyclodiene compound, was introduced under the trade name Kepone in 1958. In the United States, Kepone found use as an ant and cockroach poison. Outside the United States, it was used primarily as a pesticide against the banana root borer. The compound is the ketone analog of mirex; it is a contaminant of mirex and is also a product of mirex degradation.Definition
ChEBI: An organochlorine compound with insecticidal activity.Allgemeine Beschreibung
Odorless colorless crystalline solid.Air & Water Reaktionen
Insoluble in water.Reaktivit?t anzeigen
A halogenated ketone. Ketones are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.Health Hazard
INHALATION AND INGESTION: These symptoms present in all affected patients - Neurologic Impairment - anxiety, irritability, memory disturbance, headache, tremors, opsiclonus, stuttering, slurred speech, and abnormal tandem gait.Brandgefahr
Flash point data for KEPONE (TM) are not available; however, KEPONE (TM) is probably combustible.m?gliche Exposition
Kepone was registered for the control of rootborers on bananas with a residue tolerance of 0.01 ppm. This constituted the only food or feed use of Kepone. Nonfood uses included wireworm control in tobacco fields and bait to control ants and other insects in indoor and outdoor areas. A rebuttable presumption against registration of chlordecone was issued by the United States Environmental Protection Agency on March 25, 1976 on the basis of oncogenicity. The trademarked Kepone and products of six formulations were the subject of voluntary cancellation according to a United States Environmental Protection Agency notice dated July 27, 1977. In a series of decisions, the first of which was issued on June 17, 1976, the EPA effectively canceled all registered products containing Kepone as of May 1, 1978.Carcinogenicity
Kepone (chlordecone) is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.Environmental Fate
Photolytic. Kepone-contaminated soils from a site in Hopewell, VA were analyzed by GC/MS. 8-Chloro and 9-chloro homologs identified suggested these were photodegradation products of kepone (Borsetti and Roach, 1978). Products identified from the photolysis of kepone in cyclohexane were 1,2,3,4,6,7,9,10,10-nonachloro-5,5-dihydroxypentacyclo[ 5.3.0.02,6.03,9.04,8]decane for the hydrate and 1,2,3,4,6,7,9,10,10-nonachloro-5,5- dimethoxypentacyclo[5.3.0.02,6.03,9.04,8]decane (Alley et al., 1974).Chemical/Physical. Readily reacts with moisture forming hydrates (Hollifield, 1979). Decomposes at 350°C (Windholz et al., 1983) probably emitting toxic chlorine fumes.
Versand/Shipping
UN2761 Organochlorine pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.Inkompatibilit?ten
Acids, acid fumes.Waste disposal
A process has been developed which effects chlordecone degradation by treatment of aqueous wastes with UV radiation in the presence of hydrogen in aqueous sodium hydroxide solution. Up to 95% decomposition was effected by this process. Chlordecone previously presented serious disposal problems because of its great resistance to bio- and photo degradation in the environment. It is highly toxic to normally occur in degrading microorganisms. Although it can undergo some photodecomposition when exposed to sunlight to the dihydro compound (leaving a compound with 8 chloro substituents) that degradation product does not significantly reduce toxicity. Disposal by incineration with HCl scrubbing is recommended.Chlordecon (ISO) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Chlordecon (ISO) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 52)Lieferanten
Firmenname | Telefon | Land | Produktkatalog | Edge Rate | |
---|---|---|---|---|---|
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28172 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22963 | 58 |
Antai Fine Chemical Technology Co.,Limited | 18503026267 |
info@antaichem.com | CHINA | 9636 | 58 |
Aladdin Scientific | |
tp@aladdinsci.com | United States | 57505 | 58 |
Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 |
1026@dideu.com | China | 8808 | 58 |
Sichuan Kulinan Technology Co., Ltd | 400-1166-196 18981987031 |
cdhxsj@163.com | China | 11707 | 57 |
Spectrum Chemical Manufacturing Corp. | 021-021-021-67601398-809-809-809 15221380277 |
marketing_china@spectrumchemical.com | China | 9658 | 60 |
Shanghai Aladdin Bio-Chem Technology Co.,LTD | 400-6206333 13167063860 |
anhua.mao@aladdin-e.com | China | 25003 | 65 |
TianJin Alta Scientific Co., Ltd. | 022-65378550-8551 |
contact@altascientific.com | China | 2773 | 58 |
Codow Chemical Co.,Ltd. | 18620099427 |
amy@howeipharm.com | China | 17687 | 55 |
143-50-0(Chlordecon (ISO))Verwandte Suche:
2-Chlorcyclopentanon
2,3-Dichlorpropionaldehyd
2,5-Dichlor-2,5-dimethylhexan
1-Cyclobutylethan-1-on
5-Chlorpentan-2-on
6-Chlorhexan-2-on
[1,1'-Bicyclopentyl]-2-on
Chlordecon (ISO)
1,10-Dichlordecan
1,9-Dichlornonan
1,3-Dichloraceton
Cyclooctanon
(1α,2α,3α,4β,5β,6β)-1,2,3,4,5,6-Hexachlorcyclohexan
Lindan
Chlorcycloheptan
Cycloheptanon
HCH (ISO)
Hexachlorcyclopentan
- KEPONE (A.K.A. CHLORDECONE)
- Chlordecone(content>15%)
- Chlordecone emulsion(content>4%)
- CHLORDECON
- CHLORDECONE
- DECACHLOROOCTAHYDRO-1,3,4-METHENO-2 H,5 H-CYCLOBUTA [C,D] PENTALEN-2-ONE
- DECACHLORO OCTAHYDRO-1,3,4-METHENO-2H-CYCLOBUTA[CD]-PENTALEN-2-ONE
- GC-1189
- KEPONE, 50MG, NEAT
- KEPONE, 100MG, NEAT
- 1,3,4-metheno-2h-cyclobuta(cd)pentalen-2-one,1,1a,3,3a,4,5,5,5a,5b,6-decachlor
- 1,3,4-Metheno-2H-cyclobuta[cd]pentalen-2-one, 1,1a,3,3a,4,5,5,5a,5b,6-decachlorooctahydro-
- 2,3,3a,4,5,6,7,7a,8,8a-decachloro-3a,4,7,7a-tetrahydro-4,7-methanoinden-1-one
- 4-metheno-2h-cyclobuta(cd)pentalen-2-one,1,1a,3,3a,4,5,5,5a,5b,6-decachloroctahydro-3
- Chlorodecone
- Clordecone
- Compound 1189
- compound1189
- Decachloro-1,3,4-metheno-2H-cyclobuta(cd)pentalen-2-one
- Decachloroketone
- Decachlorooctahydro-1,3,4-metheno-2H-cyclobuta[cd]pentalin-2-one
- decachlorooctahydro-kepone-2-on
- keponealcohol
- Merex
- NCI-C00191
- ntalen-2-one
- o-4-one
- ooctahydro-
- -pentalone
- perchloropentacyclo[5.3.0.0(2,6).0(3,9).0(4,8)decan-5-one
- Rcra waste number U142
- 1,1a,3,3a,4,5,5,5a,5b,6-decachlorooctahydro-1,3,4-metheno-2h-cyclobuta(cd)pe
- 1,1a,3,3a,4,5,5,5a,5b,6-Decachlorooctahydro-1,3,4-metheno-2H-cyclobuta(cd)pentalen-2-one
- 1,1a,3,3a,4,5,5,5a,5b,6-decachloro-octahydro-1,3,4-metheno-2h-cyclobuta[cd]pen
- 1,2,3,4,5,5,6,7,8,9,10,10-dodecachlorooctahydro-1,3,4-metheno-2-cyclobuta-(c,d)
- 1,2,3,5,6,7,8,9,10,10-decachloro(5.2.1.0(sup2,6).0(sup3,9).0(sup5,8))decan
- 1,2,3,5,6,7,8,9,10,10-Decachloro(5.2.1.02,6.03,9 .05,8)decan-4-one
- 1,3,4-Metheno-2H-cyclobuta(cd)pentalen-2-one, 1,1a,3,3a,4,5,5,5a,5b,6-decachloroctahydro-
- decachloropentacyclo(5.2.1.0(2,6).0(3,9).0(5),(8))decan-4-one
- decachloropentacyclo(5.2.1.0(sup2,6).0(sup3,9).0(sup5,8))decan-4-one
- decachloropentacyclo(5.3.0.0(sup2,6).0(sup4,10).0(sup5,9))decan-3-one
- Decachloropentacyclo(5.3.0.02,6.04,10.05,9)decan-3-one
- Decachloropentacyclo[5.2.1.0(2,6).0(3,9).0(5,8)]decan-4-one
- Decachloropentacyclo[5.2.1.0(sup2,6).0(sup3,9).0(sup5,8)]decan-4-one
- Decachlorotetracyclodecanone
- decachlorotetrahydro-4,7-methanoindeneone
- decachlorpentacyclo (5.2.1.0(2,6).0(3,9).0(5,8)) decan-4-one
- ENT 16,391
- ent16,391
- ENT-16391
- General chemicals 1189
- generalchemicals1189
- hlordecane
- Kepone-2-one, decachlorooctahydro-
- rcrawastenumberu142
- talen-2-one
- CHLORDECON PESTANAL (DECACHLORO- PENTACY
- KEPONE