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Phenmedipham

Phenmedipham Struktur
13684-63-4
CAS-Nr.
13684-63-4
Bezeichnung:
Phenmedipham
Englisch Name:
Phenmedipham
Synonyma:
M75;Gusto;EP-452;Pistol;sn4075;Suplex;BEETUP;FENDER;ALEGRO;EP-462
CBNumber:
CB8404828
Summenformel:
C16H16N2O4
Molgewicht:
300.31
MOL-Datei:
13684-63-4.mol

Phenmedipham Eigenschaften

Schmelzpunkt:
140-144°C
Siedepunkt:
441.54°C (rough estimate)
Dichte
1.1782 (rough estimate)
Brechungsindex
1.6240 (estimate)
Flammpunkt:
100 °C
storage temp. 
Sealed in dry,Room Temperature
L?slichkeit
DMSO (Slightly), Methanol (Slightly)
Aggregatzustand
Solid
pka
13.03±0.70(Predicted)
Farbe
White to off-white
Wasserl?slichkeit
<0.1 g/100 mL at 21 ºC
BRN 
2395027
LogP
3.590
CAS Datenbank
13684-63-4(CAS DataBase Reference)
NIST chemische Informationen
Methyl 3-m-tolylcarbamoyloxyphenylcarbamate(13684-63-4)
EPA chemische Informationen
Phenmedipham (13684-63-4)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher N
R-S?tze: 50/53
S-S?tze: 60-61
RIDADR  UN 3077
WGK Germany  2
RTECS-Nr. FD9050000
Giftige Stoffe Daten 13684-63-4(Hazardous Substances Data)
Toxizit?t (96-hour) for bluegill sunfish 3.98 mg/L, rainbow trout 1.4–3.0 mg/L, Daphnia magna 3.2 mg/L (Worthing and Hance, 1991), harlequin fish 16.5 mg/L (Hartley and Kidd, 1987); acute oral LD50 of pure phenmedipham and the formulated product for rats 3,700 and 10,300 mg/kg, respectively (Ashton and Monaco, 1991).
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS09.jpg" width="20" height="20" /> P273, P391, P501
Sicherheit
P273 Freisetzung in die Umwelt vermeiden.
P391 Verschüttete Mengen aufnehmen.
P501 Inhalt/Beh?lter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen.

Phenmedipham Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.

S-S?tze Betriebsanweisung:

S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.

Chemische Eigenschaften

Colorless crystalline solid, or needles; white powder. Odorless. Commercial product is available as an emulsifiable concentrate

Verwenden

Phenmedipham is an carbanilate selective herbicide used post-emergence in beet crops after the emergence of most broad-leaved weeds and before they develop.

Definition

ChEBI: A carbamate ester that is (3-methylphenyl)carbamic acid in which the hydrogen of the hydroxy group has been replaced by a 3-[(methoxycarbonyl)amino]phenyl group.

Allgemeine Beschreibung

Colorless crystals or white powder.

Air & Water Reaktionen

Insoluble in water.

Reaktivit?t anzeigen

3-((Methoxycarbonyl)amino)phenyl (3-methylphenyl)carbamate is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates. 3-((Methoxycarbonyl)amino)phenyl (3-methylphenyl)carbamate is incompatible with alkaline preparations.

Brandgefahr

Flash point data for 3-((Methoxycarbonyl)amino)phenyl (3-methylphenyl)carbamate are not available, however 3-((Methoxycarbonyl)amino)phenyl (3-methylphenyl)carbamate is probably combustible.

Landwirtschaftliche Anwendung

Herbicide: A post-emergence herbicide for control of annual broadleaf weeds and grasses in sugar beets, spinach, strawberries, and sunflowers

Handelsname

AIMSAN®; BETAMIX® (phenmedipham + desmedipham); BETANAL®; CQ 1451® (phenmedipham + desmedipham + ethofumesate); EC herbicide (phenmedipham + desmedipham + ethofumesate); EP 452®; KEEPER®; KEMIFAM®; MSS HERBASAN®; NA 305® (phenmedipham + desmedipham + ethofumesate); NA 308® (phenmedipham + desmedipham + ethofumesate); POWERTWIN® (phenmedipham + ethofumesate); PROGRESS® (phenmedipham + desmedipham + ethofumesate); S-4075®; SCHERING 4072®; SN 38584®; SPINAID ®; SYNBETAN-P®; TWIN®; VANGARD®

m?gliche Exposition

A postemergence bis-carbamate/ carbamate ester herbicide used to control of annual broadleaf weeds and grasses in sugar beets, spinach, strawberries, and sunflowers.

Environmental Fate

Soil. Phenmedipham degraded in soil forming methyl N-(3-hydroxyphenyl)-carbamate and m-aminophenol (Hartley and Kidd, 1987). Hydrolysis yields m-aminophenol (Rajagopal et al., 1989). The reported half-life in soil is approximately 20 days (Rajagopal et al., 1989) and 26 days (Worthing and Hance, 1991)
Plant. In plants, methyl N-(3-hydroxyphenyl)carbamate is the major metabolite (Hartley and Kidd, 1987)
Photolytic. Bussacchini et al. (1985) studied the photolysis (λ = 254 nm) of phenmedipham in ethanol, ethanol/water and hexane as solvents. In their proposed free radical mechanism, homolysis of the carbon-oxygen bond of the carbamate linkage ga

Versand/Shipping

UN2757 Carbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material,

Inkompatibilit?ten

Decomposes .145C. Esters ith acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Carbamates are incompatible with reducing agents, strong acids, oxidizing acids, peroxides, and bases. Contact with active metals or nitrides cause the release of flammable, and potentially explosive, hydrogen gas. Releases oxides of nitrogen and carbon when heated to decomposition.

Waste disposal

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Phenmedipham Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Phenmedipham Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 169)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Qingdao Trust Agri Chemical Co.,Ltd
+8613573296305
aroma@qdtrustagri.com China 301 58
Hebei Jingbo New Material Technology Co., Ltd
+8619931165850
hbjbtech@163.com China 1000 58
Hebei Saisier Technology Co., LTD
+86-18400010335 +86-18034520335
admin@hbsaisier.cn China 1015 58
Hebei Longbang Technology Co., LTD
+86-18633929156 +86-18633929156
admin@hblongbang.com China 941 58
HebeiShuoshengImportandExportco.,Ltd
+86-18532138899 +86-18532138899
L18532138899@163.com China 939 58
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28172 58
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22963 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873
sales@chemdad.com China 39894 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 49374 58
career henan chemical co
+86-0371-86658258 +8613203830695
factory@coreychem.com China 29815 58

13684-63-4(Phenmedipham)Verwandte Suche:


  • 3-methoxycarbonyl-n-(3’-methylphenyl)-carbamat
  • 3-Methoxycarbonyl-N-(3'-methylphenyl)-carbamat
  • Beetomax
  • Betaflow
  • Betalion
  • Betamix
  • Betanal E
  • Betosip
  • Carbamic acid, (3-methylphenyl)-, 3-[(methoxycarbonyl)amino]phenyl ester
  • Carbanilic acid, m-hydroxy-, methyl ester, m-methylcarbanilate
  • Carbanilic acid, m-hydroxy-, methyl ester, m-methylcarbanilate (ester)
  • (3-methylphenyl)-carbamicaci3-((methoxycarbonyl)amino)phenylester
  • 3-(Carbomethoxyamino)phenyl 3-methylcarbanilate
  • 3-(carbomethoxyamino)phenyl3-methylcarbanilate
  • 3-(Methylphenyl)carbamic acid 3-((methoxycarbonyl)amino)phenyl ester
  • 3-(methylphenyl)carbamicacid3-((methoxycarbonyl)amino)phenylester
  • carbanilicacid,m-hydroxy-,methylester,m-methylcarbanilate
  • carbanilicacid,m-hydroxy,methylester,m-methylcarbanilate(ester)
  • EP-452
  • Fenmedifam
  • Goliath
  • Gusto
  • Headland dephend
  • Medipham
  • Methyl m-hydroxycarbanilate m-methylcarbanilate
  • Methyl N-[3-[N-(3-methylphenyl)carbamoyloxy]phenyl]carbamate
  • methyl-3-hydroxycarbanilate-3-methylcarbanilate
  • methyl-3-m-tolycarbamoloxyphenylcarbamate
  • methylm-hydroxycarbanilate,m-methylcarbanilate
  • methyln-(3-(n-(3-methylphenyl)carbamoyloxy)phenyl)carbamate
  • m-Hydroxycarbanilic acid methyl ester m-methylcarbanilate
  • m-hydroxycarbanilicacid,methylesterm-methylcarbanilate
  • m-hydroxycarbanilicacidmethylesterm-methylcarbanilate
  • Phendipham
  • phenmedipham(fenmedifam)
  • Phenmediphame
  • phenmediphan
  • Pistol
  • Pistol 400
  • Protrum K
  • Protrum K SN 38584
  • Schering 4072
  • Schering-38584
  • SN 4075
  • SN-38584
  • sn4075
  • Spin-aid
  • Suplex
  • synbetanp
  • Tripart beta
  • Tripart beta 2
  • Vanguard
  • METHYL 3-M-TOLYL CARBAMOYLOXY PHENYL CARBAMATE
  • BEETUP
  • BETANAL
  • BETAPOST
  • FENDER
  • HERBASAN
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