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3-Phenyl-2-propens?ure-2-propenylester

ALLYL CINNAMATE Struktur
1866-31-5
CAS-Nr.
1866-31-5
Bezeichnung:
3-Phenyl-2-propens?ure-2-propenylester
Englisch Name:
ALLYL CINNAMATE
Synonyma:
Nsc20972;FEMA 2022;Wln: 1U2ov1U1r;ALLYL CINNAMATE;propenylcinnamate;Propenyl cinnamate;allyl (E)-cinnamate;Allyl CinnaMate allyl3-phenylacrylate;ALLYL CINNAMATE, 99+%
CBNumber:
CB8304551
Summenformel:
C12H12O2
Molgewicht:
188.22
MOL-Datei:
1866-31-5.mol

3-Phenyl-2-propens?ure-2-propenylester Eigenschaften

Siedepunkt:
150-152 °C15 mm Hg(lit.)
Dichte
1.053 g/mL at 25 °C(lit.)
Brechungsindex
n20/D 1.566(lit.)
FEMA 
2022 | ALLYL CINNAMATE
Flammpunkt:
>230 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
L?slichkeit
Insoluble in water, soluble in alcohol and oils, almost insoluble in Propylene glycol.
Farbe
A colourless or pale straw-coloured liquid.
Geruch (Odor)
at 100.00 %. fruity balsamic pineapple spicy cinnamyl plum apricot peach
Geruchsart
fruity
JECFA Number
19
LogP
2.93
CAS Datenbank
1866-31-5(CAS DataBase Reference)
EPA chemische Informationen
2-Propenoic acid, 3-phenyl-, 2-propenyl ester (1866-31-5)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xn
R-S?tze: 22
S-S?tze: 26-36
WGK Germany  3
RTECS-Nr. GD8050000
HS Code  29163100
Toxizit?t The acute oral LD50 value in rats was reported as 1.52 g/kg and the acute dermal LD50 value in rabbits as less than 5 g/kg(Levenstein, 1975).
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitssch?dlich bei Verschlucken. Akute Toxizit?t oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
Sicherheit

3-Phenyl-2-propens?ure-2-propenylester Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R22:Gesundheitssch?dlich beim Verschlucken.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.

Chemische Eigenschaften

A colorless liquid with peach- or apricot-like aroma. It is used as a flavoring agent or adjuvant.

Occurrence

Has apparently not been reported to occur in nature.

Verwenden

Allyl Cinnamate is a synthetic flavoring agent that is a fairly stable, hazy, colorless to light yellow colored liquid of cherry odor. it is used for its cherry note in flavors and has application in baked goods and candies at 1–2 ppm.

Vorbereitung Methode

Allyl cinnamate is produced by the direct esterification of allyl alcohol with cinnamic acid.

synthetische

By esterification of cinnamic acid with allyl alcohol in the presence of concentrated H2SO4.

Sicherheitsprofil

Moderately toxic by ingestion. Human skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS

Stoffwechsel

Many esters, including benzyl cinnamate, are rapidly hydrolysed in vivo. Cinnamic acid is known to conjugate with glycine in the animal body, or it may be converted to benzoic acid(Williams, 1959). In the rabbit, cinnamic acid is almost entirely excreted as hippuric acid, without formation of cinnamoyl glycine(El Masry, Smith & Williams, 1956) . In the dog, Quick(1928) observed a large excretion of glucuronide, probably benzoylglucuronide. Dakin (1909) named B-phenyl-B-oxopropionic acid, cinnamoyl glycine and acetophenone as minor metabolites in the dog.

Solubility in organics

Allyl Cinnamate is soluble in alcohol and oils, almost insoluble in Propylene glycol.

3-Phenyl-2-propens?ure-2-propenylester Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


3-Phenyl-2-propens?ure-2-propenylester Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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1866-31-5(3-Phenyl-2-propens?ure-2-propenylester)Verwandte Suche:


  • allyl3-phenylacrylate
  • Allylester kyseliny skoricove
  • allylesterkyselinyskoricove
  • Propenyl cinnamate
  • propenylcinnamate
  • Vinyl carbinyl cinnamate
  • vinylcarbinylcinnamate
  • ALLYL CINNAMATE, 99+%
  • 3-phenyl-2-propenoicaci2-propenylester
  • Allyl (2E)-3-phenyl-2-propenoate
  • Allyl 3-phenylacrylate
  • Allyl Cinnamate (stabilized with TBC)
  • 3-Phenylacrylic acid allyl ester
  • 3-Phenylpropenoic acid allyl ester
  • (E)-3-Phenylpropenoic acid 2-propenyl ester
  • trans-Cinnamic acid allyl ester
  • Nsc20972
  • Wln: 1U2ov1U1r
  • ALLYL CINNAMATE
  • Allyl CinnaMate 
  • CINNAMIC ACID ALLYL ESTER
  • FEMA 2022
  • 2-Propenoic acid, 3-phenyl-, 2-propenyl ester
  • 2-Propenoicacid,3-phenyl-,2-propenylester
  • 2-propenyl3-phenyl-2-propenoate
  • Allyl cinnamate, 99%, stabilized with 100 ppm TBC
  • Allyl Cinnamate (stabilized with TBC)>
  • 2-Propenoic acid, 3-phenyl-, 2-propen-1-yl ester
  • ALLYL CINNAMATE USP/EP/BP
  • allyl (E)-cinnamate
  • Allyl cinnamate,contains 1ppm TBC as stabilizer
  • ALLYL CINNAMATE 1866-31-5
  • Allyl cinnamate Allyl cinnamate
  • Allyl cinnamate,contains 100ppm TBC as stabilizer
  • 1866-31-5
  • C8H7COOC3H5
  • C6H5CHCHCOOC3H5
  • C6H5CHCHCO2CH2CHCH2
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