(R)-(+)-TolBINAP
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- CAS-Nr.
- 99646-28-3
- Englisch Name:
- (R)-(+)-TolBINAP
- Synonyma:
- (R)-TOL-BINAP;(R)-T-BINAP;98% (R)-TolBINAP;(R)-p-tolyl-BINAP;(R)-(+)-2,2'-Bis(di-p-toL;phosphino)-1,1'-binaphthyL;2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthalene;(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)1,1-BINAPHTHYL;(R)-2,2’-Bis(di-p-tolylphosphino)-1,1’-binaphthalene;(R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
- CBNumber:
- CB7334533
- Summenformel:
- C48H40P2
- Molgewicht:
- 678.8
- MOL-Datei:
- 99646-28-3.mol
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(R)-(+)-TolBINAP Eigenschaften
- Schmelzpunkt:
- 255-257 °C
- alpha
- +156° (c 0.5, C6H6)
- Siedepunkt:
- 754.4±60.0 °C(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- Aggregatzustand
- Powder
- Farbe
- White to cream
- Optische Aktivit?t
- [α]20/D +162°, c = 0.5 in benzene
- Wasserl?slichkeit
- Insoluble in water.
- maximale Wellenl?nge (λmax)
- 223nm(EtOH)(lit.)
- CAS Datenbank
- 99646-28-3(CAS DataBase Reference)
(R)-(+)-TolBINAP Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
Chemische Eigenschaften
White to cream powder
Verwenden
(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl is used as chiral catalyst ligand. (R)-T-BINAP complexes derived from rhodium precursors are used for the asymmetric hydroformylation of vinyl acetate. It is a catalysts used for reductive amination of ketones, Pt dications for cation trapping, Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives.
Allgemeine Beschreibung
BINAP is based on a bis naphthalene backbone with different phosphine derivatives. 2,2′-bis(di-
p-tolylphosphino)-1,1′-binaphthyl (
p-Tol-BINAP)·AgF complex catalyzed asymmetric Mukaiyama-type aldol reaction is reported.
(R)-(+)-TolBINAP Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(R)-(+)-TolBINAP Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 151)Lieferanten
99646-28-3()Verwandte Suche:
- (R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)1,1-BINAPHTHYL
- (R)-(+)-2,2''-BIS(DI-P-TOLYLPHOSPHINO)-1,1''-BINAPHTHYL (R)-TOL-BINAP
- PHOSPHINE, 1,1''-(1R)-[1,1''-BINAPHTHALENE]-2,2''-DIYLBIS[BIS(4-METHYLPHENYL)-
- (R)-T-BINAP
- (R)-Tol-BINAP, (R)-(+)-2,2μ-Bis(di-p-tolylphosphino)-1,1μ-binaphthyl
- (R)-TolBINAP,99%e.e.
1,1'-(1R)-[1,1'-Binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)phosphine]
- (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, (R)-p-Tol-BINAP
- (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 95+%
- (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl,98%(R)-Tol-BINAP
- 98% (R)-TolBINAP
- (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl,98%
- (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl, 99% (R)-p-Tol-BINAP
- (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl 97%
- 1,1'-(1R)-[1,1'-Binaphthalene]-2,2'-diylbis[bis(4-
methylphenyl)phosphine]
- (R)-(+)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
- (R)-p-tolyl-BINAP
- (R)-(+)-2,2'-Bis(di-p-toL
- phosphino)-1,1'-binaphthyL
- (R)-(+)-2,2'-Bis-[bis-(p-tolylphosphino)]-1,1'-binaphthyl
- Phosphine, (1R)-[1,1'-binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)-
- (R)-TOL-BINAP
- (r)-(+)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl, 95+%
- (R)-2,2’-Bis(di-p-tolylphosphino)-1,1’-binaphthalene
- (1R)-[1-[2-(bis-p-tolylphosphanyl)-1-naphthyl]-2-naphthyl]-bis(p-tolyl)phosphane
- 1,1'-(1R)-[1,1'-Binaphthalene]-2,2'-diylbis[bis(4-methylphenyl)phosphine
- 2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthalene
- (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl
(R-tol-Binap)
- 99646-28-3
- 10165-88-6
- C48H4OP2
- Privileged Ligands
- Chiral Catalysts, Ligands, and Reagents
- BINAPs
- Asymmetric Synthesis
- Chiral Phosphine
- BINAP Series
