(R)-5-Isopropyl-2-methylcyclohexa-1,3-dien
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- CAS-Nr.
- 4221-98-1
- Bezeichnung:
- (R)-5-Isopropyl-2-methylcyclohexa-1,3-dien
- Englisch Name:
- (-)-P-MENTHA-1,5-DIENE
- Synonyma:
- ALPHA-PHELLANDRENE;(R)-α-Phellandrene;P-MENTHA-1,5-DIENE;L-ALPHA-PHELLANDRENE;Carylene;65.0%(GC);1-phellandrene;PHELLANDRENE, R-;(-)-α-phellandrene;(-)-α-Phellandrene
- CBNumber:
- CB6240491
- Summenformel:
- C10H16
- Molgewicht:
- 136.23
- MOL-Datei:
- 4221-98-1.mol
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(R)-5-Isopropyl-2-methylcyclohexa-1,3-dien Eigenschaften
- alpha
- D20 -217°
- Siedepunkt:
- 171-174 °C(lit.)
- Dichte
- 0.844 g/mL at 20 °C(lit.)
- Dampfdruck
- 2.35hPa at 20℃
- Brechungsindex
- n20/D 1.475
- Flammpunkt:
- 49 °C
- storage temp.
- 2-8°C
- L?slichkeit
- Benzene (Sparingly), Ethyl Acetate (Slightly)
- Aggregatzustand
- clear liquid
- Farbe
- Colorless to Light yellow to Light orange
- Geruch (Odor)
- at 100.00 %. terpene spicy medicinal
- Geruchsart
- terpenic
- Optische Aktivit?t
- [α]20/D 225±5°, c = 10% in diethyl ether
- Wasserl?slichkeit
- 4.37mg/L at 20℃
- Merck
- 14,7200
- BRN
- 2497824
- LogP
- 5.74 at 21.6℃
- CAS Datenbank
- 4221-98-1(CAS DataBase Reference)
- EPA chemische Informationen
- 1,3-Cyclohexadiene, 2-methyl-5-(1-methylethyl)-, (5R)- (4221-98-1)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| R-S?tze: |
10 |
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| RIDADR |
UN 2319 3/PG 3 |
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| WGK Germany |
3 |
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| F |
23 |
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| HS Code |
2902.19.0050 |
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| HazardClass |
3 |
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| PackingGroup |
III |
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| Bildanzeige (GHS) |
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| Alarmwort |
Warnung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H226 |
Flüssigkeit und Dampf entzündbar. |
Entzündbare Flüssigkeiten |
Kategorie 3 |
Warnung |
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| Sicherheit |
| P210 |
Von Hitze, hei?en Oberfl?chen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen. |
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(R)-5-Isopropyl-2-methylcyclohexa-1,3-dien Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R10:Entzündlich.
Chemische Eigenschaften
(?)-α-Phellandrene is a colorless
liquid with a citrus odor and a slight peppery note. It is isolated, for example, from
Eucalyptus dives oil. Pinenes are widespread, naturally occurring terpene hydrocarbons. The α- and
β-forms occur in varying ratios in essential oils.
Verwenden
(
R)-(-)-α-Phellandrene undergoes [4+2] cycloaddition with 2-naphthyl acetylenecarboxylate to form a chiral diene, which can act as a ligand for the rhodium-catalyzed asymmetric addition reactions. It may be used to synthesize (1
S,5
R)-5-(1-methylethyl)-2-methylidene-3-cyclohexen-1-yl hydroperoxide, which on reduction forms
trans-yabunikkeol.
Allgemeine Beschreibung
(
R)-(-)-α-Phellandrene is a monoterpene derivative.
l?uterung methode
Purify it by gas chromatography on an Apiezon column. Also purify it by steam distillation (with 0.5% hydroquinone), then re-distil it through a 50 plate bubble cap column b 72-72.5o/22mm [Pines & Eschinazi J Am Chem Soc 77 6318 1955]. UV: max 263nm ( 3,345) in octane. [Read & Storey J Chem Soc 2770 1930, Beilstein 5 III 341, 5 IV 436.]
(R)-5-Isopropyl-2-methylcyclohexa-1,3-dien Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(R)-5-Isopropyl-2-methylcyclohexa-1,3-dien Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 106)Lieferanten
4221-98-1((R)-5-Isopropyl-2-methylcyclohexa-1,3-dien)Verwandte Suche:
p-Mentha-1,4-dien
1-Methyl-4-(2-methyloxiranyl)-7-oxabicyclo(4.1.0)heptan
(±)-1-Methyl-4-(1-methylvinyl)cyclohexen
2-Isopropyl-5-methyl-p-benzochinon
(R)-(-)-Carvon
4,5,6,7-Tetrahydro-3,6-dimethylbenzofuran
Dipenten
(S)-p-Mentha-1,8-dien
Methylcyclohexadien
Cyclohexa-1,3-dien
p-Mentha-1,5-dien
(R)-5-Isopropyl-2-methylcyclohexa-1,3-dien
(R)-p-Mentha-1,8-dien
alpha-Terpinen
(3R-trans)-3-Methyl-6-(1-methylvinyl)cyclohexen
- (R)-5-isopropyl-2-methylcyclohexa-1,3-diene
- 1,3-Cyclohexadiene, 2-methyl-5-(1-methylethyl)-, (5R)-
- R-(-)-A-PHELLANDRENE WITH GC
- (-)-α-phellandrene
- (R)-2-methyl-5-(1-methylethyl)-1,3-cyclohexadiene
- (-)-p-Mentha-1,5-diene, (R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene
- PETUNIDIN CHLORIDE(SH)
- (R)-()-α-Phellandrene,()-p-Mentha-1,5-diene, (R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene
- (-)-5-Isopropyl-2-methyl-1,3-cyclohexadiene
(-)-p-Mentha-1,5-diene
- (R)-(-)-alpha-Phellandrene >=95.0% (sum of enantiomers, GC)
- 1,3-cyclohexadiene,2-methyl-5-(1-methylethyl)-,(R)-
- 1-phellandrene
- 2-methyl-5-(1-methylethyl)-3-cyclohexadien(theta)-
- 3-Cyclohexadiene,2-methyl-5-(1-methylethyl)-,(R)-1
- p-mentha-1,5-diene,(R)-(-)-
- α-phellandrene,(-)-
- (-)-5-ISOPROPYL-2-METHYL-1,3-CYCLOHEXADIENE
- (-)-2-METHYL-5-ISOPROPYL-1,3-CYCLOHEXADIENE
- R(-)-ALPHA-PHELLANDRENE
- (R)-5-ISOPROPYL-2-METHYL-1,3-CYCLOHEXADIENE
- (-)-P-MENTHA-1,5-DIENE
- PHELLANDRENE, R-(-)-ALPHA-
- (5R)-2-methyl-5-propan-2-ylcyclohexa-1,3-diene
- 65.0%(GC)
- (-)-α-Phellandrene>
- (-)-alpha-Phellandrene
- Carylene
- (-)-α-Phellandrene
- (-)-P-MENTHA-1,5-DIENE
- L-ALPHA-PHELLANDRENE
- ALPHA-PHELLANDRENE
- P-MENTHA-1,5-DIENE
- (R)-α-Phellandrene
- (-)-5-Isopropyl-2-Methyl-1,3-Cyclohexadiene
- )-p-Mentha-1,5-diene, (R)-5-Isopropyl-2-methyl-1,3-cyclohexadiene
- PHELLANDRENE, R-
- 4221-98-1
- 221-98-1
- Terpenes
- Monocyclic Monoterpenes
- Organic Building Blocks
- Chiral Building Blocks
- Asymmetric Synthesis
- Alkenes
- Biochemistry
- Monocyclic Monoterpenes
- Terpenes
