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1,4-Bis(diphenylphosphino)butane-palladium(II) chloride

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Struktur
29964-62-3
CAS-Nr.
29964-62-3
Englisch Name:
1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
Synonyma:
PDCI2(DPPB);PdCl2(dppb);adium(II) DichL;[1,4-Bis(diphenyL;phosphino)butane]paL;Palladium(ii) chloride 1,4-b;[(C6H5)2PCH2CH2CCH2H2P(C6H5)2]PdCl2;Bisdiphenylphosphinobutanepalladiumdichloride;[1,4-bis(diphenylphosphino)butane] palladium(II);4-diphenylphosphiniumylbutyl(diphenyl)phosphonium
CBNumber:
CB6185262
Summenformel:
C28H28P2.Cl2Pd
Molgewicht:
603.8
MOL-Datei:
29964-62-3.mol

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Eigenschaften

Schmelzpunkt:
285-305 °C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
L?slichkeit
Soluble in ethanol, benzene, and ethereal solvents.
Aggregatzustand
Powder
Farbe
light-yellow
InChIKey
JQXJBXVWVPVTOO-UHFFFAOYSA-L
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xn
R-S?tze: 36/37/38
S-S?tze: 24/25-36-27
WGK Germany  3
1-10
HS Code  28439000
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P304+P340 BEI EINATMEN: Die Person an die frische Luft bringen und für ungehinderte Atmung sorgen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.
P405 Unter Verschluss aufbewahren.

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Chemische Eigenschaften,Einsatz,Produktion Methoden

S-S?tze Betriebsanweisung:

S24/25:Berührung mit den Augen und der Haut vermeiden.

Chemische Eigenschaften

yellow solid

Verwenden

Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II) is used for the catalysis of styrene carbonylation, coupling of alkyl Grignard reagents with organic halides, selective monoalkylation of organic polyhalides, and modification of the dihalovinyl moiety of synthetic pyrethroids.

synthetische

Dichloro[1,4-bis(diphenylphosphino)butane]palladium(II) (1,4-Bis(diphenylphosphino)butane-palladium(II) chloride) can be prepared conveniently in situ by mixing the bidentate phosphine ligand and (PhCN)2PdCl2 in either benzene or chloroform.[1] The preparation of (dppb)PdCl2 is also possible through the reaction of PdCl2 with dppb in acetone, a process that slowly forms the catalyst as a white precipitate which can be isolated in 51% yield.[2] Preparation of the hydrate complex is possible via the reaction of Na2[PdCl4] with dppb in a mixture of CH2Cl2 and water.

1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 242)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Honest Joy Holdings Limited
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Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886
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Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
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ATK CHEMICAL COMPANY LIMITED
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ivan@atkchemical.com China 32965 60
career henan chemical co
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sales@coreychem.com China 29869 58
Nanjing Dolon Biotechnology Co.,Ltd.
18905173768
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Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28172 58
Accela ChemBio Inc.
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Chongqing Chemdad Co., Ltd
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Alchem Pharmtech,Inc.
8485655694
sales@alchempharmtech.com United States 63687 58

29964-62-3()Verwandte Suche:


  • Palladium(ii) chloride 1,4-b
  • 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride,98+%
  • Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II), Palladium(II) chloride 1,4-bis(diphenylphosphino)butane complex
  • Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II), Pd 17.6%
  • 1,4-Butylenebis(diphenylphosphine)-palladium dichloride
  • Dichloro[1,4-bis(diphenylphosphino)butane]palladium (II) ,98%
  • 4-Bis(diphenylphosphino)butane-palladiuM(II) chloride
  • PDCI2(DPPB)
  • 1,4- double(twophenyl phosphinebutane)twopalladiuM chloride
  • [(C6H5)2PCH2CH2CCH2H2P(C6H5)2]PdCl2
  • 1,4-bis (diphenylphosphino butane) palladiuM dichloride
  • 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II)
  • PdCl2(dppb)
  • dichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane
  • DICHLORO[1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]PALLADIUM(II)
  • 1,4-BIS(DIPHENYLPHOSPHINE)BUTANE PALLADIUM(II) CHLORIDE
  • 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE-PALLADIUM(II) CHLORIDE
  • [1,4-BIS(DIPHENYLPHOSPHINO)BUTANE]PALLADIUM(II) DICHLORIDE
  • PALLADIUM(II) CHLORIDE 1,4-BIS(DIPHENYLPHOSPHINO)BUTANE COMPLEX
  • Bisdiphenylphosphinobutanepalladiumdichloride
  • PDCL2(DPPB)/ 1,4-BIS(DIPHENYLPHOSPHINE)BUTANE PALLADIUM(II)CHLORIDE
  • Palladium(II)chloride-1,4-bis(diphenylphosphine)butane
  • Dichloro 1,4-bis(diphenylphosphino)butane palladium (II) For use in coupling reactions
  • Dichloro-1,4-bis(diphenylphosphino)butane-palladium(II),PdCl2(DPPB)
  • [1,4-bis(diphenylphosphino)butane] palladium(ll) dichloride
  • [1,4-Bis(diphenylphosphino) butane]dichloropalladium(II)
  • PdCl2(dppb) / dichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane
  • 4-diphenylphosphiniumylbutyl(diphenyl)phosphonium
  • Dichloro[bis(1,4-diphenylphosphino)butane]palladium(II)
  • [1,4-Bis(diphenylphosphino)butane]palladium(II) Dichloride >
  • [1,4-Bis(diphenylphosphino)butane]dichloropalladium(Ⅱ)
  • [1,4-bis(diphenylphosphino)butane] palladium(II)
  • [1,4-Bis(diphenyL
  • adium(II) DichL
  • phosphino)butane]paL
  • 1,4-Bis(diphenylphosphino)butane-palladium(II) chloride ISO 9001:2015 REACH
  • TIANFU-CHEM --1,4-Bis(diphenylphosphino)butane-palladium(II) chloride
  • ichloropalladium,4-diphenylphosphanylbutyl(diphenyl)phosphane
  • 29964-62-3
  • C28H28Cl2P2Pd
  • C28H28Cl2P2Pd2
  • C28H28P2Cl2Pd
  • Homogeneous Pd Catalysts
  • Catalysis and Inorganic Chemistry
  • Homogeneous Catalysts
  • Pd (Palladium) Compounds
  • Metal Complexes
  • Classes of Metal Compounds
  • Catalysts for Organic Synthesis
  • Transition Metal Compounds
  • Pd (Palladium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Metal Compounds
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