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(2-Chlorethoxy)ethen

2-Chloroethyl vinyl ether Struktur
110-75-8
CAS-Nr.
110-75-8
Bezeichnung:
(2-Chlorethoxy)ethen
Englisch Name:
2-Chloroethyl vinyl ether
Synonyma:
Vinyl choride;JACS-110-75-8;rcrawastenumberu042;2-chloroethoxy-ethen;Vinyl(2-chloroethyl)e;Rcra waste number U042;(2-chloroethoxy)-ethen;2-chlorethylvinylether;2-(CHLOROETHOXY) ETHENE;ether,2-chlorethylvinyl
CBNumber:
CB5852819
Summenformel:
C4H7ClO
Molgewicht:
106.55
MOL-Datei:
110-75-8.mol

(2-Chlorethoxy)ethen Eigenschaften

Schmelzpunkt:
-70 °C
Siedepunkt:
109 °C (lit.)
Dichte
1.048 g/mL at 25 °C (lit.)
Dampfdruck
760 mm Hg ( 109 °C)
Brechungsindex
n20/D 1.438(lit.)
Flammpunkt:
61 °F
storage temp. 
2-8°C
L?slichkeit
Soluble in ethanol and ether (Weast, 1986)
Aggregatzustand
Liquid
Farbe
Clear colorless to light yellow
Wasserl?slichkeit
Slightly soluble in water
Merck 
14,2139
BRN 
773787
Henry's Law Constant
2.5 (x 10-4 atm?m3/mol)(Pankow and Rosen, 1988)
Expositionsgrenzwerte
No exposure limit is set for this compound.
CAS Datenbank
110-75-8(CAS DataBase Reference)
NIST chemische Informationen
Ethene, (2-chloroethoxy)-(110-75-8)
EPA chemische Informationen
2-Chloroethyl vinyl ether (110-75-8)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher F,Xn,T
R-S?tze: 11-22-36/37/38-39/23/24/25-23/24/25-41-20/22
S-S?tze: 26-36-45-36/37-16-7-37/39
RIDADR  UN 1992 3/PG 2
WGK Germany  3
RTECS-Nr. KN6300000
HazardClass  3.2
PackingGroup  III
HS Code  29091990
Giftige Stoffe Daten 110-75-8(Hazardous Substances Data)
Toxizit?t Acute oral LD50 for rats 250 mg/kg (quoted, RTECS, 1985).
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H225 Flüssigkeit und Dampf leicht entzündbar. Entzündbare Flüssigkeiten Kategorie 2 Achtung GHS hazard pictogramssrc="/GHS02.jpg" width="20" height="20" /> P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H301 Giftig bei Verschlucken. Akute Toxizit?t oral Kategorie 3 Achtung GHS hazard pictogramssrc="/GHS06.jpg" width="20" height="20" /> P264, P270, P301+P310, P321, P330,P405, P501
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P210 Von Hitze, hei?en Oberfl?chen, Funken, offenen Flammen und anderen Zündquellenarten fernhalten. Nicht rauchen.
P233 Beh?lter dicht verschlossen halten.
P240 Beh?lter und zu befüllende Anlage erden.
P301+P310 BEI VERSCHLUCKEN: Sofort GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen.
P303+P361+P353 BEI BERüHRUNG MIT DER HAUT (oder dem Haar): Alle kontaminierten Kleidungsstücke sofort ausziehen. Haut mit Wasser abwaschen oder duschen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

(2-Chlorethoxy)ethen Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R11:Leichtentzündlich.
R22:Gesundheitssch?dlich beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R39/23/24/25:Giftig: ernste Gefahr irreversiblen Schadens durch Einatmen, Berührung mit der Haut und durch Verschlucken.
R23/24/25:Giftig beim Einatmen, Verschlucken und Berührung mit der Haut.
R41:Gefahr ernster Augensch?den.
R20/22:Gesundheitssch?dlich beim Einatmen und Verschlucken.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S16:Von Zündquellen fernhalten - Nicht rauchen.
S7:Beh?lter dicht geschlossen halten.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.

Chemische Eigenschaften

2-Chloroethyl vinyl ether is a highly flammable, colorless liquid.

Verwenden

2-Chloroethyl vinyl ether is used to producesedatives, anesthetics, and cellulose ethers.

Allgemeine Beschreibung

Liquid boiling at 209°C. Density 1.048 g / cm3 and insoluble in water. Hence sinks in water. Flash point 142°F. Toxic.

Air & Water Reaktionen

Flammable. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. Insoluble in water.

Reaktivit?t anzeigen

2-Chloroethyl vinyl ether forms salts with strong acids and addition complexes with Lewis acids. May react violently with strong oxidizing agents. Typically stabilized against polyermizable by addition of triethanolamine.

Hazard

Moderate fire risk. Combustible.

Health Hazard

2-Chloroethyl vinyl ether is moderately toxicto humans by inhalation and ingestion. Expo sure to its vapors can produce irritation of theeyes, nose, and lungs. Rats exposed to itsvapors at 250 ppm concentration in air died4 hours after exposure. Pure liquid is an irri tant to the skin. The liquid may be absorbedthrough the skin. The dermal toxicity, how ever, is very low
LD50 value, oral (rats): 250 mg/kg
The carcinogenicity of this compoundis not documented. However, drawing a similarity with other low aliphatic haloethers,this compound at high dosage may exhibitcarcinogenicity to animals.

Brandgefahr

Highly flammable.

Sicherheitsprofil

Poison by ingestion. Moderately toxic by inhalation and skin contact. A severe eye and skin irritant. See also ETHERS. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Potentially explosive. May form dangerous peroxides on exposure to air. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORIDES and ETHERS.

m?gliche Exposition

2-Chloroethyl vinyl ether is used in the manufacture of anesthetics, sedatives, and cellulose ethers. The number of potentially exposed individuals is greatest for the following areas: fabricated metal products; wholesale trade; leather, rubber and plastic; and chemical products.

Environmental Fate

Biological. When 2-chloroethyl vinyl ether was statically incubated in the dark at 25 °C with yeast extract and settled domestic wastewater inoculum, significant biodegradation with rapid adaptation was observed. At concentrations of 5 and 10 mg/L, complete degradation was observed after 21 d (Tabak et al., 1981).
Chemical/Physical. Chlorination of 2-chloroethyl vinyl ether to α-chloroethyl ethyl ether or β-chloroethyl ethyl ether may occur in water treatment facilities. The alpha compound is very unstable in water and decomposes almost as fast as it is formed (Summers, 1955). Although stable in NaOH solutions, in dilute acid solutions hydrolysis yields acetaldehyde and chlorohydrin (Windholz et al., 1983). At pH 7 and 25 °C, the hydrolysis half-life is 175 d (Jones and Wood, 1964).
At influent concentrations of 10.0, 1.0, 0.1, and 0.01 mg/L, the GAC adsorption capacities at pH 5.4 were 25, 3.9, 0.6, and 0.1 mg/g, respectively (Dobbs and Cohen, 1980).

Versand/Shipping

UN1992 Flammable liquids, toxic, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, 6.1-Poisonous materials, Technical Name Required.

l?uterung methode

Wash the ether repeatedly with equal volumes of water made slightly alkaline with KOH, dry with sodium, and distil it under vacuum. Stabilise it with ~0.01% of triethanolamine. [Beilstein 1 IV 2051.] TOXIC.

Inkompatibilit?ten

Peroxidizable Compound; may form unstable peroxides that can cause explosive polymerization. Stabilizer: 300 ppm triethanolamine and 50 ppm MEHQ (monomethyl ether of hydroquinone). 2-Chloroethyl vinyl ether forms explosive mixture with air. May accumulate static electrical charges, and may cause ignition of its vapors. Contact with oxidizing materials may cause fire or explosion hazard. Stabilizer: 300 ppm triethanolamine & 50 ppm MEHQ (monomethyl ether of hydroquinone).

Waste disposal

Residues may be packaged in epoxy-lined drums and disposed of by high temperature incineration with HCl scrubbing of effluent gases.

(2-Chlorethoxy)ethen Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


(2-Chlorethoxy)ethen Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 120)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806
sales@capot.com China 29791 60
Hubei xin bonus chemical co. LTD
86-13657291602
linda@hubeijusheng.com CHINA 22963 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 49374 58
career henan chemical co
+86-0371-86658258 +8613203830695
factory@coreychem.com China 29810 58
Shaanxi Didu New Materials Co. Ltd
+86-89586680 +86-13289823923
1026@dideu.com China 8670 58
Aladdin Scientific
+1-+1(833)-552-7181
sales@aladdinsci.com United States 57505 58
Qingdao Dexin Chemical Co., Ltd
+86-15553333686 +86-15553333686
15553333686@qq.com China 1662 58
Qingdao RENAS Polymer Material Co., Ltd.
+86-0532-86867058 +86-18562606086
sales@qdrenas.com China 476 58
Mainchem Co., Ltd. +86-0592-6210733
sale@mainchem.com China 32343 55
TCI (Shanghai) Development Co., Ltd. 021-67121386
Sales-CN@TCIchemicals.com China 24529 81

110-75-8((2-Chlorethoxy)ethen)Verwandte Suche:


  • (2-Chlorethyl)vinyl ether
  • ether,2-chlorethylvinyl
  • ether,2-chloroethylvinyl
  • Rcra waste number U042
  • rcrawastenumberu042
  • Vinyl beta-chloroethyl ether
  • vinylbeta-chloroethylether
  • LIQUID COMPONENTS, EPA 601
  • 2-(CHLOROETHOXY) ETHENE
  • 2-CHLOROETHYL VINYL ETHER
  • 2-Chloroethyl vinyl ether 99%, contains 300 ppm triethanolamine as stabilizer, 50 ppm MEHQ as stabilizer
  • 2-Chloroethyl vinyl ether 99%, contains triethanolamine as stabilizer, contains MEHQ as stabilizer
  • VINYL 2-CHLOROETHYL ETHER
  • 2-CHLOROETHYL VINYL ETHER, 100MG, NEAT
  • 2-CHLOROETHYL VINYL ETHER, 1X1ML, MEOH 5 000UG/ML
  • 2-CHLOROETHYL VINYL ETHER, STAB.
  • 2-CHLOROETHYL VINYL ETHER, 5000MG, NEAT
  • 2-CHLOROETHYL VINYL ETHER, 1X1ML, MEOH, 200UG/ML
  • (2-chloroethoxy)-ethen
  • 1-(2-Chloroethoxy)ethylene
  • 2-chlorethylvinylether
  • 2-chloroethoxy-ethen
  • 2-Vinyloxyethyl chloride
  • 2-vinyloxyethylchloride
  • beta-Chloroethyl vinyl ether
  • ethene,(2-chloroethoxy-
  • ethene,(2-chloroethoxy)-
  • Ether, 2-chloroethyl vinyl
  • Vinyl choride
  • 2-Chloroethyl Vinyl Ether (stabilized with MEHQ + Triethanolamine)
  • Chloroethyl vinyl ether, 2-: (Ethene, 2-chloroethoxy-)
  • 2-Chloroethyl vinyl ether, ca. 95%
  • 2-Chloroethylvinylether,>97%
  • 2-chloroethyl vinyl ether solution
  • (2-Chloroethoxy)ethylene
  • 1-(Ethenyloxy)-2-chloroethane
  • 3-Chloroethyl vinyl ether
  • 2-Chloroethyl Viny1 Ether
  • 2-Chloroethyl vinyl ether 5g [110-75-8]
  • (stabilized with MEHQ + TriethanolaMine)
  • 2-Chloroethyl Vinyl Ether 
  • Vinyl(2-chloroethyl)e
  • JACS-110-75-8
  • 2-ChloroethylVinylEther(stabilizedwithMEHQ+Triethanolamine)>
  • C11410400 2-Chloroethyl-vinyLether
  • 2-Chloroethylvinyl ether in Methanol
  • Nicotinamide Impurity 258
  • 110-75-8
  • 75-01-0
  • 1975/1/4
  • 27398
  • Others
  • Protection and Derivatization
  • Protecting and Derivatizing Reagents
  • Synthetic Reagents
  • HALOGEN
  • Intermediates of Dyes and Pigments
  • CHEPA
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