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CERIUM(III) CHLORIDE HEPTAHYDRATE

CERIUM(III) CHLORIDE HEPTAHYDRATE Struktur
18618-55-8
CAS-Nr.
18618-55-8
Englisch Name:
CERIUM(III) CHLORIDE HEPTAHYDRATE
Synonyma:
CERIUM CHLORIDE HEPTAHYDRATE;CEROUS CHLORIDE HEPTAHYDRATE;oride heptahydrate;Ceriumchloridehydrate;CERIUM CHLORIDE (CERIC);3/5000 Cerium chloride;Cerium(III) chloride 99,5%;CERIUM (III) CHLORIDE 7 H2O;CERIUM(III) CHLORIDE HYDRATE;CeriuM(III)chlorideheptahydra
CBNumber:
CB5378887
Summenformel:
CeCl3H14O7
Molgewicht:
372.58
MOL-Datei:
18618-55-8.mol

CERIUM(III) CHLORIDE HEPTAHYDRATE Eigenschaften

Schmelzpunkt:
848 °C
Dichte
~3.94 g/mL at 25 °C(lit.)
storage temp. 
Inert atmosphere,Room Temperature
L?slichkeit
very soluble in H2O, ethanol
Aggregatzustand
Crystals or Crystalline Powder
Farbe
Light yellow
Odor Threshold
Stinging odor
Wasserl?slichkeit
Soluble in alcohol, water, and acetone. Slightly soluble in tetrahydrofuran.
Sensitive 
Hygroscopic
Merck 
14,1997
Stabilit?t:
Stable, but may be moisture sensitive. Incompatible with strong acids, strong oxidizing agents.
InChI
InChI=1S/Ce.3ClH.7H2O/h;3*1H;7*1H2/q+3;;;;;;;;;;/p-3
InChIKey
KPZSTOVTJYRDIO-UHFFFAOYSA-K
SMILES
[Ce](Cl)(Cl)Cl.O.O.O.O.O.O.O
CAS Datenbank
18618-55-8(CAS DataBase Reference)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xi
R-S?tze: 36/37/38
S-S?tze: 26-36
RIDADR  UN 3260 8 / PGIII
WGK Germany  3
RTECS-Nr. FK5100000
3-10-21
Selbstentzündungstemperatur 400°C
TSCA  Yes
HS Code  28461090
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H314 Verursacht schwere Ver?tzungen der Haut und schwere Augensch?den. ?tzwirkung auf die Haut Kategorie 1B Achtung GHS hazard pictogramssrc="/GHS05.jpg" width="20" height="20" /> P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS09.jpg" width="20" height="20" /> P273, P391, P501
Sicherheit
P260 Dampf/Aerosol/Nebel nicht einatmen.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P303+P361+P353 BEI BERüHRUNG MIT DER HAUT (oder dem Haar): Alle kontaminierten Kleidungsstücke sofort ausziehen. Haut mit Wasser abwaschen oder duschen.

CERIUM(III) CHLORIDE HEPTAHYDRATE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-S?tze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.

Chemische Eigenschaften

colourless crystalline solid

Verwenden

Cerium(III) chloride heptahydrate can be used in the conversion of esters to allylsilanes.

Application

Cerium(III) chloride heptahydrate can be used:
As a precursor to prepare cerium oxide nanoparticles for biomedical applications and photocatalytic degradation.
As a solution to fabricate thin films of CeO2 on glass substrates by the spray pyrolysis process.
As a dopant to fabricate ZnO and CeO2 nanocrystals for electrochemical sensing of H2O2 and photocatalytic degradation of Rhodamine B and Congo red dyes.
As an additive to prepare corrosion-inhibiting formulations and coatings.
To synthesize carbon nanofiber composites to fabricate high-temperature polymer electrolyte membrane fuel cell cathodes.
As a support for the combination of cerium(III)chloride heptahydrate and sodium iodide supported on silica gel to promoteMichael-type additions. These catalysts are used to convert from indolesand nitroalkenes to 2-indolyl-1-nitroalkane derivatives in good yields.

Allgemeine Beschreibung

Cerium(III) chloride heptahydrate is a mild Lewis acid. It participates in the allylation of aldehydes. Cerium(III) chloride heptahydrate in combination with sodium iodide supported on silica gel efficiently promotes Michael-type addition. Cerium(III) chloride heptahydrate in the presence of sodium iodide acts as an efficient catalyst for the Michael addition of 1,3-dicarbonyl compounds to α,β-unsaturated ketones and α,β-unsaturated aldehydes.

CERIUM(III) CHLORIDE HEPTAHYDRATE Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


CERIUM(III) CHLORIDE HEPTAHYDRATE Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 273)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
CHENGDU BEYOND CHEMICAL CO.,LTD.
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18871490254
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18618-55-8()Verwandte Suche:


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  • 18618-55-8
  • CeCl37H2O
  • H14O7CeCl3
  • H14CeCl3O7
  • Catalysis and Inorganic Chemistry
  • Cerium
  • Rare-Earth Metals
  • Catalysis and Inorganic Chemistry
  • Ce
  • Cerium
  • Isoquinolines ,Quinolines ,Indolines ,Quinaldines
  • Cerium Salts
  • Chemical Synthesis
  • Materials Science
  • Metal and Ceramic Science
  • Salts
  • Ultra-High Purity Materials
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