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Naphthalin-2,7-disulfonsure

Naphthalene-2,7-disulfonic acid Struktur
92-41-1
CAS-Nr.
92-41-1
Bezeichnung:
Naphthalin-2,7-disulfonsure
Englisch Name:
Naphthalene-2,7-disulfonic acid
Synonyma:
Ebert-Merz α-acid;naphthalene-2,7-disulfonicaci;3,6-Naphthalenedisulfonic acid;2,7-NAPHTHALENE DISULFONIC ACID;naphthalene-2,7-disulfonic acid;naphthalene-2,7-disulphonic acid
CBNumber:
CB5297140
Summenformel:
C10H8O6S2
Molgewicht:
288.3
MOL-Datei:
92-41-1.mol

Naphthalin-2,7-disulfonsure Eigenschaften

Schmelzpunkt:
199°C
Siedepunkt:
400.53°C (rough estimate)
Dichte
1.6867 (rough estimate)
Brechungsindex
1.6950 (estimate)
storage temp. 
2-8°C
pka
-0.33±0.40(Predicted)
CAS Datenbank
92-41-1(CAS DataBase Reference)
EPA chemische Informationen
2,7-Naphthalenedisulfonic acid (92-41-1)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
RIDADR  1759
HazardClass  8
PackingGroup  III
HS Code  2904100090
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H314 Verursacht schwere Ver?tzungen der Haut und schwere Augensch?den. ?tzwirkung auf die Haut Kategorie 1B Achtung GHS hazard pictogramssrc="/GHS05.jpg" width="20" height="20" /> P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Sicherheit
P260 Dampf/Aerosol/Nebel nicht einatmen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P310 Sofort GIFTINFORMATIONSZENTRUM/Arzt/ anrufen.

Naphthalin-2,7-disulfonsure Chemische Eigenschaften,Einsatz,Produktion Methoden

Chemische Eigenschaften

White, crystalline solid.Soluble in water. Combustible. Naphthalene-2,7-disulfonic acid [92- 41-1]. C10H8O6S2, Mr 288.28; the sodium salt of Naphthalene-2,7-disulfonic acid is much more soluble than that of the 2,6- isomer but can be isolated and purified by precipitation of the calcium salt at lower temperature followed by recrystallization.

Verwenden

Intermediate for dyes. The disodium salt of 8 gives 2-hydroxynaphthalene-7-sulfonic acid or 2,7-dihydroxynaphthalene by fusion processes. Sulfonation by oleum gives the 1,3,6-trisulfonic acid, and nitration gives 1-nitronaphthalene-3,6- disulfonic acid. In sulfuric acid solution, the disodium salt of naphthalene-2,7-disulfonic acid undergoes an unusual reaction at the 4-position with 4,40 -bis- (dimethylamino)benzhydrol. The resulting condensation product is oxidized with lead dioxide to give the acid basic dye C.I. Acid Green 16.

Definition

ChEBI: A naphthalenesulfonic acid in which the sulfo groups are attached to positions 2 and 7 of the naphthalene ring.

l?uterung methode

Crystallise the acid from conc HCl. The disulfonamide has m 273o (from EtOH). [Beilstein 11 II 119, 11 III 463.]

Naphthalin-2,7-disulfonsure Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


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