BrettPhosPalladacycle
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- CAS-Nr.
- 1148148-01-9
- Englisch Name:
- BrettPhosPalladacycle
- Synonyma:
- BrettPhos Pd G1;BrettPhos precatalyst;BrettPhos Palladacycle;BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct;BrettPhos Pd G1 MTBE adduct;BrettPhos Palladacycle Gen. 1;chloro-(2-phenylethylamino)palladium;[2-(2-aminoethyl)phenyl]palladium(1+);(BrettPhos) palladium(II) phenethylamine chloride;Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-...
- CBNumber:
- CB52614378
- Summenformel:
- C43H63ClNO2PPd
- Molgewicht:
- 798.83
- MOL-Datei:
- 1148148-01-9.mol
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BrettPhosPalladacycle Eigenschaften
- Schmelzpunkt:
- 198-204 °C
- Aggregatzustand
- Powder
- Farbe
- white
BrettPhosPalladacycle Chemische Eigenschaften,Einsatz,Produktion Methoden
Verwenden
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsCatalyst for:
- C,N-cross coupling of unprotected 3-halo-2-aminopyridines with primary and secondary amines
- Amination reaction
- N-arylation of aminophenols
Allgemeine Beschreibung
BrettPhos Pd G1 is a Buchwald first generation (G1) palladacycle precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. The formation of the active Pd(0) species in the G1 precatalyst is easy to generate, requiring merely a deprotonation with a base. The resulting catalyst is very active, even at temperatures down to ?40 °C, and can be used in a variety of cross-coupling protocols.
BrettPhosPalladacycle Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
BrettPhosPalladacycle Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 89)Lieferanten
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)
- Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II),98%
- Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II), Min. 98% [BrettPhos Palladacycle]
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoeth
- Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-Minoethyl)phenyl]palladiuM(II),Min.98%[BrettPhosPalladacycle]
- (BrettPhos) palladium(II) phenethylamine chloride
- Dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine-(2-(2-aminoethyl)phenyl)palladium(II) chloride
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(ii)
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-amino
- CHLORO[2-(DICYCLOHEXYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL][2-(2-AMINOETHYL)PHENYL]PALLADIUM(II),MIN.98%[BRETTPHOSPALLADACYCLEGEN.1]
- BrettPhos Palladacycle Gen. 1
- Chloride (2-dicyclohexylphosphino-3,6-dimethoxy-2 ', 4', 6 '- triisopropyl-1,1' - biphenyl) [2 - (2-aminoethyl phenyl)] palladium (II)
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II) /
BrettPhos Pd G1
- Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP]-, (SP-4-4)-
- Chloro[2-(dicyclohexylphosphino)-2',4',6'-triisopropyl-3,6-dimethoxybiphenyl][2-(2-aminoethyl)phenyl]palladium(II)
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-...
- BrettPhos Pd G1 / Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)
- (SP-4-4)-[2-[2-(Amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP]palladium
- Chloro[2-(dicyclohexylphosphino)-3,6-diMethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aMinoethyl)phenyl]palladiuM(II) [BrettPhos Palladacycle]
- [2-(2-aminoethyl)phenyl]palladium(1+)
- dicyclohexyl-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane
- BrettPhos Pd G1 Methyl-t-Butyl Ether Adduct
- BrettPhos Palladacycle
- BrettPhos precatalyst
- BrettPhos Pd G1
- Dicyclohexyl(2',4',6'-triisopropyl-3,6-dimethoxy-[1,1'-biphenyl]-2-yl)phosphine-(2-(2-aminoethyl)phenyl)palladium(II) chloride
- chloro-(2-phenylethylamino)palladium
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)
- Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)
- BrettPhos Pd G1 MTBE adduct
- Chloro[2-(dicyclohexylphosphino)-2’,4’,6’-triisopropyl-3,6-dimethoxybiphenyl][2-(2-aminoethyl)phenyl]palladium(II)
- Palladium, [2-[2-(amino-κN)ethyl]phenyl-κC]chloro[dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP]-, (SP-4-4)-
- 1148148-01-9
- C43H63ClNO2PPd
- C48H74ClNO3PPd
- Buchwald Ligands&Precatalysts
- Buchwald Precatalysts Series
- Pd