Methane sulfonyl azide Chemische Eigenschaften,Einsatz,Produktion Methoden
Verwenden
Methane sulfonyl azide is used as a diazo transfer reagent for activated methylene,
[1] methine,
[1,2] and methyl
[3] groups; functionalization of double
and triple bonds.
synthetische
Preparative Methods of Methane sulfonyl azide: reaction of Methanesulfonyl Chloride with Sodium Azide in MeOH(EtOH)/H2O
[1,3] or
acetone
[2] (55-61 or 96% yields, respectively). By substituting acetone for methanol, the formation of
MeSO2OMe is avoided and the reagent is obtained in >95% purity.
Methane sulfonyl azide Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte