N,N'-Ethylenbis[N-acetylacetamid]
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- CAS-Nr.
- 10543-57-4
- Bezeichnung:
- N,N'-Ethylenbis[N-acetylacetamid]
- Englisch Name:
- Tetraacetylethylenediamine
- Synonyma:
- TAED;TEAD;TAEG;Nikon A;Mykon ATC;Mikon ATC;TETRAACETYLENEDIAMINE;TETRACETYLETHYLENEDIAMINE;TETRAACETYLETHYLENEDIAMINE;1,2-Bis(diacetylamino)ethane
- CBNumber:
- CB4401238
- Summenformel:
- C10H16N2O4
- Molgewicht:
- 228.24
- MOL-Datei:
- 10543-57-4.mol
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N,N'-Ethylenbis[N-acetylacetamid] Eigenschaften
- Schmelzpunkt:
- 149-154 °C
- Siedepunkt:
- 140 °C (1.5002 mmHg)
- Dichte
- 0.9
- Brechungsindex
- 1.4550 (estimate)
- Flammpunkt:
- 140 °C
- Aggregatzustand
- Granular Powder
- pka
- -1.23±0.70(Predicted)
- Farbe
- Off-white to beige
- Wasserl?slichkeit
- slightly soluble
- Merck
- 14,9028
- BRN
- 1795711
- InChIKey
- BGRWYDHXPHLNKA-UHFFFAOYSA-N
- CAS Datenbank
- 10543-57-4(CAS DataBase Reference)
- NIST chemische Informationen
- EPA chemische Informationen
- Tetraacetylethylenediamine (10543-57-4)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
S-S?tze: |
22-24/25 |
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WGK Germany |
1 |
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TSCA |
Yes |
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HS Code |
29241900 |
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Bildanzeige (GHS) |
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Alarmwort |
Warnung |
Gefahrenhinweise |
Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P302+P352, P321,P332+P313, P362 |
H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P305+P351+P338,P337+P313P |
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Sicherheit |
P264 |
Nach Gebrauch gründlich waschen. |
P264 |
Nach Gebrauch gründlich waschen. |
P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
P302+P352 |
BEI BERüHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckm??ig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen. |
P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen. |
P332+P313 |
Bei Hautreizung: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen. |
P337+P313 |
Bei anhaltender Augenreizung: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen. |
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N,N'-Ethylenbis[N-acetylacetamid] Chemische Eigenschaften,Einsatz,Produktion Methoden
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
Tetraacetylethylenediamine is off-white to beige granular powder
Verwenden
Tetraacetylethylenediamine (TAED) is a bleaching activator which is mainly used in detergents and additives for laundry washing and dishwashing. Typical concentrations of TAED range between 1.4% and 13% in these products. A small amount of the produced TAED is also used in bleaching of paper, textiles and for the generation of Peracetic acid.
Peroxide bleach activator for household detergents, paper pulp.
synthetische
Tetraacetylethylenediamine (TAED) is produced in a two stage process from ethylenediamine (ED) and acetic anhydride (Ac2O). ED is first diacetylated to DAED. In the second step DAED is subsequently converted with Ac2O via TriAED into TAED (Clariant, 1999). TAED is crystallized out of the reaction mixture, filtered, washed and dried, and if necessary also granulated. The raw materials used occur almost quantitatively in the product. Byproducts are not formed.
TAED was prepared by acetylation of diacetylethylenediamine (DAED) with acetic anhydride in a 5 L reactor coupled with a packed distillation column, 2.5 cm in inside diameter and 1 m in length. The reaction temperature was set at 135 °C and the reflux ratio at 6. The molar ratio of acetic anhydride to DAED was varied from 3 to 5. A TAED yield as high as 80% was obtained, higher by 15% than in the absence of distillation.
Health Hazard
TAED is of very low toxicity by all exposure routes examined. Up to 2 g/kg BW there is no acute toxicity. TAED is practically non-irritating to skin and eyes and there is no evidence of a sensitizing potential by skin contact. The only effect after repeated oral and dermal dosing was reversible centrilobular hypertrophy in the liver at high doses due to the induction of metabolizing enzymes. In a 90-day whole body inhalation study no adverse effects in the rat lung, respiratory tract or nasal mucosa were observed. Biokinetic data showed that TAED is rapidly absorbed from the rat intestine and largely metabolized via diacetylation to TriAED and DAED which are excreted in the urine.
N,N'-Ethylenbis[N-acetylacetamid] Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
N,N'-Ethylenbis[N-acetylacetamid] Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 357)Lieferanten
10543-57-4(N,N'-Ethylenbis[N-acetylacetamid])Verwandte Suche:
N,N,N',N'-Tetramethylethylendiamin
4,5-Dichlor-3,6-dioxocyclohexa-1,4-dien-1,2-dicarbonitril
Tetrakis(triphenylphosphin)palladium
Tetraoctylammoniumbromid
Dinatriumcarbonat, Verbindung mitHydrogenperoxid (2:3)
1,1',1'',1'''-Ethylendinitrilotetrapropan-2-ol
N-2-Aminoethyl-1-naphthylamindihydrochlorid
Lysergid
1,2-Diaminoethan
Natriumferedetat
N,N'-Ethylenbis(3,4,5,6-tetrabromphthalimid)
N,N'-Ethylenbis[N-acetylacetamid]
N,N'-Ethylenbis(3,4,5,6-tetrachlorphthalimid)
- n,n’-1,2-ethanediylbis[n-acetyl-acetamid
- N,N’-1,2-ethanediylbis[N-acetyl-Acetamide
- N,N’-1,2-ethanediylbis[N-acetylacetamide]
- N,N’-ethylenebis[N-acetylacetamide]
- N-Acetyl-N-[2-(diacetylamino)ethyl]acetamide
- TetraAcetylEthyleneDiamine(Taed)
- Mykon ATC
- Nikon A
- 1,2-Bis(diacetylamino)ethane
- Tetraacetylethylenediamine,90%
- Tetraacetylethylenediamine,99.5+%
- TETRAACETYLENEDIAMINE
- N,N'-Ethylenbis-(N-acetylacetamid)
- 1,2-Bis-(diacetamido)-ethane
- N,N'-(ethane-1,2-diyl)bis(N-acetylacetaMide)
- N,N,N',N'-Tetraacetylethylenediamine technical, >=90% (CHN)
- N,N,N',N'-Tetraacetylethylenediamine≥ 90% (HPLC)
- TETRACETYLETHYLENEDIAMINE
- TETRAACETYLETHYLENEDIAMINE
- N,N'-ETHYLENEBIS(DIACETAMIDE)
- N,N,N',N'-TETRAACETYLETHYLENEDIAMINE
- Acetamide, N,N'-1,2-ethanediylbis[N-acetyl-
- TAED Tetraacetylethylenediamine
- Tetraacetylethylenediamine ISO 9001:2015 REACH
- Mikon ATC
- Detergents Tetraacetylethylenediamine
- TEAD
- TAED
- TAEG
- N,N,N',N'-Tetraacetylethylenediamine
- N,N'-(Ethane-1,2-diyl)bis(N-acetylacetamide)
- N,N'-ethylenebis[N-acetylacetamide]
- 10543-57-4
- C10H16O4N2
- Nitrogen Compounds
- Organic Building Blocks
- Protected Amines
- Building Blocks
- Daily Chemical Usage
- bc0001