(Ethylenbis(nitrilomethylidyn)-2,2'-diphenolato)cobalt(II)
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- CAS-Nr.
- 14167-18-1
- Bezeichnung:
- (Ethylenbis(nitrilomethylidyn)-2,2'-diphenolato)cobalt(II)
- Englisch Name:
- SALCOMINE
- Synonyma:
- o’)-o;SALEN-CO;Salcomin;Nsc32965;(sp-4-2)-;SALCOMINE;N,N&priMe;Co(salen);CO(SALEN)2;salcomin[qr]
- CBNumber:
- CB4223164
- Summenformel:
- C16H14CoN2O2
- Molgewicht:
- 325.23
- MOL-Datei:
- 14167-18-1.mol
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(Ethylenbis(nitrilomethylidyn)-2,2'-diphenolato)cobalt(II) Eigenschaften
- Schmelzpunkt:
- >300 °C
- storage temp.
- Inert atmosphere,Room Temperature
- Aggregatzustand
- Powder
- Farbe
- Orange to Amber to Dark red
- Wasserl?slichkeit
- Insoluble in water. Soluble in benzene, chloroform, and pyridine.
- Stabilit?t:
- Stable. Incompatible with strong acids, strong oxidizing agents.
- EPA chemische Informationen
- Salcomine (14167-18-1)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher |
Xi |
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R-S?tze: |
36/37/38 |
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S-S?tze: |
26-36 |
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WGK Germany |
2 |
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RTECS-Nr. |
GG0590000 |
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F |
10 |
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TSCA |
Yes |
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HS Code |
29349990 |
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Giftige Stoffe Daten |
14167-18-1(Hazardous Substances Data) |
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Toxizit?t |
mouse,LCLo,inhalation,390mg/m3/5.5H (390mg/m3),LUNGS, THORAX, OR RESPIRATION: STRUCTURAL OR FUNCTIONAL CHANGE IN TRACHEA OR BRONCHILUNGS, THORAX, OR RESPIRATION: OTHER CHANGESLUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA,Aerospace Medical Research Laboratory Report. Vol. TR-74-78, Pg. 1974, |
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Bildanzeige (GHS) |
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Alarmwort |
Warnung |
Gefahrenhinweise |
Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P302+P352, P321,P332+P313, P362 |
H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P305+P351+P338,P337+P313P |
H335 |
Kann die Atemwege reizen. |
Spezifische Zielorgan-Toxizit?t (einmalige Exposition) |
Kategorie 3 (Atemwegsreizung) |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
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Sicherheit |
P261 |
Einatmen von Staub vermeiden. |
P264 |
Nach Gebrauch gründlich waschen. |
P264 |
Nach Gebrauch gründlich waschen. |
P271 |
Nur im Freien oder in gut belüfteten R?umen verwenden. |
P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
P302+P352 |
BEI BERüHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckm??ig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen. |
P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen. |
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(Ethylenbis(nitrilomethylidyn)-2,2'-diphenolato)cobalt(II) Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
black crystalline powder
Verwenden
Salcomine catalyzes the oxidation of 2,6-disubstituted phenols by dioxygen. Experimental inhibitor of human cytμloviris proteinase activity. Metal complex dyes used as redox catalysts.
Allgemeine Beschreibung
A solid complex between the cobalt(II) ion and the condensation product of salicylaldehyde and ethylenediamine. Such condensation products are called "Schiff's bases." Complexation with cobalt nullifies their basic properties. Used as a catalyst for various oxidation reactions in which SALCOMINE behaves as an oxygen carrier.
Reaktivit?t anzeigen
SALCOMINE may increase the rate of oxidation reactions such as the conversion of amines to nitro compounds by peroxides or hydroperoxides.
l?uterung methode
The powder should have an oxygen capacity of 4.7-4.8% as measured by the increase in weight under O2 at 100 pounds pressure at ca 20o. The O2 is expelled on heating the material to 65o. It crystallises from pyridine, CHCl3 or *C6H6, and the solvent may be removed by heating at 120o in a vacuum. However, this heating may mean reduced O2 capacity. In the dry state it absorbs O2, turning from a maroon colour to black. [Diehl & Hack Inorg Synth III 196 1950.]
(Ethylenbis(nitrilomethylidyn)-2,2'-diphenolato)cobalt(II) Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(Ethylenbis(nitrilomethylidyn)-2,2'-diphenolato)cobalt(II) Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 134)Lieferanten
14167-18-1((Ethylenbis(nitrilomethylidyn)-2,2'-diphenolato)cobalt(II))Verwandte Suche:
- N,N'-DISALICYLALETHYLENEDIAMINE COBALT(II)
- N,N'-ETHYLENEBIS(SALICYLIDENEIMINATO)COBALT(II)
- SALCOMINE
- SALEN-CO
- ((2,2’-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-n,n-cobal
- ((alpha,alpha’-(ethylenedinitrilo)di-o-cresolato)(2-))-cobal
- (N,N'-Ethylenebis(salicylaldehyde iminato))cobalt(II)
- (N,N'-Ethylenebis(salicylideniminato))cobalt
- (sp-4-2)-
- a13-30876[qr]
- Bis(salicylaldehyde)ethylenediimine cobalt(ii)
- bis(salicylaldehyde)ethylenediiminecobalt(ii)
- Cobalt, ((2,2'-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-N,N',O,O')-
- Cobalt, ((alpha,alpha'-(ethylenedinitrilo)di-o-cresolato)(2-))-
- Cobalt, [[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-, (SP-4-2)-
- Cobalt, N,N'-ethylenebis(salicylideneiminato)-
- cobalt,((2,2’-(1,2-ethanediylbis(nitrilomethylidyne))bis(phenolato))(2-)-n,n
- cobalt,((alpha,alpha’-(ethylenedinitrilo)di-o-cresolato)(2-))-[qr]
- cobalt,[[2,2’-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-n,n’,
- n,n’-bis(salicylidene)ethylenediaminecobalt(ii)salthyd.
- n,n’-bis(salicylidene)ethylenediamino
- n,n’-ethylenebis(salicylideneiminato)-cobal
- N,N'-Ethylenebis(salicylideneiminato)cobalt
- n,n-ethylenebis(salicylideneiminato)cobaltii[qr]
- N,N'-Ethylenebis(salicylideniminato)cobalt(II)
- o,o’)-(sp-4-2)-[qr]
- o’)-o
- Salcomin
- CO(SALEN)2
- Salcomine: (bis(Salicylaldehyde)ethylenediimine cobalt(II))
- N,N'-Bis(salicylidene)ethylenediamine cobalt salt
- Co(SALEN)2, Ethylenebis(salicylimine) cobalt(II) salt, Salcomine, N,Nμ-Disalicylidene-ethylenediamine cobalt(II) salt
- [2,2'-[Ethane-1,2-diylbis(nitrilomethylidene)]diphenolato]cobalt(II)
- [Bis(salicylidene)ethylenediaminato]cobalt
- [Bis(salicylidene)ethylenediamine]cobalt
- [N,N'-Bis(salicylidene)ethane-1,2-diaminato]cobalt(II)
- [N,N'-Bis(salicylidene)ethylenediaminato]cobalt
- [N,N'-Disalicylideneethylenediamine]cobalt
- N,N-BIS(SALICYLIDENE)ETHYLENE-DIIMINOCOBALT (II)
- N,N'-BIS(SALICYLIDENE)ETHYLENEDIIMINOCOBALT(II)
- N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINOCOBALT(II)
- Ethylenebis(salicylimine) cobalt(II) salt
- N,N'-Bis(salicylidene)ethylenediaminecobalt(Ⅱ)
- Salcomine, N,N'-Disalicylidene-ethylenediamine cobalt(II) salt
- N,N'-Bis(salicyliden)ethylenediaminocobalt (ii)
- Nsc32965
- N,N'-Bis(salicylidene)ethylenediiminocobalt(II)
N,N'-Disalicylalethylenediamine Cobalt(II)
N,N'-Ethylenebis(salicylideneiminato)cobalt(II)
- SalcoMine 
- -Bis(salicylidene)ethylenediaMinocobalt(II)
- N,N&priMe
- The twosalicylaldehydeethylenediaMinecobalt
- Co(salen)
- N,N'-Bis(salicylidene)ethylenediaminocobalt(II)
- 2,2'-((1Z,3Z)-2,3-Diaminobuta-1,3-diene-1,4-diyl)diphenol, cobalt salt
- salcomin[qr]
- Salcomine powder
- salcominepowder
- Salicylaldehyde ethylenediimine cobalt