Dikaliumtetrachloroplatinat Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R25:Giftig beim Verschlucken.
R38:Reizt die Haut.
R41:Gefahr ernster Augensch?den.
R42/43:Sensibilisierung durch Einatmen und Hautkontakt m?glich.
S-S?tze Betriebsanweisung:
S22:Staub nicht einatmen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
Chemische Eigenschaften
Red/Brown, Tetragonal Crystals
Verwenden
In photography, in acid toning baths.
Allgemeine Beschreibung
Potassium tetrachloroplatinate(II) is a ruby red crystalline solid and can be prepared by reacting potassium hexachloroplatinate (IV) with cuprous chloride.
Sicherheitsprofil
Human poison by
ingestion. Poison experimentally by
intraperitoneal route. Corrosive to human
skin by intradermal route. Mutation data
reported. Human systemic effects:
eosinophha, gastritis, renal function tests
depressed. When heated to decomposition it
emits toxic fumes of Cland K2O. Used as a
catalyst for hydroformulations,
photocatalysts, and dissociation of water.
See also PLATINUM COMPOUNDS.
Synthese
To a suspension of 9.72g (0.02mol) of potassium hexachloroplatinate(IV) in 100cm3 of water, in a 250cm3 beaker, is added in small portions 1.0g (0.01mol) of hydrazine dihydrochloride. Excess hydrazine dihydrochloride must be avoided to prevent the formation of hydrazine complexes and the reduction of potassium hexachloroplatinate(IV) to platinum when the solution is made basic with ammonia during cisplatin synthesis. The mixture is stirred mechanically while the temperature is raised to 50-65°C over 5-10 minutes. This temperature is maintained for about 2 hours until only a small amount of yellow potassium hexachloroplatinate(IV) remains in the deep red solution. The temperature is then raised to 80-90°C to ensure completion of the reaction, and the mixture is cooled in an ice bath and filtered. The latter is washed with several 10cm3 portions of ice water until the washings are colourless. The washings and deep red filtrate contain pure potassium tetrachloroplatinate(II) and HCl(aq). Half of this solution is used to make the cisplatin.
l?uterung methode
It forms crystals from aqueous 0.75M HCl (20mL/g) between 100o and 0o. Wash them with ice-cold water and dry.
Dikaliumtetrachloroplatinat Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte