stemmadenine Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

First isolated from various species of Stemmadenia, this alkaloid has subsequently been found in DipZorrhynchus rondyZocarpon subsp. mossambiensis Benth. and MeZodinus australis. The following specific rotations have been reported; [α]¹⁹_D + 310° (c 0.527, pyridine), [α]²⁰_D~O + 329° (pyridine) and [α]²⁵_D~S + 324° (pyridine). The alkaloid gives an ultraviolet spectrum exhibiting absorption maxima at 227, 284 and 292 m/J. with shoulders at 275 and 305 m/J.. One nitrogen atom is tertiary, the other being part of the indole ring. The solution in concentrated HN03 is a bright yellow.

Einzelnachweise

Watts, Collera, Sandoval., Tetrahedron, 2, 173 (1958)
Stauffacher., HeZv. Chim. Acta, 44, 2006 (1961)
Sandoval et aZ., Tetrahedron Lett., 409 (1962)
Schumann, Schmid., HeZv. Chim. Acta., 46, 1996 (1963)
Linde., ibid, 48,1822 (1965)

stemmadenine Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

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• stemmadenine
• (15β,19E)-2,7,19,20-Tetradehydro-17-hydroxy-3,7-secocuran-16-carboxylic acid methyl ester
• (19E)-2,7,19,20-Tetradehydro-17-hydroxy-3,7-secocuran-16-carboxylic acid methyl ester
• 15-epi-Stemmadenine
• 1H-3,6-Ethanoazonino[5,4-b]indole-7-carboxylic acid, 5-ethylidene-2,4,5,6,7,8-hexahydro-7-(hydroxymethyl)-, methyl ester, (3S,5E,6S,7S)-
• 10012-73-4