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2'-O-(2-Methoxyethyl)cytidine

2'-O-(2-Methoxyethyl)cytidine Struktur
223777-16-0
CAS-Nr.
223777-16-0
Englisch Name:
2'-O-(2-Methoxyethyl)cytidine
Synonyma:
2'-MOE-C;2'-MOE-rC;2'-O-MOE-rC;2'-O-MOE-Cr;2'-MOE-Cytidine;2'-O-MOE Cytidine;2'-O-MOE Cytidine;2'-O-(2-mthoxyethyl)Cytidine;2'-O-(2-Methoxyethyl)cytidine;2'-O-(2-Methoxyethyl)cytidine
CBNumber:
CB32510559
Summenformel:
C12H19N3O6
Molgewicht:
301.3
MOL-Datei:
223777-16-0.mol

2'-O-(2-Methoxyethyl)cytidine Eigenschaften

Siedepunkt:
535.3±60.0 °C(Predicted)
Dichte
1.57±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
L?slichkeit
DMSO : 250 mg/mL (829.74 mM)
pka
13.36±0.70(Predicted)
Aggregatzustand
Solid
Farbe
White to off-white
InChI
InChI=1S/C12H19N3O6/c1-19-4-5-20-10-9(17)7(6-16)21-11(10)15-3-2-8(13)14-12(15)18/h2-3,7,9-11,16-17H,4-6H2,1H3,(H2,13,14,18)/t7-,9-,10-,11-/m1/s1
InChIKey
YKOGMMXZKKVMBT-QCNRFFRDSA-N
SMILES
OC[C@H]1O[C@@H](N2C=CC(N)=NC2=O)[C@H](OCCOC)[C@@H]1O
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitssch?dlich bei Verschlucken. Akute Toxizit?t oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

2'-O-(2-Methoxyethyl)cytidine Chemische Eigenschaften,Einsatz,Produktion Methoden

Verwenden

A cytidine derivative as building blocks for cross-linking oligonucleotides.

Synthese

2'-O-(2-Methoxyethyl)uridine could be converted into the corresponding cytidine derivative (2'-O-(2-Methoxyethyl)cytidine) by the 4-nitrophenylation[1]. 2'-O-(2-Methoxyethyl)uridine, l-methylpyrrolidine, chlorotrimethylsilane and dry acetonitrile were stirred together at rt. After 1 h, the reaction mixture was cooled to 0 ℃, and trifluoroacetic anhydride was added dropwise over 5 min. After a further period of 30 rain at 0 ℃, 4-nitrophenol was added to the stirred reactants which were maintained at 0 °C. After 3 h, the products were poured into saturated aqueous sodium hydrogen carbonate, and the resulting mixture was extracted with dichloromethane. The combined organic layers were dried, and evaporated under reduced pressure. Concentrated aqueous ammonia was added to a stirred solution of the residue in dioxane, contained in a sealed flask that was then heated at 55°C for 24 h. The resulting yellow solution was concentrated under reduced pressure and the residue was evaporated with absolute ethanol. The products were fractionated by short column chromatography on silica gel and were evaporated under reduced pressure to give 2'-O-(2-Methoxyethyl)cytidine as an off-white solid.
2'-O-(2-Methoxyethyl)cytidine

2'-O-(2-Methoxyethyl)cytidine Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


2'-O-(2-Methoxyethyl)cytidine Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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  • 2'-O-(2-Methoxyethyl)cytidine
  • 2'-O-MOE Cytidine
  • 4-AMINO-1-[(2R,3R,4R,5R)-4-HYDROXY-5-(HYDROXYMETHYL)-3-(2-METHOXYETHOXY)OXOLAN-2-YL]PYRIMIDIN-2-ONE
  • 2'-O-(2-Methoxyethyl)-cytidine, >97%
  • 4-AMINO-1-[4-HYDROXY-5-(HYDROXYMETHYL)-3-(2-METHOXYETHOXY)OXOLAN-2-YL]PYRIMIDIN-2-ONE
  • 4-amino-1-[(2R,3S,4S,5R)-4-hydroxy-5-(hydroxymethyl)-3-(2-methoxyethoxy)tetrahydrofuran-2-yl]pyrimidin-2-one
  • Cytidine, 2'-O-(2-methoxyethyl)-
  • 2'-O-MOE-rC
  • 2'-MOE-Cytidine
  • 2'-O-MOE-Cr
  • 2'-MOE-rC
  • 2'-MOE-C
  • 4-amino-1-[(2R,3R,4R,5R)-4-hydroxy-5-(hydroxymethyl)-3-(2-methoxyethoxy)tetrahydrofuran-2-yl]pyrimidin-2-one
  • 2'-O-(2-mthoxyethyl)Cytidine
  • 2'-O-(2-Methoxyethyl)cytidine
  • 2'-O-MOE Cytidine
  • 223777-16-0
  • Bases & Related Reagents
  • Carbohydrates & Derivatives
  • Heterocycles
  • Nucleotides
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