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1-(Diphenylmethyl)-3-azetidinyl methanesulfonate

1-(Diphenylmethyl)-3-azetidinyl methanesulfonate Struktur
33301-41-6
CAS-Nr.
33301-41-6
Englisch Name:
1-(Diphenylmethyl)-3-azetidinyl methanesulfonate
Synonyma:
1-BENZHYDRYLAZETIDIN-3-YL METHANESULFONATE;BUTTPARK 37\04-14;1-(Diphenylmethyl)-3-(mesyloxy)azetidine;1-BENZHYDRYL-3-METHANESULFONATOAZETIDINE;1-Benzhydryl-3-methanesulphonyloxyazetidine;1-BENZHYDRYL-3-METHANESULFONYLOXY AZETIDINE;1-BENZHYDRYL-3-METHANESULFONATOAZETIDINE 98%;1-Benzhydryl-3-azetidinylMethanesulfonate>1-BENZHYDRYL-3-METHANESULFONATOAZETIDINE CAS;1-DIPHENYLMETHYL-3-AZETIDINYL METHANESULFONATE
CBNumber:
CB3111828
Summenformel:
C17H19NO3S
Molgewicht:
317.4
MOL-Datei:
33301-41-6.mol

1-(Diphenylmethyl)-3-azetidinyl methanesulfonate Eigenschaften

Schmelzpunkt:
111-112°C
Siedepunkt:
459.9±34.0 °C(Predicted)
Dichte
1.28±0.1 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
L?slichkeit
Dichloromethane, Ether, Ethyl Acetate, Methanol
Aggregatzustand
Solid
pka
5.67±0.10(Predicted)
Farbe
White
InChI
InChI=1S/C17H19NO3S/c1-22(19,20)21-16-12-18(13-16)17(14-8-4-2-5-9-14)15-10-6-3-7-11-15/h2-11,16-17H,12-13H2,1H3
InChIKey
MSVZMUILYMLJCF-UHFFFAOYSA-N
SMILES
N1(C(C2=CC=CC=C2)C2=CC=CC=C2)CC(OS(C)(=O)=O)C1
CAS Datenbank
33301-41-6(CAS DataBase Reference)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
S-S?tze: 24/25
HazardClass  IRRITANT
HS Code  29339900
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitssch?dlich bei Verschlucken. Akute Toxizit?t oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P304+P340 BEI EINATMEN: Die Person an die frische Luft bringen und für ungehinderte Atmung sorgen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.
P405 Unter Verschluss aufbewahren.

1-(Diphenylmethyl)-3-azetidinyl methanesulfonate Chemische Eigenschaften,Einsatz,Produktion Methoden

Chemische Eigenschaften

White Crystalline Solid

Verwenden

A proline analog and proline formation inhibitor

Synthese

Preparation procedure of 1-(Diphenylmethyl)-3-azetidinyl methanesulfonate: To a reaction flask was charged 632 g (2.64 mol) of 1-benzhydrylazetidin- 3-ol, acetonitrile (1.9 L), and triethylamine (601 g, 1.5 equiv). The mixture was cooled in an ice-acetone bath (-5 °C). Methanesulfonyl chloride (436 g, 1.20 equiv) was added via a drop funnel while keeping the reaction temperature at less than5 °C. HPLC showed reaction completion after 15 min. Water (6.3 L) was added, and the reaction mixture was stirred for 2 h at room temperature and filtered. The filter cake was rinsed with water (2 x 1 L), pulled dry under vacuum, and directly subjected to the amination reaction in the next step. Yield 100%.
1-(Diphenylmethyl)-3-azetidinyl methanesulfonate synthesis

1-(Diphenylmethyl)-3-azetidinyl methanesulfonate Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

1-(DIPHENYLMETHYL)-3-(HYDROXYMETHYL)AZETIDINE 1-Benzhydrylazetidine-3-carboxylic acid 1-Benzhydryl-3-phenoxy-azetidine 3-[(4-Chlorophenyl)thio]-1-(diphenylmethyl)azetidine

1-(Diphenylmethyl)-3-azetidinyl methanesulfonate Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 245)Lieferanten
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info@edengenechem.com China 2158 58
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33301-41-6()Verwandte Suche:

  • BUTTPARK 37\04-14
  • 1-BENZHYDRYL-3-METHANESULFONATOAZETIDINE
  • 1-BENZHYDRYL-3-METHANESULFONYLOXY AZETIDINE
  • 1-(DIPHENYLMETHYL)-3-(METHANESULFONYLOXY)AZETIDINE
  • 1-DIPHENYLMETHYL-3-AZETIDINYL METHANESULFONATE
  • 1-(diphenylmethyl)-3-(methanesulfonyloxy)azetinide
  • 1-Diphenylmethyl-3-azetidinyl Methanethiosulfonate
  • 1-Benzhydryl-3-methanesulphonyloxyazetidine
  • 1-BENZHYDRYL-3-METHANESULFONATOAZETIDINE 98%
  • Methanesulfonic acid 1-benzhydryl-azetidin-3-yl ester
  • 1-(Diphenylmethyl)-3-(mesyloxy)azetidine
  • 1-(Diphenylmethyl)-3-[(methylsulfonyl)oxy]azetidine
  • 1-(Diphenylmethyl)azetidin-3-yl methanesulfonate
  • 1-Benzhydryl-3-azetidinyl Methanesulfonate, 95%
  • methanesulfonic acid [1-[di(phenyl)methyl]-3-azetidinyl] ester
  • methanesulfonic acid [1-[di(phenyl)methyl]azetidin-3-yl] ester
  • (1-benzhydryl-2-hydroxyazetidin-3-yl)methanesulfonate
  • 1-(Diphenylmethyl)-3-azetidinyl methanesulfote
  • 1-Benzhydrylazetidin-3-yl methanesulfonate 97%
  • 1-(Diphenylmethyl)-3-azetidinyl methanesulfonate 95%
  • 1-Benzhydryl-3-azetidinylMethanesulfonate>
  • 3-Azetidinol, 1-(diphenylmethyl)-, 3-methanesulfonate
  • 1-BENZHYDRYL-3-METHANESULFONATOAZETIDINE CAS
  • 1-BENZHYDRYLAZETIDIN-3-YL METHANESULFONATE
  • 1-(Diphenylmethyl) azitidine-3-yl methane sulfonate
  • Methane Sulphonic acid 1-Bezhydryl Azetidine 3-yl Ester
  • 33301-41-6
  • 3301-41-6
  • C17H19NO3S
  • Aromatics
  • Heterocycles
  • MTS & Sulfhydryl Active Reagents
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