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2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin

Bathocuproine Struktur
4733-39-5
CAS-Nr.
4733-39-5
Bezeichnung:
2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin
Englisch Name:
Bathocuproine
Synonyma:
2,9-DIMETHYL-4,7-DIPHENYL-1,10-PHENANTHROLINE;BATHOCUPROIN;BLANC FIXE XR;BATHOCUPROINE;BathocuproineGr;Bathocuproin BCP;EINECS 225-240-5;BATHOCUPROINE AR;2,9-dm-4,7-dpphen;BATHOCUPROINE(RG)
CBNumber:
CB2299411
Summenformel:
C26H20N2
Molgewicht:
360.45
MOL-Datei:
4733-39-5.mol

2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin Eigenschaften

Schmelzpunkt:
279-283 °C(lit.)
Siedepunkt:
482.47°C (rough estimate)
Dichte
1.2408 (rough estimate)
Brechungsindex
1.7620 (estimate)
storage temp. 
Sealed in dry,Room Temperature
L?slichkeit
Benzene (Slightly, Heated), DMSO (Slightly, Heated), Methanol (Slightly, Heated)
Aggregatzustand
Powder
pka
5.88±0.30(Predicted)
Farbe
Yellow
Wasserl?slichkeit
Soluble in methanol (36mg/100ml), ethanol, 2-propanol, bezene, and acetone. Partly miscible in water.
maximale Wellenl?nge (λmax)
277 nm
BRN 
306714
InChI
InChI=1S/C26H20N2/c1-17-15-23(19-9-5-3-6-10-19)21-13-14-22-24(20-11-7-4-8-12-20)16-18(2)28-26(22)25(21)27-17/h3-16H,1-2H3
InChIKey
STTGYIUESPWXOW-UHFFFAOYSA-N
SMILES
N1C2C(=CC=C3C=2N=C(C)C=C3C2=CC=CC=C2)C(C2=CC=CC=C2)=CC=1C
CAS Datenbank
4733-39-5(CAS DataBase Reference)
EPA chemische Informationen
1,10-Phenanthroline, 2,9-dimethyl-4,7-diphenyl- (4733-39-5)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xn
R-S?tze: 22-36/37/38-20/21/22
S-S?tze: 24/25-36-26-37/39
WGK Germany  3
TSCA  Yes
HS Code  29339990
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H413 Kann für Wasserorganismen sch?dlich sein, mit langfristiger Wirkung. Langfristig (chronisch) gew?ssergef?hrdend Kategorie 4
Sicherheit
P273 Freisetzung in die Umwelt vermeiden.

2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

Organic photovoltaic cells (OPVCs) are considered to be promising devices because of their mechanical flexibility, ease of fabrication and potential for low-cost production. For small-molecule OPVCs the most-common material to use between the acceptor, here C60, and the top electrode, Al, is 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline, also known as bathocuproine. Indeed, the insertion of BCP results in an enhanced power-conversion efficiency (PCE). The improved power-conversion efficiency has been attributed to an increased exciton harvesting in the active layer. As BCP is a wide-band-gap material it acts as an exciton-blocking barrier (EBL) that prohibits excitons diffusing towards the Al electrode where they would otherwise be quenched.

R-S?tze Betriebsanweisung:

R22:Gesundheitssch?dlich beim Verschlucken.
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R20/21/22:Gesundheitssch?dlich beim Einatmen,Verschlucken und Berührung mit der Haut.

S-S?tze Betriebsanweisung:

S24/25:Berührung mit den Augen und der Haut vermeiden.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.

Chemische Eigenschaften

Yellow powder

Verwenden

Bathocuproine can be used as an electron-modifying layer or as an interlayer between ETLs (electron transport layers) in calcite solar cells, and it can be prepared by spin-coating deposition or vacuum thermal evaporation. The addition of Bathocuproine enhances the energy conversion efficiency of organic photovoltaic cells.

Allgemeine Beschreibung

TGA/DSC Lot specific scans available upon request

l?uterung methode

Purify it by recrystallisation from *benzene. [Smith & Wilkins Anal Chem 25 510 1953, Beilstein 23 III/IV 2160.]

Einzelnachweise

[1] Mao, Lingling et al. “Role of Organic Counterion in Lead- and Tin-Based Two-Dimensional Semiconducting Iodide Perovskites and Application in Planar Solar Cells.” Chemistry of Materials 28 (2016): 7781–7792.

2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 386)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
SHANGHAI KEAN TECHNOLOGY CO., LTD.
+8613817748580
cooperation@kean-chem.com China 40066 58
Jilin Uland Tech Co.,Ltd.
+86-18604466210 +86-18604466210
yolanda@uldtech.com China 289 58
Shaanxi Dideu Medichem Co. Ltd
+86-29-81139210 +86-18192627656
1059@dideu.com China 3003 58
Shanghai UCHEM Inc.
+862156762820 +86-13564624040
sales@myuchem.com China 7711 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652
info@fdachem.com China 20267 58
Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806
sales@capot.com China 29793 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886
info@dakenam.com China 18940 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21634 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795
ivan@atkchemical.com China 32965 60
career henan chemical co
+86-0371-86658258 +8613203830695
sales@coreychem.com China 29879 58

4733-39-5(2,9-Dimethyl-4,7-diphenyl-1,10-phenanthrolin)Verwandte Suche:


  • EINECS 225-240-5
  • 2,9-dm-4,7-dpphen
  • 2,9-dimethyl-4,7-diphenyl-phen
  • 2,9-DiMethyl-4,7-diphenyl-1,10-phenantroline
  • 2,9-DiMethyl-4,7-diphenyl-1,10-phenanthroline, 98% 1GR
  • Bathocuproin BCP
  • Bathocuproine p.a.
  • Bathocuproine,2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, BCP
  • Bathocuproine ,99%
  • BATHOCUPROINE(RG)
  • 4,7-DIPHENYL-2,9-DIMETHYL-1,10-PHENANTHROLINE
  • BLANC FIXE XR
  • BATHOCUPROINE
  • 2,9-dimethyl-4,7-diphenyl-10-phenanthroline
  • 2,9-Dimethyl-4,7-diphenyl-1,10
  • 10-Phenanthroline,2,9-dimethyl-4,7-diphenyl-1
  • 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline,98%
  • BATHOCUPROINE (2,9-DIMETHYL-4,7-DIPHENYL-1,10-PHENANTHROLINE)
  • 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, BCP
  • BATHOCUPROIN extrapure AR
  • Bathocuproin, 98+%
  • Bathocuproine (refined product of D0711)
  • 2,9-DIMETHYL-4,7-DIPHENYL-1,10-PHENANTHROLINE SUBLIMED HOLE BLOCKING MATERIAL
  • 1,10-Phenanthroline, 2,9-dimethyl-4,7-diphenyl-
  • BATHOCUPROINE REAGENT (ACS)
  • BATHOCUPROINE, REAG.
  • BathocuproineGr
  • BATHOCUPROIN R. G.
  • 2-DIMETHYL-4,7-DIPHENYL-1,10-PHENANTHROLINE
  • TIMTEC-BB SBB008863
  • Bathocuproine (purified by sublimation)
  • 2,9-dimethyl-4,7-diphenyl-1,10-phenanthrolin
  • Bathocuproin SynonyMs 2,9-DiMethyl-4,7-diphenyl-1,10-phenanthroline
  • Bathocuproine subliMed grade, 99.99% trace Metals basis
  • BATHOCUPROINE AR
  • Bathocuproine (BCP) extrapure AR, ACS, 99%
  • Bathocuproine (BCP) extrapure AR, 99%
  • Bathocuproin 4733-39-5
  • Bathocuproine, GR 99%+
  • 2,9-Dimethyl-4,7-diphenyl-1,1-phenanthroline
  • Bathocuproine (BCP)
  • 2,9-dimethy-4,7-diphenyl -1,10-phenathroline
  • Bathocuproine (purified by sublimation)>
  • Bathocuproine >
  • Bathocuproine, sublimed
  • Bathocuproine subliMed grade, trace Metals basis
  • 2,9-DIMETHYL-4,7-D
  • BATHOCUPROINE, LABORATORY REAGENTBATHOCUPROINE, LABORATORY REAGENTBATHOCUPROINE, LABORATORY REAGENTBATHOCUPROINE, LABORATORY REAGENT
  • 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline/Bathocuproine
  • BATHOCUPROIN
  • 2,9-DIMETHYL-4,7-DIPHENYL-1,10-PHENANTHROLINE
  • 2,9- dimethyl -4,7- biphenyl -1,10- phenanthroline
  • 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline (purified by sublimation)
  • Bathocuproine 99% AR
  • 4733-39-5
  • CH32C6H52C12H4N2
  • C26H20N2
  • Analytical Chromatography Product Catalog
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