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D-Gluconsure

Gluconic acid Struktur
526-95-4
CAS-Nr.
526-95-4
Bezeichnung:
D-Gluconsure
Englisch Name:
Gluconic acid
Synonyma:
gluconic;(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanoic acid;Hexonic acid;Glyconic acid;D-Gluconic acid solution;GLUCONIC ACI;d-gluconicaci;2,3,4,5,6-Pentahydroxyhexanoic acid;glosanto;NSC 77381
CBNumber:
CB2252915
Summenformel:
C6H12O7
Molgewicht:
196.16
MOL-Datei:
526-95-4.mol

D-Gluconsure Eigenschaften

Schmelzpunkt:
15 °C
alpha 
D20 -6.7° (c = 1)
Siedepunkt:
102 °C
Dichte
1.23
Brechungsindex
1.4161
storage temp. 
Store below +30°C.
L?slichkeit
DMSO (Slightly), Methanol (Slightly), Water
Aggregatzustand
Crystalline Powder or Crystals
pka
pK (25°) 3.60
Farbe
White to light yellow
Wichte
1.234
Geruch (Odor)
commercial 50 aq. soln. lt. amber, faint odor of vinegar
Optische Aktivit?t
[α]/D +9.0 to 15.5°
Wasserl?slichkeit
Soluble in water.
Merck 
14,4456
BRN 
1726055
LogP
-2.116 (est)
CAS Datenbank
526-95-4(CAS DataBase Reference)
NIST chemische Informationen
Gluconic acid(526-95-4)
EPA chemische Informationen
D-Gluconic acid (526-95-4)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xi,C
R-S?tze: 36/37/38-34
S-S?tze: 37/39-26-45-36/37/39
RIDADR  3265
WGK Germany  -
RTECS-Nr. LZ5057100
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29181600
Giftige Stoffe Daten 526-95-4(Hazardous Substances Data)
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H314 Verursacht schwere Ver?tzungen der Haut und schwere Augensch?den. ?tzwirkung auf die Haut Kategorie 1B Achtung GHS hazard pictogramssrc="/GHS05.jpg" width="20" height="20" /> P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Verursacht schwere Augensch?den. Schwere Augensch?digung Kategorie 1 Achtung GHS hazard pictogramssrc="/GHS05.jpg" width="20" height="20" /> P280, P305+P351+P338, P310
Sicherheit
P260 Dampf/Aerosol/Nebel nicht einatmen.
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P405 Unter Verschluss aufbewahren.

D-Gluconsure Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R34:Verursacht Ver?tzungen.

S-S?tze Betriebsanweisung:

S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.

Beschreibung

Gluconic acid is an organic compound with molecular formula C6H12O7 and condensed structural formula HOCH2(CHOH)4COOH. It is one of the 16 stereoisomers of 2,3,4,5,6-penta hydroxy hexanoic acid.
In aqueous solution at neutral pH, gluconic acid forms the gluconate ion. The salts of gluconic acid are known as "gluconates". Gluconic acid, gluconate salts, and gluconate esters occur widely in nature because such species arise from the oxidation of glucose. Some drugs are injected in the form of gluconates.

Chemische Eigenschaften

d-Gluconic acid is an acid sugar composed of white crystals with a milk-acidic taste. In aqueous solutions, it is in equilibrium with gamma- and delta-gluconolactones. It is prepared by enzymatic oxidation of glucose and strains of the microorganisms used to supply the enzyme action are nonpathogenic and nontoxicogenic to man or other animals. This substance is used as a component of bottle rinsing formulations, at levels not to exceed good manufacturing practice.
An FDA letter to a trade association revoking affirmation of general recognition of safety in dietary supplements was dated April 9, 1970.

Physikalische Eigenschaften

The chemical structure of gluconic acid consists of a six-carbon chain with five hydroxyl groups terminating in a carboxylic acid group. In aqueous solution, gluconic acid exists in equilibrium with the cyclic ester glucono delta-lactone.

Occurrence

Gluconic acid occurs naturally in fruit, honey, kombucha tea, and wine. As a food additive ( E574 ), it is an acidity regulator. It is also used in cleaning products where it dissolves mineral deposits especially in alkaline solution. The gluconate anion chelates Ca2+,Fe2+, Al3+, and other metals. In 1929 Horace Terhune Herrick developed a process for producing the salt by fermentation.
Calcium gluconate, in the form of a gel, is used to treat burns from hydrofluoric acid; calcium gluconate injections may be used for more severe cases to avoid necrosis of deep tissues. Quinine gluconate is a salt between gluconic acid and quinine, which is used for intramuscular injection in the treatment of malaria. Zinc gluconate injections are used to neuter male dogs. Iron gluconate injections have been proposed in the past to treat anemia.

Verwenden

Gluconic Acid is an acidulant that is a mild organic acid which is the hydrolyzed form of glucono-delta-lactone. it is prepared by the fermentation of dextrose, whereby the physiological d-form is produced. it is soluble in water with a solubility of 100 g/100 ml at 20°c. it has a mild taste and at 1% has a ph of 2.8. it functions as an antioxidant and enhances the function of other antioxidants. in beverages, syrups, and wine, it can eliminate calcium turbidities. it is used as a leavening component in cake mixes, and as an acid component in dry-mix desserts and dry beverage mixes.

Definition

gluconic acid: An opticallyactive hydroxycarboxylic acid,CH2(OH)(CHOH)4COOH. It is the carboxylicacid corresponding to the aldosesugar glucose, and can be madeby the action of certain moulds.

D-Gluconsure Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


D-Gluconsure Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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526-95-4(D-Gluconsure)Verwandte Suche:


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