5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one Chemische Eigenschaften,Einsatz,Produktion Methoden
Beschreibung
This alkaloid, sometimes referred to as cryptopalmine, occurs in Papaver nudi-cauZe L. and in Argernone rnunita Dur. & Hilg. subsp. rotunda. When crystallized
from Me2CO it forms clusters of colourless crystals. It furnishes a crystalline
hydriodide, m.p. 176-7°C (dec.) and a methiodide, m.p. 192-4°C. The struc_x0002_ture has been deduced from the mass spectrum and confirmed by synthesis.
Einzelnachweise
Boit, Flentje., Naturwiss., 47, 180 (1960)
Preininger et aZ., PZanta Med., 10, 124 (1962)
Mass spectrum:
Cross et aZ., Collect. Czech. Chern. Cornrnun., 30, 1335 (1965)
Synthesis:
Haworth, Koepfli, Perkin., 1. Chern. Soc., 2261 (1927)
Giacopello, Deulofeu., Tetrahedron Lett., 2859 (1966)
5,7,8,14-Tetrahydro-3,4,10,11-tetramethoxy-6-methyldibenz[c,g]azecin-13(6H)-one Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte