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[6aS,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-6-methyl-4H-dibenzo[de,g]isoquinoline-9-ol

[6aS,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-6-methyl-4H-dibenzo[de,g]isoquinoline-9-ol Struktur
CAS-Nr.
Englisch Name:
[6aS,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-6-methyl-4H-dibenzo[de,g]isoquinoline-9-ol
Synonyma:
N-Methyllaurotetanine;[6aS,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-6-methyl-4H-dibenzo[de,g]isoquinoline-9-ol
CBNumber:
CB22160708
Summenformel:
C20H23NO4
Molgewicht:
341.40092
MOL-Datei:
Mol file

[6aS,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-6-methyl-4H-dibenzo[de,g]isoquinoline-9-ol Eigenschaften

Sicherheit

[6aS,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-6-methyl-4H-dibenzo[de,g]isoquinoline-9-ol Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

First obtained by Spath and Suominen from Litsea citrata, this alkaloid has also been found in Phylica rogersii Pillans. With CH2N2 it gives glaucine (q.v.) while Hofmann degradation of the O-ethyl ether gives 3: S: 6-trimethoxy-2-ethoxy-8- vinylphenanthrene, m.p. 140-loC, identical with that obtained from laurotetanine (q.v.). The O-ethyl ether is characterized as the methiodide, colourless crystals from Me2CO-MeOH, m.p. 206-7°C; [α]D + 61° (c 0.70, EtOH).

Einzelnachweise

Spath, Suominen., Ber., 66, 1344 (1933)
Arndt, Baarschers.,J. Chern. Soc., 2244 (1964)

[6aS,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-6-methyl-4H-dibenzo[de,g]isoquinoline-9-ol Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


[6aS,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-6-methyl-4H-dibenzo[de,g]isoquinoline-9-ol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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  • [6aS,(+)]-5,6,6a,7-Tetrahydro-1,2,10-trimethoxy-6-methyl-4H-dibenzo[de,g]isoquinoline-9-ol
  • N-Methyllaurotetanine
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