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FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID

FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID Struktur
93372-25-9
CAS-Nr.
93372-25-9
Englisch Name:
FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID
Synonyma:
FMOC-TOAC;FMOC-TOAC-OH 500 MG;FMOC-TOAC-OH 100 MG;FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID;Fmoc-2,2,6,6-tetramethylpiperidine-N-oxyl-4-amino-4-carboxylic acid≥ 98% (HPLC);4-(9H-fluoren-9-ylmethoxycarbonylamino)-2,2,6,6-tetramethyl-1-oxidopiperidin-1-ium-4-carboxylic acid
CBNumber:
CB2166593
Summenformel:
C25H29N2O5*
Molgewicht:
437.51
MOL-Datei:
Mol file

FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID Eigenschaften

Schmelzpunkt:
162-164°C
storage temp. 
Store at +2°C to +8°C.
L?slichkeit
Acetonitrile (Slightly), Chloroform (Slightly), Methanol (Slightly)
Aggregatzustand
Solid
Farbe
Pale Yellow to Yellow

Sicherheit

WGK Germany  WGK 2 water endangering
HS Code  2933 39 99

FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID Chemische Eigenschaften,Einsatz,Produktion Methoden

Chemische Eigenschaften

Yellow Solid

Verwenden

A protected spin-labelled, cyclic, chiral ?amino acid resolved in an enantiomerically pure state

Allgemeine Beschreibung

Fmoc-TOAC-OH is a useful tool for the incorporation of the ESR spin-label TOAC into peptide sequences [1]. Incorporation of this derivative and the following residue is best achieved using HATU activation. TFA/water/TIS should be used for cleavage of TOAC-containing peptides. The use of EDT should be avoided as it can cause permanent reduction of the nitroxide radical [2]. Following cleavage, the TOAC peptide should be treated with aqueous ammonia in air to regenerate the nitroxide from the hydroxylamine that is generated by the TFA treatment.

FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID Upstream-Materialien And Downstream Produkte

Upstream-Materialien

2,2,6,6-TETRAMETHYLPIPERIDINE-1-OXYL-4-AMINO-4-CARBOXYLIC ACID N-(9-Fluorenylmethoxycarbonyloxy)succinimide

Downstream Produkte

FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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  • Fmoc-2,2,6,6-tetramethylpiperidine-N-oxyl-4-amino-4-carboxylic acid≥ 98% (HPLC)
  • FMOC-2,2,6,6-TETRAMETHYLPIPERIDINE-N-OXYL-4-AMINO-4-CARBOXYLIC ACID
  • FMOC-TOAC
  • FMOC-TOAC-OH 100 MG
  • FMOC-TOAC-OH 500 MG
  • 4-(9H-fluoren-9-ylmethoxycarbonylamino)-2,2,6,6-tetramethyl-1-oxidopiperidin-1-ium-4-carboxylic acid
  • 93372-25-9
  • Chiral Reagents
  • Spin Labeling Compounds
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