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2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Struktur
357209-32-6
CAS-Nr.
357209-32-6
Englisch Name:
2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
Synonyma:
(R,S)-In-Pybox;(3aR,8aS)-in-pybox;2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&;2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D) OXAZOLIN-2-YL)PYRIDINE;2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine >=94%;2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine, >=98%;2,6-Bis((3aR,8aS)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine;2,6-bis((3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazol-2-yl)pyridine;2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine,95%,99%ee;(+)-2,6-Bis[(3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl)pyridine
CBNumber:
CB1973015
Summenformel:
C25H19N3O2
Molgewicht:
393.44
MOL-Datei:
357209-32-6.mol

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Eigenschaften

Schmelzpunkt:
284 °C (dec.)
Siedepunkt:
633.0±55.0 °C(Predicted)
Dichte
1.50±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
4.35±0.20(Predicted)
Optische Aktivit?t
[α]20/D +386°, c = 1 in methylene chloride(lit.)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
R-S?tze: 36/37/38
S-S?tze: 26-36
WGK Germany  3
HS Code  29349990
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H302 Gesundheitssch?dlich bei Verschlucken. Akute Toxizit?t oral Kategorie 4 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P270, P301+P312, P330, P501
Sicherheit
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Chemische Eigenschaften,Einsatz,Produktion Methoden

Chemische Eigenschaften

White powder

Verwenden

Catalytic ligand used for:
  • [3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage
  • Enantioselective Mukaiyama-aldol reactions
  • Enantioselective carbonyl-ene reactions
  • Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes
  • Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex
  • Enantioselective Diels-Alder reaction
  • Ni-catalyzed cross-coupling reactions

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 78)Lieferanten
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  • 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
  • 2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D) OXAZOLIN-2-YL)PYRIDINE
  • (3aR,8aS)-in-pybox, (3aR,3μaR,8aS,8μaS)-2,2μ-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole
  • 2,6-Bis((3aR,8aS)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine
  • 8H-Indeno[1,2-d]oxazole,2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-, (3aR,3'aR,8aS,8'aS)-
  • (3aR,3'aR,8aS,8'aS)-2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole
  • 2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine >=94%
  • 2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine, >=98%
  • (3aR,3'aR,8aS,8'aS)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole],99%e.e.
  • (3aR,8aS)-in-pybox
  • (3aS,8bR)-2-[6-[(3aS,8bR)-4,8b-dihydro-3aH-indeno[1,2-d][1,3]oxazol-2-yl]pyridin-2-yl]-4,8b-dihydro-3aH-indeno[1,2-d][1,3]oxazole
  • (+)-2,6-Bis[(3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl)pyridine
  • 2,6-bis((3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazol-2-yl)pyridine
  • (3aR,3'aR,8aS,8'aS)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole], 98% (99% ee)
  • 2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine,95%,99%ee
  • (R,S)-In-Pybox
  • (+)-2,6-Bis[(3aR,8aS)-3a,8a-dihydro-8H-indeno[1,2-d]oxazolin-2-yl)pyridine
  • (3aR,3'aR,8aS,8'aS)-2,2'-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole
  • 357209-32-6
  • BOX series
  • Chiral Nitrogen
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