3-Methyl-1-nitrobutan
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3-Methyl-1-nitrobutan Eigenschaften
- Schmelzpunkt:
- 97°C
- Siedepunkt:
- 168.95°C (estimate)
- Dichte
- 0.9458
- Brechungsindex
- 1.4153
- pka
- 8.65±0.29(Predicted)
- LogP
- 1.800 (est)
Sicherheit
3-Methyl-1-nitrobutan Chemische Eigenschaften,Einsatz,Produktion Methoden
synthetische
Synthesis of 3-methyl-1-nitrobutane: Isopentyl bromide (120.84 g, 0.80 mol) was added dropwise to a mechanical stirred solution of sodium nitrite (110.39g, 1.60 mol) in DMF (500 mL) at 0°C. The reaction mixture was mechanically stirred overnight at room temperature. Water (1 L) was added to the mixture. The mixture was extracted with pet. ether (4 x 150 mL). The combined organic phases were washed with water (2 x 150 mL). The organic phase was dried with Na2SO4 then the solvent was evaporated under reduced pressure. Distillation under vacuum gave 30.2g (32%) of the colorless nitroalkane 3-methyl-1-nitrobutane (b.p. 58 - 60°C 21 mmHg)Not visible on TLC IR (neat) ν 2962, 1549, 1470, 1434, 1434, 1381, 1211, 1133, 851 cm-1 . 1H NMR (500 MHz, CDCl3) a 0.96 (d, J = 6.7 Hz, 6 H), 1.69 (h, J = 6.7Hz, 1 H), 1.91 (q, J = 7.2 Hz, 2 H), 4.41 (t, J = 7.3 Hz, 2 H). 13C NMR (125 MHz, CDCl3) a = 21.9, 25.5, 35.9, 74.2
Definition
ChEBI: 3-methyl-1-nitrobutane is a primary nitroalkane that is 2-methylbutane substituted by a nitro group at position 4. It is a herbivore-induced plant volatile found in the leaves of Oenothera biennis. It has a role as a plant metabolite. It is a primary nitroalkane and a volatile organic compound.3-Methyl-1-nitrobutan Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
3-Methyl-1-nitrobutan Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 18)Lieferanten
Firmenname | Telefon | Land | Produktkatalog | Edge Rate | |
---|---|---|---|---|---|
Accela ChemBio Inc. | +1-858-6993322 |
info@accelachem.com | United States | 17982 | 58 |
Suzhou ARTK Medchem Co., Ltd. | +86-512-68323658 +86-18168183658 |
sales1@artkmedchem.com | China | 39004 | 58 |
Amadis Chemical Company Limited | 571-89925085 |
sales@amadischem.com | China | 131957 | 58 |
PharmaBlock Sciences (Nanjing),Inc. | 025-86918202 4000255188 |
sales@pharmablock.com | China | 4986 | 55 |
Accela ChemBio Co.,Ltd. | 021-50795510 4000665055 |
sales@accelachem.com | China | 11655 | 64 |
Aikon International Limited | 025-66028182 18112977050 |
cfzhang@aikonchem.com | China | 15818 | 58 |
SHANGHAI FDC-CHEMICAL CO.,LTD | 021-61469567 13482353728 |
sales@fdc-chemical.com | China | 14729 | 58 |
BOC Sciences | -- |
info@bocsci.com | USA | 0 | 65 |
Shanghai Haohong Pharmaceutical Co., Ltd. | 4008210725 4008210725 |
malulu@leyan.com | China | 54987 | 58 |
Block Chemical Technology (Shanghai) Co., LTD | 021-20432219 13918097649 |
li_jinfei@acblock-lab.com | China | 9964 | 58 |
- 3-methyl-1-nitrobutane
- 4-Nitro-2-methylbutane
- Butane, 3-methyl-1-nitro-
- 1-Nitro-3-methylbutane
- 627-67-8