Acetoacetanilid
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- CAS-Nr.
- 102-01-2
- Bezeichnung:
- Acetoacetanilid
- Englisch Name:
- Acetoacetanilide
- Synonyma:
- AAA;3-OXO-N-PHENYLBUTANAMIDE;AAN;ethyl 3-oxo-3-(phenylamino)propanoate;Acetoacetanilid;n-phenylacetoacetamide;Linazol;usafek-1239;Coupler 633;USAF ek-1239
- CBNumber:
- CB0463919
- Summenformel:
- C10H11NO2
- Molgewicht:
- 177.2
- MOL-Datei:
- 102-01-2.mol
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Acetoacetanilid Eigenschaften
- Schmelzpunkt:
- 83-88 °C (lit.)
- Siedepunkt:
- 129°C 24mm
- Dichte
- 1.26
- Dampfdichte
- 6.1 (vs air)
- Dampfdruck
- 0-0.013Pa at 20-50℃
- Brechungsindex
- 1.5168 (estimate)
- Flammpunkt:
- 325 °F
- storage temp.
- Refrigerator
- L?slichkeit
- Chloroform (Slightly), Methanol (Slightly)
- pka
- 12.21±0.46(Predicted)
- Aggregatzustand
- Crystalline Powder
- Farbe
- White
- Biologische Quelle
- synthetic
- Wasserl?slichkeit
- 5 g/L (20 ºC)
- Merck
- 14,58
- BRN
- 473419
- Stabilit?t:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- LogP
- 0.93 at 23℃
- CAS Datenbank
- 102-01-2(CAS DataBase Reference)
- NIST chemische Informationen
- Butanamide, 3-oxo-N-phenyl-(102-01-2)
- EPA chemische Informationen
- Acetoacetanilide (102-01-2)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Kennzeichnung gef?hrlicher |
Xn |
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| R-S?tze: |
21/22 |
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| S-S?tze: |
36 |
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| RTECS-Nr. |
AK4200000 |
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| Selbstentzündungstemperatur |
843 °F |
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| HS Code |
2921419000 |
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| Giftige Stoffe Daten |
102-01-2(Hazardous Substances Data) |
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| Toxizit?t |
LD50 orl-rat: 5400 mg/kg LONZA# 08FEB79 |
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| Bildanzeige (GHS) |
 
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| Alarmwort |
Warnung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H302 |
Gesundheitssch?dlich bei Verschlucken. |
Akute Toxizit?t oral |
Kategorie 4 |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
P264, P270, P301+P312, P330, P501 |
| H312 |
Gesundheitssch?dlich bei Hautkontakt. |
Akute Toxizit?t dermal |
Kategorie 4 |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
P280,P302+P352, P312, P322, P363,P501 |
| H341 |
Kann vermutlich genetische Defekte verursachen. |
Keimzellmutagenit?t |
Kategorie 2 |
Warnung |
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P201,P202, P281, P308+P313, P405,P501 |
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| Sicherheit |
| P201 |
Vor Gebrauch besondere Anweisungen einholen. |
| P202 |
Vor Gebrauch alle Sicherheitshinweise lesen und verstehen. |
| P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
| P308+P313 |
BEI Exposition oder falls betroffen: ?rztlichen Rat einholen/?rztliche Hilfe hinzuziehen. |
| P405 |
Unter Verschluss aufbewahren. |
| P501 |
Inhalt/Beh?lter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen. |
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Acetoacetanilid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R21/22:Gesundheitssch?dlich bei Berührung mit der Haut und beim Verschlucken.
S-S?tze Betriebsanweisung:
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
Chemische Eigenschaften
White to off-white powder
Verwenden
Acetoacetanilide is used as intermediate for the manufacture of organic pigments and dyestuffs.
Allgemeine Beschreibung
White crystalline solid.
Air & Water Reaktionen
Water insoluble.
Reaktivit?t anzeigen
Organic amides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides with strong reducing agents. Amides are very weak bases (weaker than water). Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx). Ketones are reactive with many acids and bases liberating heat and flammable gases (e.g., H2). The amount of heat may be sufficient to start a fire in the unreacted portion of the ketone. Ketones react with reducing agents such as hydrides, alkali metals, and nitrides to produce flammable gas (H2) and heat. Ketones are incompatible with isocyanates, aldehydes, cyanides, peroxides, and anhydrides. They react violently with aldehydes, HNO3, HNO3 + H2O2, and HClO4.
Health Hazard
ACUTE/CHRONIC HAZARDS: Acetoacetanilide is a weak allergen. When heated to decomposition it emits toxic fumes.
Brandgefahr
Acetoacetanilide is combustible.
Sicherheitsprofil
Poison by intraperitoneal route. Moderately toxic by ingestion. A weak allergen. See also ACETANILIDE. Combustible when exposed to heat or flame. See ANILINE and CYANIDE for disaster hazard. When heated to decomposition it emits toxic NOx, fumes. To fight fire, use alcohol foam, water mist, CO2, dry chemical.
l?uterung methode
Crystallise the anilide from H2O, aqueous EtOH or pet ether (b 60-80o). [Williams & Krynitsky Org Synth Coll Vol III 10 1955.]
Acetoacetanilid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
4-Methylchinolin-2-ol
[3-[[1-[Anilinocarbonyl]-2-oxopropyl]azo]-2-hydroxy-5-nitrobenzol-1-sulfonato(3-)]chrom
Disperse Yellow S-3GL
Dinatrium-2-[4-[[1-[[(2-methoxyphenyl)amino]carbonyl]-2-oxopropyl]azo]-3-sulfonatophenyl]-6-methylbenzothiazol-7-sulfonat
Dinatrium-5,5'-dimethyl-4,4'-bis[[2-oxo-1-[(phenylamino)carbonyl]propyl]azo][1,1'-biphenyl]-2,2'-disulfonat
Acid Yellow 116
Acid Yellow 128
2-Chloracetoacetanilid
2,2'-[(3,3'-Dichlor[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(2,4-dimethylphenyl)-3-oxobutyramid]
2-[(4-Methyl-2-nitrophenyl)azo]-3-oxo-N-phenylbutyramid
Hydrogenbis[2-[(2-hydroxy-5-nitrophenyl)azo]-3-oxo-N-phenylbutyramidato(2-)]cobaltat(1-)
2-[(o-Nitrophenyl)azo]acetoacetanilid
Seedavay(Uniroyal)
4-Methylchinolin
Pigment Yellow 13
Carboxin
Hydrogenbis[2-[(4,5-dihydro-3-methyl-5-oxo-1-phenyl-1H-pyrazol-4-yl)azo]benzoato(2-)]chromat(1-)
Natriumhydroxy[2-hydroxy-5-nitro-3-[[2-oxo-1-(phenylcarbamoyl)propyl]azo]benzolsulfonato(3-)]chromat(1-)
[3-[[1-[Anilinocarbonyl]-2-oxopropyl]azo]-2-hydroxy-5-nitrobenzol-1-sulfonato(3-)]chrom
102-01-2(Acetoacetanilid)Verwandte Suche:
- Acetoacetanilide;Acetoacetic amilide;Acetoacetylaniline;α-Acetylacetanilide;β-Ketobutyranilide;3-Oxo-N-phenylbutanamide
- Acetoacetic amilide
- Butanamide, 3-oxo-N-phenyl-
- à-acetylacetanilide
- ACETOACETANILIDE 98+%
- AcetoacetanilideForSynthesis
- Naringenin 7b-neohesperidoside
- Acetoacetanilide,99%
- Cetoactanilide
- Acetoacetanilide, 99% 5GR
- AAA, Acetoacetaniline
- Acetoacetanilide >=99.5%
- .alpha.-Acetylacetanilide
- [(Acetoacetyl)amino]benzene
- 1-(Phenylcarbamoyl)-2-propanone
- 2-acetyl-acetanilid
- 3-oxo-,amide,n-phenyl-butanoicaci
- 3-oxo-n-phenyl-butanamid
- a-Acetylactanilide
- Acetanilide, 2-acetyl-
- Acetoacetamidobenzene
- Acetoacetonilide
- Acetoacetylaniline
- Acetylacetanilide
- alpha-Acetylacetanilide
- alpha-Acetyl-N-phenylacetamide
- Anilid kyseliny acetoctove
- anilidkyselinyacetoctove
- beta-Ketobutyranilide
- -Keto-butyranilide
- N-Acetoacetanilide
- USAF ek-1239
- usafek-1239
- B-KETOBUTYRANILIDE
- 2-acetyl-acetanilide
- N-Acetoacetylaniline
- Acetoacetanilide (flakes)
- Linazol
- N-Phenlyacetoacetamide
- TIMTEC-BB SBB003774
- n-(acetylacetyl)aniline
- N-Phenyl-3-oxobutanamide
- 1-ACETYLACETANILIDE
- 3-OXO-N-PHENYLBUTYRAMIDE
- ACETOACETIC ANILIDE
- ACETOACETIC ACID ANILIDE
- ACETOACETANILIDE
- ((acetoacetyl)amino)benzene
- 4-(Phenylamino)-2,4-butanedione
- 4H-1-Benzopyran-4-one, 7-[[2-O-(6-deoxy-a-L-mannopyranosyl)-b-D-glucopyranosyl]oxy]-2,3-dihydro-5-hydroxy-2-(4-hydroxyphenyl)-, (2S)-
- 7-[(2S,3R,4S,5S,6R)-4,5-Dihydroxy-6-(hydroxymethyl)-3-[(2S,3R,4R,5R,6S)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxyoxan-2-yl]oxy-5-hydroxy-2-(4-hydroxyphenyl)chroman-4-one
- Coupler 633
- AAA, Acetoacetanilid
- Acetoacetanilide 102-01-2
- 102-01-2 Acetoacetanilide
- Acetoacetanilide >
- AAN
- Acetoacetanilid
