[4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside Chemische Eigenschaften,Einsatz,Produktion Methoden
Beschreibung
This alkaloid, which is the O-~-D-glucoside of ipalbidine, also occurs in Ipomoea
alba L. It is dextrorotatory with [α]
23D + 32.5° (c 0.03, EtOH). The structure has
been confirmed by the total synthesis from 2-methoxypyrroline and the methyl
ester of acetylacetic acid.
Einzelnachweise
Gourley et al., Chem. Commun., 709 (1969)
Total synthesis:
Wick, Bartlett, Dolphin., Helv. Chim. Acta., 54, 513 (1971)
[4-(1,2,3,5,8,8a-Hexahydro-7-methylindolizin-6-yl)phenyl]β-D-glucopyranoside Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte