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C10603

C10603 Struktur
24185-51-1
CAS-Nr.
24185-51-1
Englisch Name:
C10603
Synonyma:
C10603;Lunarine;(1E,15E,20aR,24aS)-4,5,6,7,8,9,10,11,12,13,20a,21,23,24-Tetradecahydro-17,19-etheno-22H-benzofuro[3a,3-n][1,5,10]triazacycloicosine-3,14,22-trione;17,19-Etheno-22H-benzofuro[3a,3-n][1,5,10]triazacycloeicosine-3,14,22-trione, 4,5,6,7,8,9,10,11,12,13,20a,21,23,24-tetradecahydro-, (1E,15E,20aR,24aS)-
CBNumber:
CB01246395
Summenformel:
C25H31N3O4
Molgewicht:
437.54
MOL-Datei:
24185-51-1.mol

C10603 Eigenschaften

Schmelzpunkt:
227 -231°C (dec.).
Siedepunkt:
771.1±60.0 °C(Predicted)
Dichte
1.25±0.1 g/cm3(Predicted)
pka
14.40±0.20(Predicted)

Sicherheit

C10603 Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

A major alkaloid of the seeds of Lunaria biennis Mnch. and also found in L. rediviva, this alkaloid crystallizes as colourless needles from aqueous Me2CO. It is dextrorotatory with [α]27D + 300° (CHCI3) and forms crystalline salts including the hydrochloride, m.p. above 340°C; hydrobromide, m.p. 280-340°C, aurichloride, m.p. 166-170°C (dec.) and the sulphate, m.p. above 340°C.

Einzelnachweise

Steinegger, Reichstein., Pharrn. Acta Helv., 22, 258 (1947)
Boit., Chern. Ber., 87,1082 (1954)
Janot, LeMen., Bull. Soc. Chirn. Fr., 1840 (1956)
Poiter et al., ibid, 456 (1959)
Bladonetal., Tetrahedron Lett., No.9, 18(1959)
Poiter et al., Tetrahedron Lett., No. 18,36 (1960)
Huneck., Naturwiss., 49, 233 (1962)
Poiter et al., Tetrahedron Lett., 293 (1963)
Crystal structure:
Tamura et al., Chern. Cornrnun., 485 (1965)

C10603 Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


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  • C10603
  • (1E,15E,20aR,24aS)-4,5,6,7,8,9,10,11,12,13,20a,21,23,24-Tetradecahydro-17,19-etheno-22H-benzofuro[3a,3-n][1,5,10]triazacycloicosine-3,14,22-trione
  • Lunarine
  • 17,19-Etheno-22H-benzofuro[3a,3-n][1,5,10]triazacycloeicosine-3,14,22-trione, 4,5,6,7,8,9,10,11,12,13,20a,21,23,24-tetradecahydro-, (1E,15E,20aR,24aS)-
  • 24185-51-1
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