| Identification | More | [Name]
N-Cyclohexyl-2-benzothiazolesulfenamide | [CAS]
95-33-0 | [Synonyms]
accelerator cz
CBS
DURAX
DURAX RODFORM
N-CYCLOHEXYL-2-BENZOTHIAZOLESULFENAMIDE
N-CYCLOHEXYL-2-BENZOTHIAZOLESULPHENAMIDE
N-CYCLOHEXYL-2-BENZOTHIAZOLYLSULFENAMIDE
n-cyclohexylbenzothiazole-2-sulfenamide
N-CYCLOHEXYLBENZOTHIAZYL SULFENAMIDE
SANTOCURE(R)
Sulfenamide TS
2-(cyclohexylaminothio)benzothiazole
accicurehbs
benzothiazyl-2-cyclohexylsulfenamide
conaca
conach
conacs
curax
cyclohexyl_2_benzothiazolesulfenamide
cyclohexyl-2-benzothiazolesulfenamide | [EINECS(EC#)]
202-411-2 | [Molecular Formula]
C13H16N2S2 | [MDL Number]
MFCD00022872 | [Molecular Weight]
264.41 | [MOL File]
95-33-0.mol |
| Chemical Properties | Back Directory | [Melting point ]
93-100°C | [Boiling point ]
410.4±28.0 °C(Predicted) | [density ]
1.31~1.34g/cm3 | [vapor pressure ]
0Pa at 25℃ | [refractive index ]
1.5700 (estimate) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Chloroform (Slightly), DMSO (Slightly), Ethyl Acetatae (Slightly) | [form ]
Solid | [pka]
0.59±0.10(Predicted) | [color ]
Pale Yellow to Light Beige | [Water Solubility ]
Insoluble | [Contact allergens]
A rubber accelerator chemical. The most frequent occupational categories are metal industry, homemakers health services and laboratories, and the building industry.
| [InChIKey]
DEQZTKGFXNUBJL-UHFFFAOYSA-N | [LogP]
5 at 25℃ | [CAS DataBase Reference]
95-33-0(CAS DataBase Reference) | [EPA Substance Registry System]
95-33-0(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,N | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R43:May cause sensitization by skin contact. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S60:This material and/or its container must be disposed of as hazardous waste .
S37:Wear suitable gloves .
S24:Avoid contact with skin . | [RIDADR ]
3077 | [RTECS ]
DL6250000 | [HS Code ]
2934.20.8000 | [HazardClass ]
9 | [PackingGroup ]
III | [Safety Profile]
A poison by
intravenous route. Questionable carcinogen
with experimental tumorigenic data. An
experimental teratogen. Experimental
reproductive effects. When heated to
decomposition it emits toxic fumes of SOx
and NOx. | [Hazardous Substances Data]
95-33-0(Hazardous Substances Data) | [Toxicity]
LD50 oral in rat: 5300mg/kg |
| Hazard Information | Back Directory | [Description]
N-Cyelohexyl-2-benzothiazylsulfenamide is a rubber
accelerator chemical. The most frequent occupational
categories are metal industry, homemakers, health
services and laboratories, and building industries.
| [Uses]
N-Cyclohexylbenzo[d]thiazole-2-sulfonamide is useful for the production of sulfur-modified chloroprene rubber. | [Definition]
N-Cyclohexyl-2-benzothiazolesulfenamide (CBS) is one of the important kinds of sulfenamide vulcanization accelerator, have an anti-incipient scorch and the big advantage of curingprocess rate fast two concurrently in natural rubber, butadiene-styrene rubber, butadiene rubber, isoprene rubber, it is particularly suited for the furnace black sizing material that alkalescence is higher, variable colour and pollution are slight, and volume of production and the consumption of the most external CBS account for the 50% of thiazoles sulfuration chemicals total amount. In recent years, along with China's radial development, the demand for accelerator CBS has also presented the longest trend. | [Production Methods]
The synthetic method of N-Cyclohexyl-2-benzothiazolesulfenamide (CBS) mainly has sodium hypochlorite oxidization, Oxygen Catalytic Oxidation method, electrolytic oxidation, chlorine oxidation process, hydrogen peroxide oxidation method etc. at present, oxidizing process has raw material and is easy to get, the advantages such as equipment requirements is the highest. Product yield is high, and technique is simple and widely used by institute both at home and abroad. This method is to carry out condensation with 2-benzothiazolyl mercaptan (hereinafter referred to as M) in the presence of an oxidizer with cyclohexylamine to generate CBS.
| [Synthesis Reference(s)]
The Journal of Organic Chemistry, 43, p. 3223, 1978 DOI: 10.1021/jo00410a025 | [Flammability and Explosibility]
Notclassified |
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