| Identification | Back Directory | [Name]
POLYSTYRENE-B-POLYBUTADIENE-B-POLYSTYRENE | [CAS]
9003-55-8 | [Synonyms]
SBR
sbs
up1e
780F
492L
620A
631M
638A
kro1
kro2
k55e
UZ 1
dst50
dst75
8000a
tr201
sd354
sks85
r-104
ps-su2
AT 008
AT 011
B 1342
B 1530
A 7269
ABR 60
andrez
dow209
dow234
dow460
dow620
dow680
dow816
XP 808
XA 7135
XLB 115
duranit
dienols
litexca
base661
nipol407
plioflex
ALB 1443
ALB 1735
ricon100
ricon109
ricon181
ricon182
ricon183
XD 30374
ViscUp P
X 4399-05
ricona-84
76RES4100
76RES4402
76RES4470
duranit40
diarex600
hycarlx407
pliolites5
lytron5202
SBR rubber
marbon9200
polyco2410
polyco2415
synpol1500
vestyronhi
SBS mixture
solprene300
solprene303
pliolites5d
marbon8000a
pharos100.1
pliolites50
pliolites5a
pliolite151
pliolite160
pliolite491
pliolite55b
dowlatex612
dowtextl612
afcolacb101
Asaflex 845
Asaflex 1015
Vestyron 620
XUR-YM 12274
butakon85-71
histyrenes6f
edistirrb268
pliolites-5b
pliolites-5c
pliolites-5e
sbscopolymer
Aquacoat 100
Aquacoat 220
Arlatex 43DA
Arolon 870W51
PLIOLITE S-6B
PLIOLITE S-6H
Asaflex T 420
Asahi Dow 2301
Zetasizer 3000
Tylac 68010-01
sd345(polymer)
goodrite1800x73
Vaporcoat 2200r
thermoplastic125
soilstabilizer661
sbs(blockpolymer)
s6fhistyreneresin
butadiene-styrene
BUTADIENESTYRENERUBBER
STYRENE-BUTADIENELATEX
butadiene-styreneresins
BUTADIENE-STYRENE LATEX
BUTADIENE-STYRENE RESIN
POLY(STYRENE/BUTADIENE)
butadiene-styrenepolymer
STYRENE-BUTADIENE RUBBER
styrene-butadienepolymer
Butadienestyrenecopolymer
butadiene-styrenecopolymer
POLY(STYRENE-CO-BUTADIENE)
kopolymerbutadienstyrenovy
STYRENE/BUTADIENE COPOLYMER
Styrene-butadienerubber1500
styrene-butadienecopolymers
BUTADIENE-STYRENE50:50RUBBER
BUTADIENE-STYRENE75:25RUBBER
1,3-butadiene-styrenepolymer
Styrene-butadiene rubber 1502
Styrene-butadiene rubber 1712
Styrene, 1,3-butadiene polymer
styrene-1,3-butadienecopolymer
1,3-butadiene-styrenecopolymer
POLYSTYRENE-BLOCK-POLYBUTADIENE
styrenepolymerwith1,3-butadiene
1,3-BUTADIENE/STYRENE COPOLYMERS
SBR-1502 STYRENE-BUTADIENE RUBBER
polybutadiene-polystyrenecopolymer
STYRENE BUTADIENE LATEX, WATER BASED
copolymeresdustyreneetdubutadiene-1,3
Styrene-butadiene rubber,oil-extended
Poly(styrene-co-butadiene), 5% styrene
STYRENE/BUTADIENE, ABA BLOCK COPOLYMER
ethenylbenzenepolymerwith1,3-butadiene
POLYSTYRENE-BLOCK-POLYBUTADIENE-BLOCK-P
POLY(STYRENE-CO-BUTADIENE), MELT INDEX 6
Styrene-butadiene-styrene block copolymer
SBS Thermoplastic elastomer mixed granula
Benzene,ethenyl-,polymerwith1,3-butadiene
POLYSTYRENE-B-POLYBUTADIENE(1,2 ADDITION)
POLYSTYRENE-B-POLYBUTADIENE(1,4 ADDITION)
POLYSTYRENE-B-POLYBUTADIENE-B-POLYSTYRENE
POLYBUTADIENE-B-POLYSTYRENE-B-POLYBUTADIENE
POLY(STYRENE-CO-BUTADIENE), MELT INDEX 2 .8
Poly(styrene-co-butadiene) styrene 45 wt. %
POLY(STYRENE-CO-BUTADIENE), 45 WT. % STY RENE
POLYSTYRENE-BLOCK-POLYBUTADIENE-BLOCK-POLYSTYRENE
TAPERED BLOCK COPOLYMER POLYSTYRENE-B-POLYBUTADIENE
POLYSTYRENE-BLOCK-POLYBUTADIENE-BLOCK-POLYSTYRENE, BRANCHED
POLYSTYRENE-BLOCK-POLYBUTADIENE, BRANCHE D, 30 WT. % STYRENE
POLYSTYRENE-BLOCK-POLYBUTADIENE, 30 WT. % STYRENE, 80% DIBLOCK
Polystyrene-block-polybutadiene-block-polystyrene styrene 30 wt. %
POLY(STYRENE-B-BUTADIENE-B-STYRENE), 28 WT. % STYRENE, AVE MW CA. 100,000(G
POLY(STYRENE-B-BUTADIENE-B-STYRENE), 30 WT. STYRENE, AVE MW CA. 140,000 (GP
POLYSTYRENE-BLOCK-POLYBUTADIENE-BLOCK-PO LYSTYRENE,BRANCHED,21 WT.% STYRENE
Poly(styrene-co-butadiene) butadiene 4 wt. %, melt index 6 g/10 min (200C/5kg)
POLYBUTADIENE(1,4 AND 1,2 ADDITION)-B-POLYSTYRENE-B-POLYBUTADIENE(1,4 AND 1,2 ADDITION)
Polystyrene-block-polybutadiene-block-polystyrene styrene 30 wt. %, average Mw ~140,000 by GPC, contains <0.5 wt. % antioxidant | [EINECS(EC#)]
618-370-2 | [Molecular Formula]
C36H42X2 | [MDL Number]
MFCD00134010 | [MOL File]
9003-55-8.mol | [Molecular Weight]
474.72 |
| Chemical Properties | Back Directory | [Appearance]
solid or viscous liquid, depending upon the degree of polymerisation | [Melting point ]
253 °C | [density ]
1.04 g/mL at 25 °C
| [refractive index ]
1.57 | [solubility ]
solvents with solubility parameters between 7.7 and 9.4: soluble
| [form ]
slab/chunk
| [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents. | [LogP]
2.700 (est) | [IARC]
3 (Vol. 19, Sup 7) 1987 | [EPA Substance Registry System]
Styrene 1,3-butadiene polymer (9003-55-8) |
| Hazard Information | Back Directory | [Chemical Properties]
solid or viscous liquid, depending upon the degree of polymerisation | [Usage]
Molded or extruded into toys, packaging, appliances, communication cassettes, dinnerware and serviceware. | [Uses]
Molded or extruded into toys, packaging, appliances, communication cassettes, dinnerware and serviceware. | [Definition]
ChEBI: Styrene-butadiene copolymer is a polymer. | [Production Methods]
SBR is prepared mainly by emulsion and solution polymerization
in a free-radical process with a mercaptan, such as
dodecylmercaptan, which is used as a chain-transfer agent
to control molecular weight. In the emulsion process, a soapstabilized
water emulsion of styrene and butadiene is polymerized in continuous reactors to form SBR elastomer.
“Cold” SBR is produced at a temperature of 5–10°C, and
“hot” SBR at about 50°C . Solution SBR is typically
made in hydrocarbon solution with an n-butyllithium initiator.
The major differences between emulsion and solution
styrene–butadiene are in the linearity and molecular-weight
distribution of the polymer chains. In nonpolar solvents, the
tendency is to produce block copolymer, but random copolymers
are formed in polar solvents. SBR can be vulcanized
similar to natural rubber but generally requires less sulfur and
is more accelerated because of its lowunsaturation. | [Hazard]
Questionable carcinogen. | [Health Hazard]
Styrene Butadiene Rubber is prepared in large quantities for tire treads and other, similar uses. The properties, molecular weight, and percentage of monomer can all be controlled in the polymerization process. Hazards of the SBR industry have been identified and related mostly to the monomers and additives. Contact dermatitis and leukemia have been associated with solvent and additive use but not with the actual polymer itself (Checkoway et al., 1984; Kilpikari, 1982). Epidemiological studies in the industry have not revealed a significant increase in disease or causes of death (Matanoski and Schwartz, 1987; Meinhardt et al., 1982). The hazards of the butadiene and styrene monomers were discussed previously. | [Solubility in organics]
Chloroform, dichloromethane, hexane, MEK, toluene | [Toxics Screening Level]
Due to a lack of available toxicity data, the ITSL for Styrene-butadiene polymer is being set at 0.1 μg/m3 with annual averaging.
|
| Safety Data | Back Directory | [WGK Germany ]
3
| [RTECS ]
WL6478000
| [TSCA ]
TSCA listed | [Safety Profile]
An eye irritant. Questionable carcinogen. When heated to decomposition it emits acrid smoke and irritating fumes. See also POLYMERS, INSOLUBLE. |
| Questions And Answer | Back Directory | [Description]
By far the most widely used type of synthetic rubber, its consumption for all applications is four times that of polybutadiene, its nearest competitor, and 1.5 times that of all other elastomers combined. Its manufacture involves copolymerization of three parts butadiene with one part styrene. These materials are suspended in finely divided emulsion form in a large proportion of water, in the presence of a soap or detergent. Also present in small amounts are an initiator or catalyst which is usually a peroxide, and a chain-modifying agent such as dodecyl mercaptan.
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