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ChemicalBook--->CAS DataBase List--->874-42-0

874-42-0

874-42-0 Structure

874-42-0 Structure
IdentificationMore
[Name]

2,4-Dichlorobenzaldehyde
[CAS]

874-42-0
[Synonyms]

2,4-DCAD
2,4-DICHLOROBENZALDEHYDE
AKOS BBS-00003196
DICHLOROBENZALDEHYDE
DICHLOROBENZALDEHYDE(2,4-)
2,4-dichloro-benzaldehyd
2,4-Dichlorobenzaldehyde,98%
Benzaldehyde, 2,4-dichloro-
20) 2,4-DICHLORO BENZALDEHYDE
[EINECS(EC#)]

212-861-1
[Molecular Formula]

C7H4Cl2O
[MDL Number]

MFCD00003305
[Molecular Weight]

175.01
[MOL File]

874-42-0.mol
Chemical PropertiesBack Directory
[Appearance]

light yellow to beige crystalline powder, crystals
[Melting point ]

64-69 °C (lit.)
[Boiling point ]

233 °C (lit.)
[bulk density]

700kg/m3
[density ]

1.3456 (rough estimate)
[refractive index ]

1.5756 (estimate)
[Fp ]

135 °C
[storage temp. ]

Store below +30°C.
[form ]

Crystalline Powder, Crystals and/or Chunks
[color ]

Light yellow to beige
[Water Solubility ]

<0.1 g/100 mL at 24 ºC
[Sensitive ]

Air Sensitive
[BRN ]

471601
[CAS DataBase Reference]

874-42-0(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzaldehyde, 2,4-dichloro-(874-42-0)
[EPA Substance Registry System]

874-42-0(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C,N,Xi
[Risk Statements ]

R34:Causes burns.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

2
[Autoignition Temperature]

440 °C
[Hazard Note ]

Corrosive
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29130000
[Toxicity]

LD50 orally in Rabbit: 3470 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Chlorine-->Acetylacetone-->2,4-Dichlorotoluene-->Metallic oxides-->2,4-Dichlorobenzyl chloride-->ALPHA,ALPHA,2,4-TETRACHLOROTOLUENE-->2,5-DICHLOROBENZALDEHYDE-->Methanediol, (2,4-dichlorophenyl)-, diacetate-->(NE)-N-[(2,4-dichlorophenyl)methylidene]hydroxylamine-->2,4-DICHLOROBENZYL MERCAPTAN-->2,4-Dichlorophenylacetic acid-->2,4-DICHLOROBENZALDEHYDE OXIME-->1,3-DICHLORO-4-IODOBENZENE-->2,4-Dichlorobenzyl alcohol-->Formic acid-->2,4-Dichlorobenzoyl chloride
[Preparation Products]

Diniconazole-->Diclobutrazol-->2,4-Dichloro-5-nitrobenzalehyde-->2,4-Dichlorobenzoic acid-->2,4-Difluorobenzaldehyde
Hazard InformationBack Directory
[General Description]

White crystalline solid or off-white chunky solid with black specks and a pungent odor. Average shelf life 1 year in a closed container.
[Reactivity Profile]

2,4-DICHLOROBENZALDEHYDE(874-42-0) is incompatible with iron, oxygen and oxygen-containing materials. 2,4-DICHLOROBENZALDEHYDE(874-42-0) is also incompatible with strong oxidizers and strong bases.
[Air & Water Reactions]

Sensitive to light. May also be sensitive to prolonged exposure to air and moisture. Insoluble in water.
[Fire Hazard]

This compound is combustible.
[Chemical Properties]

light yellow to beige crystalline powder, crystals
[Uses]

2,4-Dichlorobenzaldehyde is used in the synthesis of platelet aggregation inhibitors. Also used in the preparation of novel Schiff bases containing quinazolinone rings.
[Synthesis Reference(s)]

Tetrahedron Letters, 30, p. 3677, 1989 DOI: 10.1016/S0040-4039(01)80481-0
[Purification Methods]

Crystallise the aldehyde from EtOH or ligroin. [Beilstein 7 IV 575.]
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2,4-Dichlorobenzaldehyde(874-42-0).msds
Spectrum DetailBack Directory
[Spectrum Detail]

2,4-Dichlorobenzaldehyde(874-42-0)MS
2,4-Dichlorobenzaldehyde(874-42-0)1HNMR
2,4-Dichlorobenzaldehyde(874-42-0)13CNMR
2,4-Dichlorobenzaldehyde(874-42-0)IR1
2,4-Dichlorobenzaldehyde(874-42-0)IR2
2,4-Dichlorobenzaldehyde(874-42-0)IR3
2,4-Dichlorobenzaldehyde(874-42-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2,4-Dichlorobenzaldehyde, 98%(874-42-0)
[Alfa Aesar]

2,4-Dichlorobenzaldehyde, 98%(874-42-0)
[Sigma Aldrich]

874-42-0(sigmaaldrich)
[TCI AMERICA]

2,4-Dichlorobenzaldehyde,>95.0%(GC)(874-42-0)
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