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ChemicalBook--->CAS DataBase List--->86-52-2

86-52-2

86-52-2 Structure

86-52-2 Structure
IdentificationMore
[Name]

1-Chloromethyl naphthalene
[CAS]

86-52-2
[Synonyms]

1-(CHLOROMETHYL)NAPHTHALENE
1-CHLOROMETHYLNAPHTHYL
1-NAPHTHYLMETHYL CHLORIDE
2,5-BIS[(1,3-DIOXOBUTYL)AMINO]BENZENESULFONIC ACID
2,5-DIACETOACETAMIDO BENZENE SULFONIC ACID
AKOS BBS-00004040
CHLOROMETHYLNAPHTHALENE(1-)
1-(Chlormethyl)naftalen
1-(chloromethyl)-naphthalen
1-(Chloromethyl)naphthene
1-chloromethyl-naphthalen
1-Menaphthyl chloride
1-menaphthylchloride
alpha-(Chloromethyl)naphthalene
alpha-chloromethyl-naphthalen
alpha-Naphthylmethyl chloride
alpha-naphthylmethylchloride
-Menaphthylchloride
Naphthalene, alpha-(chloromethyl)-
Naphthalene,1-(chloromethyl)-
[EINECS(EC#)]

201-678-2
[Molecular Formula]

C11H9Cl
[MDL Number]

MFCD04972525
[Molecular Weight]

176.64
[MOL File]

86-52-2.mol
Chemical PropertiesBack Directory
[Appearance]

Solid
[Melting point ]

32 °C(lit.)
[Boiling point ]

291 °C
[density ]

1.18 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.635(lit.)
[Fp ]

>230 °F
[storage temp. ]

Refrigerator
[form ]

Liquid After Melting
[color ]

deep brown
[Specific Gravity]

1.18
[Water Solubility ]

Insoluble in water.
[Sensitive ]

Moisture Sensitive
[BRN ]

636885
[InChIKey]

XMWGTKZEDLCVIG-UHFFFAOYSA-N
[CAS DataBase Reference]

86-52-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Naphthalene, 1-(chloromethyl)-(86-52-2)
[EPA Substance Registry System]

86-52-2(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C,Xn
[Risk Statements ]

R21/22:Harmful in contact with skin and if swallowed .
R34:Causes burns.
R36/37/38:Irritating to eyes, respiratory system and skin .
R36:Irritating to the eyes.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S20:When using, do not eat or drink .
S27:Take off immediately all contaminated clothing .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
[RTECS ]

QJ2800000
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

29036990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium carbonate-->Paraformaldehyde-->1-Methylnaphthalene
[Preparation Products]

alpha-(1-Naphthylmethyl)-2-tetrahydrofuranpropionic acid diethylaminoethyl ester oxalate-->1-NAPHTHALENEMETHYLAMINE-->1-Naphthalenemethanol-->1,2-BIS(1-NAPHTHYL)ETHANE-->5-bromonaphthalene-1-carboxylic acid-->3-METHOXY-4-(1-NAPHTHYLMETHOXY)BENZALDEHYDE-->(2-methyl-1-naphthyl)acetonitrile-->propyl 2-naphthalen-1-ylacetate-->1-(1-naphthylmethyl)-1H-indole-2,3-dione-->(naphthalen-4-yl)methanesulfonyl chloride-->(1-Naphthyl)methyl Methacrylate-->3-[Methyl(1-naphthalenylmethyl)amino]-1-phenyl-1-Propanone-->(1-NAPHTHYLMETHYL)TRICHLOROSILANE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-Chloromethyl naphthalene(86-52-2).msds
Hazard InformationBack Directory
[Chemical Properties]

Solid
[Uses]

1-(Chloromethyl)naphthalene is a key material for synthesis dye pigment and as fluorescent brightening agent. It is employed in synthetic resin and medicine. Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives produce ortho- or para-substituted carbocycles in satisfactory to excellent yields.
[General Description]

Kinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.
Spectrum DetailBack Directory
[Spectrum Detail]

1-Chloromethyl naphthalene(86-52-2)MS
1-Chloromethyl naphthalene(86-52-2)1HNMR
1-Chloromethyl naphthalene(86-52-2)13CNMR
1-Chloromethyl naphthalene(86-52-2)IR1
1-Chloromethyl naphthalene(86-52-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1-(Chloromethyl)naphthalene, 95%(86-52-2)
[Alfa Aesar]

1-(Chloromethyl)naphthalene, 94%(86-52-2)
[Sigma Aldrich]

86-52-2(sigmaaldrich)
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