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ChemicalBook--->CAS DataBase List--->827-54-3

827-54-3

827-54-3 Structure

827-54-3 Structure
IdentificationMore
[Name]

2-Vinylnaphthalene
[CAS]

827-54-3
[Synonyms]

2-VINYLNAPHTHALENE
BETA-VINYLNAPHTHALENE
VINYLNAPHTHALENE-2
2-EthenyInaphthalene
2-ethenyl-naphthalen
2-ethenylnaphthalene
2-VINYLNAPHTHALENE, 99+%
2-VINYLNAPHTHALIN 98%
2-Vinylnaphthalene, stabilized, 98%
Naphthalene, 2-ethenyl-
2-VINYLNAPHTHALENE , STABILIZED WITH CA 0.4% 4-T-BUTYLCATECHOL
2-Vinylnaphthalene, 97%, stab. with ca 0.4% 4-tert-butylcatechol
(2-Naphthyl)ethylene
b-Vinylnaphthalene
2-Vinylnaphthalene, 98%, stabilized
2-Vinylnaphthalene, 97%, stab. with ca 0.4% 4-t-butylcatechol
[EINECS(EC#)]

212-573-6
[Molecular Formula]

C12H10
[MDL Number]

MFCD00004125
[Molecular Weight]

154.21
[MOL File]

827-54-3.mol
Chemical PropertiesBack Directory
[Appearance]

Tan powder
[Melting point ]

64-68 °C (lit.)
[Boiling point ]

135 °C (18 mmHg)
[density ]

1.1092 (estimate)
[refractive index ]

1.4840 (estimate)
[Fp ]

>230 °F
[storage temp. ]

Keep Cold
[form ]

Powder
[color ]

White to slightly beige or yellow
[Water Solubility ]

INSOLUBLE
[BRN ]

2038190
[InChIKey]

KXYAVSFOJVUIHT-UHFFFAOYSA-N
[CAS DataBase Reference]

827-54-3(CAS DataBase Reference)
[NIST Chemistry Reference]

Naphthalene, 2-ethenyl-(827-54-3)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R20/22:Harmful by inhalation and if swallowed .
R36/38:Irritating to eyes and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[Hazard Note ]

Keep Cold
[HS Code ]

29029090
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Vinylnaphthalene(827-54-3).msds
Hazard InformationBack Directory
[Chemical Properties]

Tan powder
[Application]

Used in plastic scintillators, neutron detectors and other demanding device applications. Poly(2-vinyl naphthalene) is synthesized by free radical or anionic living polymerization 2-vinylnaphthalene.
[Uses]

2-Vinylnaphthalene is employed in the synthesis of various copolymers such as Poly (sodium styrenesulfonate-co-2-vinyl-napthalene) copolymer?and Poly (2-vinylnapthalene-alt-maleic acid)-graft-polystyrene. The latter finds applications as a photoactive polymer micelle and stabilizer for polystyrene latexes.
[Definition]

ChEBI: A vinylnaphthalene carrying a vinyl group at position 2.
[Synthesis Reference(s)]

Tetrahedron Letters, 24, p. 2723, 1983 DOI: 10.1016/S0040-4039(00)88005-3
[General Description]

2-Vinylnaphthalene (2VNP) can be prepared by the alkylation of naphthalene to I-and 2 ethylnapthalenes followed by dehydrogenation, or by oxidation followed by dehydration. 2VNP is the monomer for poly-(2-vinylnapthalene).
[Purification Methods]

The flammable solid can be fractionally distilled under reduced pressure using a spinning-band column; dry it with CaH2 and again distil it under vacuum. It crystallises from aqueous MeOH, EtOH (m 66o) or pet ether (m 66-66.5o). Store it in sealed ampoules in a freezer. The picrate has m 91-92o (from EtOH). [Beilstein 5 III 1775, 5 IV 1833.] It is an irritant.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Vinylnaphthalene(827-54-3)MS
2-Vinylnaphthalene(827-54-3)1HNMR
2-Vinylnaphthalene(827-54-3)13CNMR
2-Vinylnaphthalene(827-54-3)IR1
2-Vinylnaphthalene(827-54-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Vinylnaphthalene, stabilized, 98%(827-54-3)
[Alfa Aesar]

2-Vinylnaphthalene, 97%, stab. with ca 0.4% 4-tert-butylcatechol(827-54-3)
[Sigma Aldrich]

827-54-3(sigmaaldrich)
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