Identification | Back Directory | [Name]
[Ru(bpz)3][PF6]2 | [CAS]
80907-56-8 | [Synonyms]
[Ru(bpz)3][PF6]2 [Ru(bpz)3][PF6]2 95% [Ru(bpz)3][PF6]2 AldrichCPR Tris (2,2'-bipyrazine) ruthenium hexafluoroborate Tris(2,2'-bipyrazine)ruthenium(II) hexafluorophosphate, 95% | [Molecular Formula]
C24H18F12N12P2Ru | [MDL Number]
MFCD27952557 | [MOL File]
80907-56-8.mol | [Molecular Weight]
720.53 |
Chemical Properties | Back Directory | [Melting point ]
162-210°C (The MP data is a DECOMP) (lit.) | [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Powder | [color ]
red | [Sensitive ]
air sensitive |
Questions And Answer | Back Directory | [Reaction]
- Endoperoxide synthesis by photocatalytic aerobic [2+2+2] cycloadditions.
- Aerobic oxidation of a tertiary aliphatic amine under visible-light photocatalysis. Facile synthesis of methylenebridged bis-1,3-dicarbonyl compounds.
- Hydrophosphinylation of unactivated alkenes with secondary phosphine oxides under visible-light photocatalysis.
- Photooxygenation of aryl cyclopropanes via visible light photocatalysis.
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Hazard Information | Back Directory | [Uses]
[Ru(bpz)3][PF6]2 may be employed as a photocatalyst during the preparation of cyclopentylamine derivatives, via visible light-assisted cycloaddition reaction of N-arylcyclopropylamines with styrene derivatives. It may also be employed for the photocatalytic synthesis of trans-substituted cyclohexene derivative. | [General Description]
[Ru(bpz)3][PF6]2 can be prepared from 2-iodopyrazine. | [reaction suitability]
core: ruthenium reaction type: Photocatalysis reagent type: catalyst |
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