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ChemicalBook--->CAS DataBase List--->75777-87-6

75777-87-6

75777-87-6 Structure

75777-87-6 Structure
IdentificationBack Directory
[Name]

Tris[4,4'-di-tert-butyl-(2,2')-bipyridine]ruthenium(III) dihexafluorophosphate
[CAS]

75777-87-6
[Synonyms]

Tris[4,4'-bis(t-butyl)-2,2'-bipyridine]ruthenium(II) hexafluorophosphate, 95%
Tris[4,4'-di-tert-butyl-(2,2')-bipyridine]ruthenium(III) dihexafluorophosphate
[Molecular Formula]

C54H72F12N6RuP2
[MOL File]

75777-87-6.mol
[Molecular Weight]

1051.25
Chemical PropertiesBack Directory
[Melting point ]

>300 °C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[color ]

red
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[TSCA ]

No
Questions And AnswerBack Directory
[Reaction]

  1. Photoredox catalysed C-P bond formation reactions – visible light mediated oxidative phosphonylations of amines.
  2. Photoredox catalysis as an efficient tool for the aerobic oxidation of amines and alcohols.
  3. Visible-light induced, direct synthesis of polysubstituted furans from cyclopropyl ketones
Reactions of 75777-87-6
Hazard InformationBack Directory
[Uses]

This ruthenium photocatalyst facilitates a variety of transformations using visible light.
Spectrum DetailBack Directory
[Spectrum Detail]

Tris[4,4'-di-tert-butyl-(2,2')-bipyridine]ruthenium(III) dihexafluorophosphate(75777-87-6)1HNMR
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