Identification | More | [Name]
TIN(IV) IODIDE | [CAS]
7790-47-8 | [Synonyms]
STANNIC IODIDE TIN IODIDE TIN(IV) IODIDE Stannane, tetraiodo- tetraiodo-stannan Tetraiodostannane tetraiodo-Stannane Tetraiodotin Tin iodide (SnI4) Tin(iv) iodide (1:4) tin(iv)iodide(1:4) Tintetraiodide Tiniodideorangextl Tin(Ⅳ)iodide TIN(IV) IODIDE 95% TIN(IV) IODIDE, 99.999% ultradry,99.998%metalsbasis Tin(IV)iodide,95% tin(iv) iodide, ultra dry Tin(IV) iodide, ultra dry, 99.998% (metals basis) | [EINECS(EC#)]
232-208-4 | [Molecular Formula]
I4Sn | [MDL Number]
MFCD00036272 | [Molecular Weight]
626.33 | [MOL File]
7790-47-8.mol |
Chemical Properties | Back Directory | [Appearance]
Brown powder | [Melting point ]
144 °C | [Boiling point ]
364 °C | [density ]
4.47 g/mL at 25 °C(lit.)
| [refractive index ]
2.106 | [Fp ]
340°C | [solubility ]
Soluble in alcohol, benzene, carbon disulfide, chloroform and ether. | [form ]
powder
| [color ]
Red | [Specific Gravity]
4.473 | [Water Solubility ]
Soluble in alcohol, benzene, CS{2}, chloroform, and ether. Decomposes in water | [Hydrolytic Sensitivity]
8: reacts rapidly with moisture, water, protic solvents | [Sensitive ]
Moisture Sensitive | [Merck ]
14,8777 | [Exposure limits]
ACGIH: TWA 2 mg/m3 NIOSH: IDLH 100 mg/m3; TWA 2 mg/m3 | [CAS DataBase Reference]
7790-47-8(CAS DataBase Reference) | [EPA Substance Registry System]
Stannane, tetraiodo- (7790-47-8) |
Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . R34:Causes burns. R42/43:May cause sensitization by inhalation and skin contact . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) . S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3260 8/PG 2
| [WGK Germany ]
3
| [RTECS ]
XQ3675000
| [F ]
1-8-10-19 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28276000 | [Safety Profile]
Poison by intravenous
route. Strong reaction with N02Cl, (K+ S),
(Na + S). When heated to decomposition it
emits toxic fumes of I-. See also TIN
COMPOUNDS and IODIDES. | [Toxicity]
MLD in rats (mg/kg): 200 i.v. (Kolmer) |
Hazard Information | Back Directory | [Chemical Properties]
Brown powder | [Uses]
Tin(IV) iodide is used in the preparation of tin(IV) oxide and tin(II) oxide. It reacts with hydroiodic acid to get rare tin hexaiodide. It forms tetraiodobis triphenylphosphine tin complexes by reacting with triphenylphosphine, which finds application in toothpaste formulation. Further, it acts as analytical reagents and also used in organic synthesis. | [Purification Methods]
It is recrystallised from anhydrous CHCl3, dry it under vacuum and store it in a vacuum desiccator. It sublimes at 180o. |
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