| Identification | More | [Name]
Tributyl(vinyl)tin | [CAS]
7486-35-3 | [Synonyms]
ETHENYLTRIBUTYLSTANNANE
TIN VINYLTRIBUTYL
TRIBUTYLETHENYLSTANNANE
TRIBUTYLSTANNYLETHYLENE
TRIBUTYLVINYLSTANNANE
TRIBUTYL(VINYL)TIN
TRI-N-BUTYL(VINYL)TIN
VINYLTRIBUTYLSTANNANE
VINYLTRIBUTYLTIN
VINYLTRI-N-BUTYLTIN
Stannane, tributylvinyl-
Tri-n-butylstannylethylene~Tri-n-butyl(vinyl)stannane
Tri-n-butyl(vinyl)tin,96%
tri-n-butyl(vinyl)stannane
tri-n-butylstannylethylene
Tributyl(vinyl)stannane, Tributylstannylethylene, Vinyltributylstannane
Tributylstannylethylene, Vinyltributylstannane
Stannane, tributylethenyl-
(Tributylstannyl)ethene
1-(Tributylstannyl)ethene | [EINECS(EC#)]
231-291-4 | [Molecular Formula]
C14H30Sn | [MDL Number]
MFCD00009421 | [Molecular Weight]
317.1 | [MOL File]
7486-35-3.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to pale yellow liquid | [Melting point ]
<0°C | [Boiling point ]
104-106 °C/3.5 mmHg (lit.) | [density ]
1.085 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.478(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Refrigerator | [Specific Gravity]
1.085 | [Water Solubility ]
Not miscible or difficult to mix in water. | [Hydrolytic Sensitivity]
1: no significant reaction with aqueous systems | [BRN ]
3537662 | [InChIKey]
QIWRFOJWQSSRJZ-UHFFFAOYSA-N | [CAS DataBase Reference]
7486-35-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Stannane, tributylethenyl-(7486-35-3) |
| Safety Data | Back Directory | [Hazard Codes ]
T,N | [Risk Statements ]
R21:Harmful in contact with skin.
R25:Toxic if swallowed.
R36/38:Irritating to eyes and skin .
R48/23/25:Toxic: danger of serious damage to health by prolonged exposure through inhalation and if swallowed .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S35:This material and its container must be disposed of in a safe way .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 2788 6.1/PG 3
| [WGK Germany ]
3
| [F ]
13 | [TSCA ]
No | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29312000 |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless to pale yellow liquid | [Uses]
Tributyl(vinyl)tin is used as a reagent in the palladium catalyzed synthesis of allyl and benzyl ethers. Tributyl(vinyl)tin is also a vinyl nucleophile for bromoacetylene and bromoaromatics. | [Purification Methods]
Fractionate the stannane under reduced pressure and taking the middle fraction to remove impurities such as (n-Bu)3SnCl. [Seyferth & Stone J Am Chem Soc 79 515 1957, Beilstein 16 III 1279.] |
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