Identification | Back Directory | [Name]
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) | [CAS]
72287-26-4 | [Synonyms]
PDCL2(DPPF) (dppf)2PdCl2 dichloropalladiuM [1,1′-Bis(diphenylph (II)dichloromethane adduct [1,1'-Bis(diphenylphosphino)ferrocene]dichloropall [1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADI -Bis(diphenylphosphino)ferrocene]dichloropalladium(II) [1,1'-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium [bis(diphenylphosphino)ferrocene]PdCl2/ dichloromethane 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II) 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II) DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(Ⅱ) 1'-Bis(diphenylphosphino)ferrocene-palladiuM(II) dichloride [1,1''-Bis(diphenyphosphino)ferrocene]dichloropalladium(II) Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE 1,1'-Bis(diphenylphosphiNA)ferrocene palladiuM(II)dichloride 1,1'-Bis(diphenylphosphino)ferrocene-palladium dichloride,98% 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99% [1,1''-Bis-(diphenylphosphino)-ferrocene]-palladous dichloride [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II): 99.9% 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99.9% 1,1'-Bis(diphenylphosphino)ferrocenepalladiuM( II) dichloride Pd (1,1'-Bis(diphenylphosphimoferrocene)dichloropalladium (II)-CH2CL2 Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II), (DPPF)PdCl2 [1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
PdCl2(dppf)
1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride [Pd(dppf)Cl2] (1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE)-P ALLADIUM(II) CHLORIDE CH2CL2 COMPL Palladium, 1,1-bis(diphenylphosphino-.kappa.P)ferrocenedichloro-, (SP-4-2)- Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2 Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add -Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) DICHLOROMETHANE ADDUCT 1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM() COMPLEX WITH DICHLOROMETHANE 1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane [1,1'-Bis(diphenylphosphino)ferrocen]dichloropalladiuM(II),
coMplex with dichloroMethane [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(ii) dichloromethane complex (1:1) dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloromethane complex (1:1) [1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloride dichloromethane complex (1:1) 1,1'-Bis(diphenylphosphino)ferroceneüpalladium(II) chloride, 1:1 complex with dichloromethane | [EINECS(EC#)]
460-040-3 | [Molecular Formula]
C34H28Cl2FeP2Pd 10* | [MDL Number]
MFCD00015757 | [MOL File]
72287-26-4.mol | [Molecular Weight]
731.7 |
Chemical Properties | Back Directory | [Melting point ]
275-280 °C(lit.)
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Soluble in dichloromethane. | [form ]
powder | [color ]
red to very dark red | [Stability:]
Hygroscopic |
Questions And Answer | Back Directory | [Uses]
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds.Is used in preparation of Nucleosides as Ectonucleotidase inhibitors. |
Hazard Information | Back Directory | [Chemical Properties]
Red solid | [Usage]
suzuki reaction | [Application]
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions: Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity. Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives. Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes. | [reaction suitability]
reagent type: catalyst reaction type: Cross Couplings | [Mechanism of action]
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.
R = usually sp2
hybridised carbon X = usually I, Br, Cl or OTf The nature of R' and M are dependant upon the specic coupling being performed
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