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ChemicalBook--->CAS DataBase List--->68478-92-2

68478-92-2

68478-92-2 Structure

68478-92-2 Structure
IdentificationBack Directory
[Name]

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane
[CAS]

68478-92-2
[Synonyms]

Karstedt cat
KARSTEDT CATALYST
platinumvinylsiloxane
Karstedt Catalyst Soluti
Karstedt Catalyst Solution
PLATINUM-DIVINYLTETRAMETHYLDISILOXANE
PLATINUM-DIVINYLTETRAMETHYLDISILOXANE COMPLEX
solutioninvinylterminatedpolydimethylsiloxane
pt(0)-1,3-divinyl-tetrame-disiloxane compl 0.100
PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisilox
1,3-diethenyl-1,1,3,3-tetramethyldisiloxane platinum
PlatinuM(o) 1,3 divinyl-1,1,3,3 tetraMethyldisiloxane
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane
Platinum-divinyltetramethyldisiloxane complex inxylene
1,3-Divinyl-1,1,3,3-tetramethyl-disiloxane-platinum (0)
Platinum-Divinyltetramethyldisiloxane (in Xylene)low colour
PLATINUM(0)-1,3-DIVINYL-1,1,3,3-TETRAMETHYLDISILOXANE COMPLEX
Platinum,1,3-diethenyl-1,1,3,3-tetramethyldisiloxanecomplexes
PLATINUM DIVINYLTETRAMETHYLDISILOXANE COMPLEX, xylene solution
PLATINUM-DIVINYLTETRAMETHYLDISILOXANE COMPLEX IN XYLENE LOW COLOR
PLATINUM-DIVINYLTETRAMETHYLDISILOXANE COMPLEX IN XYLENE: (2.1-2.4%PT)
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution
PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, Pt 2000 ppM
PT(0)-1,3-DIVINYL-TETRAME-DISILOXANE COM PL 0.100M IN POLY(DIME-SILOXANE),VINYL
PLATINUM(0)-1,3-DIVINYL-TETRAME-DISILOXA NE IN POLY(DI-ME-SILOXANE),VINYLTERMINA
PlatinuM (0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, soln. in Isopropanol
PLATINUM(0)-1,3-DIVINYL-1,1,3,3-TETRAMEDI-SILOXANE COMPLEX, SOLUTION IN XYLENES (PT~2%)
PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, in poly(diMethylsiloxane)
PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex, 20% Pt, Product of UMicore
PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex solution in xylene, Pt ~2 %
Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution [in dimethylsiloxane]
Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, soln. in vinyl terminated polydimeth
platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, soln. in vinyl terminated polydimethylsiloxane
Karstedt Catalyst Solution Hydrosilylation. Usually supplied in propan-2-ol/ divinyltetramethyldisiloxane
Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex, solution in vinyl terminated polydimethylsiloxane
Platinum(0) - 1,3-Divinyltetramethyldisiloxane Complex (19.0-21.5% as Pt) (contains 1,3-Divinyltetramethyldisiloxane)
PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex solution 0.1 M in poly(diMethylsiloxane), vinyl terMinated
PlatinuM(0)-1,3-divinyl-1,1,3,3-tetraMethyldisiloxane coMplex solution 0.05 M in poly(diMethylsiloxane), vinyl terMinated
Platinum, 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane complexes platinum-divinyltetramethyldisiloxane complex karstedt catalyst platinum vinylsiloxane platinumvinylsiloxane Platinum,1,3-diethenyl-1,1,3,3-tetramethyldisiloxane complexes
[EINECS(EC#)]

270-844-4
[Molecular Formula]

C8H18OPtSi2
[MDL Number]

MFCD00151662
[MOL File]

68478-92-2.mol
[Molecular Weight]

381.48
Chemical PropertiesBack Directory
[Appearance]

pale yellow solution
[Melting point ]

12-13 °C
[Boiling point ]

138 °C
[density ]

0.984 g/mL at 25 °C
[vapor pressure ]

7 mm Hg ( 21 °C)
[refractive index ]

1.4954
[Fp ]

86 °F
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

clear liquid
[color ]

Light yellow to Yellow to Green
[Specific Gravity]

0.984
[Stability:]

Flammable. Incompatible with reducing agents, oxidizing agents. Contact with water yields hydrogen gas.
[Water Solubility ]

Miscible with toluene, xylene, isopropyl alcohol, double-vinyl silicone oil and vinyl terminated poly(dimethylsiloxane). Immiscible with water.
[Hydrolytic Sensitivity]

4: no reaction with water under neutral conditions
[Sensitive ]

Moisture Sensitive
[EPA Substance Registry System]

Platinum, 1,3-diethenyl-1,1,3,3-tetramethyldisiloxane complexes (68478-92-2)
Hazard InformationBack Directory
[Chemical Properties]

pale yellow solution
[Description]

Platinum (0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex Solution is a kind of yellow liquid with a chemical formula of O[Si(CH3)2CH=CH2]2Pt and a molecular weight of 381.48. Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex solution (Pt-DVTMDS) has emerged as a novel organometallic compound with diverse applications in recent scientific research. This compound represents a coordination complex of platinum(0) and divinyl-1,1,3,3-tetramethyldisiloxane complex solution (DVTMDS). It has proven valuable in synthesizing diverse organometallic compounds, including gold(I)-DVTMDS and palladium(II)-DVTMDS. Furthermore, it has played a significant role in investigating chemical reactions, such as the catalytic hydrogenation of aldehydes and ketones theand oxidation of organic compounds. It was used as a precursor of the metallic phase to obtain a highly active electrochemical system Pt/SnO2 catalyst with a low metal load[1].
[Uses]

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane Complex Solution is a catalyst in the preparation of phenol functional silanes which are used as adhesion promoters.
[General Description]

Platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex is a platinum complex, commonly known as a Karstedt′s catalyst. It is generally employed as a catalyst in hydrosilylation reactions.
[reaction suitability]

core: platinum
reagent type: catalyst
Safety DataBack Directory
[Hazard Codes ]

T,Xi,Xn
[Risk Statements ]

61-10-20/21-37/38-41-62-36/37/38-38
[Safety Statements ]

53-16-26-36/37/39-45-36-36/37
[RIDADR ]

UN 1307 3/PG 3
[WGK Germany ]

3
[TSCA ]

Yes
[HS Code ]

28439000
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