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ChemicalBook--->CAS DataBase List--->2627-95-4

2627-95-4

2627-95-4 Structure

2627-95-4 Structure
IdentificationMore
[Name]

Divinyltetramethyldisiloxane
[CAS]

2627-95-4
[Synonyms]

1,1,3,3-TETRAMETHYL-1,3-DIVINYLDISILOXANE
1,3-diethenyl-1,1,3,3-tetramethyl-disiloxane
1,3-DIVINYL-1,1,3,3-TETRAMETHYLDISILOXANE
1,3-DIVINYLTETRAMETHYLDISILOXANE
DIVINYLTETRAMETHYLDISILOXANE
LABOTEST-BB LT00067562
TETRAMETHYL-1,3-DIVINYLDISILOXANE
1,1,3,3-Tetramethyl-1,3-divinylsiloxane
1,3-diethenyl-1,1,3,3-tetramethyl-disiloxan
Bisvinyltetramethyldisiloxane
CD6210
Disiloxane, 1,1,3,3-tetramethyl-1,3-divinyl-
Sym-tetramethyldi(ethenyl)disiloxane
tetramethyldivinyldisiloxane
Tetramethyldivinylsiloxane
Polydimethylsiloxane, vinyldimethylsiloxy terminated, viscosity 0.7 cSt.
1,3-Divinyltetramethyldisiloxane, 98+%
1,1,3,3-Tetramethyl-1,3-divinyldisiloxane(1,3-Divinyltetramethyldisiloxane)
1,3-Divinyltetramethyldisiloxane,min.97%
Disiloxane, 1,3-diethenyl-1,1,3,3-tetramethyl-
[EINECS(EC#)]

220-099-6
[Molecular Formula]

C8H18OSi2
[MDL Number]

MFCD00014933
[Molecular Weight]

186.4
[MOL File]

2627-95-4.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless or yellowish transparent liquid
[Melting point ]

-99 °C (lit.)
[Boiling point ]

139 °C (lit.)
[density ]

0.81 g/mL at 20 °C(lit.)
[vapor pressure ]

17hPa at 25℃
[refractive index ]

n20/D 1.411(lit.)
[Fp ]

76 °F
[storage temp. ]

Flammables area
[form ]

liquid
[color ]

colorless
[Specific Gravity]

0.811
[Water Solubility ]

insoluble
[Hydrolytic Sensitivity]

1: no significant reaction with aqueous systems
[Sensitive ]

Moisture Sensitive
[BRN ]

1762585
[InChIKey]

BITPLIXHRASDQB-UHFFFAOYSA-N
[LogP]

5.4 at 20℃
[CAS DataBase Reference]

2627-95-4(CAS DataBase Reference)
[NIST Chemistry Reference]

Disiloxane, 1,3-diethenyl-1,1,3,3-tetramethyl-(2627-95-4)
[EPA Substance Registry System]

1,3-Divinyl-1,1,3,3-tetramethyl disiloxane (2627-95-4)
Safety DataBack Directory
[Hazard Codes ]

F,Xi
[Risk Statements ]

R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
R10:Flammable.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 1993 3/PG 2
[WGK Germany ]

2
[RTECS ]

JM9235250
[F ]

10-21
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29319090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Acetone-->Ethoxydimethylvinylsilane-->Dimethylvinylsilane-->1,1,3,3-Tetramethyldisiloxane-->TRIISOPROPYLSILANOL-->Triethoxyvinylsilane-->N-METHYLETHYLENEDIAMINE
[Preparation Products]

6-Methoxy-2-vinylnaphthalene
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1,1,3,3-Tetramethyl-1,3-divinyldisiloxane(2627-95-4).msds
Hazard InformationBack Directory
[Chemical Properties]

Colorless or yellowish transparent liquid
[Uses]

Divinyl tetramethyl disiloxane could be used as a additives(intermediates) in the production process of addition silicone rubber, silicone gel, liquid silicone, vinyl silicone resin, vinyl silicone oil, platinum chromium compound and others. POTENTIAL VINYL NUCLEOPHILE IN CROSS-COUPLING REACTIONS. 1,3-Divinyltetramethyldisiloxane acts as a potential vinyl donor used in cross-coupling reactions. It is also involved in the copolymerization reaction with aromatic ketones.
[Flammability and Explosibility]

Flammable
[Properties and Applications]

Divinyltetramethyldisiloxane (DVTMSO) could used as a diolefin ligand in the complexes with d10-metal centers (M). This is a rather labile ligand capable of changing the π–π-bridging function to the chelating one in the ligand exchange reactions to form a stable six-membered cycle, for example, Pd(0)(CH2=CH–Si)2O. In addition, DVTMSO is the first representative of the series of unsaturated polysiloxanes, whose complexes, including those with Cu(I), serve as precursors for producing thin copper films by thermal disproportionation[1].
[References]

[1] T. Duzak. “Tetragonal cubanoid Cu4X4 in the isostructural π-complexes with divinyltetramethyldisiloxane: [Cu4X4(C8H18OSi2) (X = Cl, Br).” Russian Journal of Coordination Chemistry 35 6 (2009): 416–421.
Spectrum DetailBack Directory
[Spectrum Detail]

Divinyltetramethyldisiloxane(2627-95-4)MS
Divinyltetramethyldisiloxane(2627-95-4)1HNMR
Divinyltetramethyldisiloxane(2627-95-4)13CNMR
Divinyltetramethyldisiloxane(2627-95-4)IR1
Divinyltetramethyldisiloxane(2627-95-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Divinyltetramethyldisiloxane, 97%(2627-95-4)
[Alfa Aesar]

1,3-Divinyltetramethyldisiloxane, 96%, cont. up to 4% 1-vinyl-3-ethyltetramethyldisiloxane(2627-95-4)
[Sigma Aldrich]

2627-95-4(sigmaaldrich)
[TCI AMERICA]

1,3-Divinyltetramethyldisiloxane,>97.0%(GC)(2627-95-4)
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