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ChemicalBook--->CAS DataBase List--->65181-78-4

65181-78-4

65181-78-4 Structure

65181-78-4 Structure
IdentificationMore
[Name]

N,N'-Bis(3-methylphenyl)-N,N'-bis(phenyl)benzidine
[CAS]

65181-78-4
[Synonyms]

[1,1'-BIPHENYL]-4,4'-DIAMINE,N,N'-BIS(3-METHYLPHENYL)-N,N'-DIPHENYL-
4,4'-BIS[N-PHENYL-N-(M-TOLYL)AMINO]BIPHENYL
N,N'-BIS(3-METHYLPHENYL)-N,N'-BIS(PHENYL)BENZIDINE
N,N'-BIS(3-METHYLPHENYL)-N,N'-DIPHENYLBENZIDINE
N,N'-DIPHENYL-N,N'-DI(3-TOLYL)-4-BENZIDINE
N,N'-DIPHENYL-N,N'-DI(M-TOLYL)BENZIDINE
TPD
1’-biphenyl]-4,4’-diamine,n,n’-bis(3-methylphenyl)-n,n’-diphenyl-[
1’-Biphenyl]-4,4’-diamine,N,N’-bis(3-methylphenyl)-N,N’-diphenyl-[1
N,N-Dipehnyl-N,N-di(m-Tolyl)benzidine
4,4'-BIS(3-MethylPhenyl)-4,4'-Bis(Phenyl)-Benzidine
N,N'-Diphenyl-N,N'-di(3-methylphenyl)-1,1'-biphenyl-4,4'-diamine
N,N'-Diphenyl-N,N'-di(3-tolyl)-4-benzidine(TPD)
N N'-BIS(3-METHYLPHENYL)-N N'-DIPHENYL-&
N,N'-BIS-(3-METHYLPHENYL)-N,N'-BI-(PHENYL)-BENZIDINE
N,N'-Diphenyl-N,N'-bis(3-methylphenyl)-(1,1'-diphenyl)-4,4'-diamine
m-TPD
N,N'-bis(3-methylphenyl)-N,N'-diphenyl-benzidine TPD
N,N-DIPHENYL-N,N''-BIS (3-METHYLPHENYL) BENZIDINE
N,N'-Bis(3-methylphenyl)-N,N'-diphenyl-(1,1'-biphenyl)-4,4'-diamine dihydrochloride
[EINECS(EC#)]

413-810-8
[Molecular Formula]

C38H32N2
[MDL Number]

MFCD00144965
[Molecular Weight]

516.67
[MOL File]

65181-78-4.mol
Chemical PropertiesBack Directory
[Appearance]

solid
[Melting point ]

169°C
[Boiling point ]

680.1±55.0 °C(Predicted)
[density ]

1.37 g/cm3
[vapor pressure ]

3.356Pa at 25℃
[storage temp. ]

Sealed in dry,Room Temperature
[Water Solubility ]

Insoluble in water
[form ]

Powder
[pka]

-2.40±0.60(Predicted)
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[LogP]

4.29 at 20℃ and pH6.3-6.5
[Surface tension]

72.3mN/m at 242μg/L and 21.9℃
[CAS DataBase Reference]

65181-78-4(CAS DataBase Reference)
[EPA Substance Registry System]

65181-78-4(EPA Substance)
[Absorption]

λmax?352 nm?in THF
[color ]

White powder/crystals
[Description]

N,N′-Bis(3-methylphenyl)-N,N′-diphenylbenzidine, commonly abbreviated as TPD,?is widely used as hole transport materials in organic electronic devices.
Safety DataBack Directory
[Hazard Codes ]

N
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

3077
[WGK Germany ]

2
[HazardClass ]

9
[PackingGroup ]

III
[HS Code ]

29215900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sulfuric acid-->Acetic acid-->Potassium carbonate-->Xylene-->Sodium bisulfite-->Potassium dichromate-->Nitrobenzene-->Diphenylamine-->3-Iodotoluene
Hazard InformationBack Directory
[Chemical Properties]

solid
Questions And AnswerBack Directory
[Applications]

N,N′-Bis(3-methylphenyl)-N,N′-diphenylbenzidine, commonly abbreviated as TPD, is widely used as hole transport materials in organic electronic devices.
TPD is also used as a blue-violet light emitting material or host material on the phosphorescence organic light emitting diodes for its wide energy band is about 3.2 eV with highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) 5.5 eV and 2.3 eV respectively.
[Uses]

Hole transport material for electrophotographic photoconductor in xerography.
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

65181-78-4(sigmaaldrich)
[TCI AMERICA]

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