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ChemicalBook--->CAS DataBase List--->638-37-9

638-37-9

638-37-9 Structure

638-37-9 Structure
IdentificationMore
[Name]

SUCCINALDEHYDE
[CAS]

638-37-9
[Synonyms]

1,4-BUTANEDIAL
SDA
SUCCINALDEHYDE
SUCCINIC DIALDEHYDE
butanedial
Succindialdehyde
Butanedial,40%Solution
1,4-BUTANEDIAL, SOLUTION
Succinic aldehyde
BUTANDIAL
SUCCINALDEHYDE-FORMALDEHYDECOMPOSITE
[EINECS(EC#)]

211-333-8
[Molecular Formula]

C4H6O2
[MDL Number]

MFCD00192456
[Molecular Weight]

86.09
[MOL File]

638-37-9.mol
Chemical PropertiesBack Directory
[Appearance]

Liquid. Soluble in water, alcohol, and ether. The name succinaldehyde is often incorrectly used in commerce as a synonym for succinic anhydride.
[Boiling point ]

98.74°C (rough estimate)
[density ]

1.0650
[refractive index ]

1.4262
[storage temp. ]

Inert atmosphere,Store in freezer, under -20°C
[LogP]

-0.220 (est)
[CAS DataBase Reference]

638-37-9(CAS DataBase Reference)
[EPA Substance Registry System]

Butanedial (638-37-9)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

40
[Safety Statements ]

36/37
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Carbon-->Ozone-->2,5-Dihydro-2,5-dimethoxyfuran-->TRANS,TRANS,CIS-1,5,9-CYCLODODECATRIENE-->1,1-Dimethyl-2-methylenehydrazine-->N-NITROSODIMETHYLAMINE-->dimethylnitramine-->Dimethylaminoacetonitrile-->Dimethylamine-->1,1-Dimethylhydrazine
[Preparation Products]

TROPYL A ORMULPHENYLACETATE-->Tropinone-->endo-8-isopropyl-8-azabicyclo[3.2.1]octan-3-ol-->8-isopropyl-8-azabicyclo[3.2.1]octan-3-one-->1-PHENYLPYRROLE-->1,3-Oxazolidine
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

succinaldehyde(638-37-9).msds
Hazard InformationBack Directory
[Chemical Properties]

Liquid. Soluble in water, alcohol, and ether. The name succinaldehyde is often incorrectly used in commerce as a synonym for succinic anhydride.
[Uses]

Succinaldehyde (SA) was added directly into UF resins before application for plywood production; these urea-formaldehyde-succinaldehyde (UFSA) resins, as they were formed during curing, improved markedly the water resistance of the hardened UF bondline as well as decreased its formaldehyde emission.
[Definition]

ChEBI: Succinic aldehyde is an aldehyde.
[Preparation]

Preparation method of succinaldehyde: Using furan as the raw material, 2,5-Dihydro-2,5-dimethoxyfuran is prepared by electrolysis, followed by hydrogenation and hydrolysis to obtain succinaldehyde. Alternatively, Cyclododeca-1,5,9-triene can be used as the raw material. In ethyl acetate, at -20 to 10°C, it is oxidized with 3% ozone to produce triene ozonide. It is then subjected to catalytic hydrogenation with 5% lead-activated carbon at room temperature to prepare succinaldehyde.
[References]

[1] BENNETT S H. Organocatalytic Dimerization of Succinaldehyde[J]. Organic Syntheses, 2022. DOI:10.15227/orgsyn.099.0139.
[2] D. P. KAMDEM A. J A Pizzi. Durability of heat-treated wood[J]. European Journal of Wood and Wood Products, 2002, 60 1: 1-6. DOI:10.1007/s00107-001-0261-1.
[3] MCINTOSH J M. ChemInform Abstract: Robinson-Schopf Condensations with Succinaldehyde.[J]. ChemInform, 1988, 19 26. DOI:10.1002/chin.198826164.
[4] STEVEN H. BENNETT Prof. Dr V K A Dr Graeme Coulthard. Prostaglandin Total Synthesis Enabled by the Organocatalytic Dimerization of Succinaldehyde[J]. Chemical record, 2020, 20 9: 936-947. DOI:10.1002/tcr.202000054.
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