| Identification | More | [Name]
3-Methylpiperidine | [CAS]
626-56-2 | [Synonyms]
3-METHYLPIPERIDINE
3-PIPECOLINE
3PPC
BETA-PIPECOLIN
BETA-PIPECOLINE
Hexahydro-3-picoline
LABOTEST-BB LTBB000786
(R,S)-3-Methyl-piperidine
3-methyl-piperidin
3-methylpiperidine(corrosiveliquid,flammable,n.o.s.)
3-pipercoline(beta-)
beta-Methylpiperidine
3-Methylpiperidine,98%
3-PIPECOLINE 99.5%
3-PIPECOLINE (BETA-) 97+%
3-PIPECOLINE 3-METHYL PIPERIDINE
β-Pipecoline, 3-Pipecoline
3-Methylpiperidine ,99% | [EINECS(EC#)]
210-953-6 | [Molecular Formula]
C6H13N | [MDL Number]
MFCD00005994 | [Molecular Weight]
99.17 | [MOL File]
626-56-2.mol |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xi | [Risk Statements ]
R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S33:Take precautionary measures against static discharges .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S7/9:Keep container tightly closed and in a well-ventilated place . | [RIDADR ]
UN 1993 3/PG 2
| [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29333990 |
| Hazard Information | Back Directory | [General Description]
A colorless liquid with a characteristic odor. Less dense than water. Flash point less than 141°F. Contact may cause severe irritation to skin, eyes, and mucous membranes. Toxic by ingestion, inhalation and skin absorption. | [Reactivity Profile]
3-METHYLPIPERIDINE neutralizes acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Generates flammable gaseous hydrogen in combination with strong reducing agents, such as hydrides. | [Air & Water Reactions]
Highly flammable. Water soluble. | [Health Hazard]
May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. | [Fire Hazard]
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. | [Chemical Properties]
clear colorless to yellow liquid | [Uses]
3-Methylpiperidine, is used as a reactant for synthesis of Phenylpropenamide derivatives for anti-hepatitis B virus activity, CB2 receptor agonists for treatment of chronic pain, aurora kinase inhibitors, spiroimidazolidinone NPC1L1 inhibitors, 1,3,5-Oxadiazinones, selective serotonin 5-HT6 receptor antagonists. It is also used as a pharmaceutical intermediate and as a intermediate in organic synthesis. | [Purification Methods]
Purify it via the hydrochloride (m 172o). The hydrobromide has m 162-163o(from iso-PrOH). [Chapman et al. J Chem Soc 1925 1959, Beilstein 20 III/IV 1499, 20/4 V 100.] |
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