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ChemicalBook--->CAS DataBase List--->547-25-1

547-25-1

547-25-1 Structure

547-25-1 Structure
IdentificationMore
[Name]

D-(+)-TURANOSE
[CAS]

547-25-1
[Synonyms]

3-[ALPHA-D-GLUCOSIDO]-D-FRUCTOSE
3-O-A-D-GLUCOPYRANOSYL-D-FRUCTOSE
3-O-ALPHA-D-GLUCOPYRANOSYL-D-FRUCTOSE
D-(+)-TURANOSE
D-TURANOSE
TURANOSE
3-o-alpha-d-glucopyranosyl-d-fructos
3-O-α-D-Glucopyranosyl-D-fructose
D-(+)-TURANOSE 98%
D-Turanose,98%
D-Fructose, 3-O-.alpha.-D-glucopyranosyl-
3-o-à-d-glucopyranosyl-d-fructose
D-TURANOSETURANOSE
3-O-α-D-Glucopyranosyl-α-D-fructopyranose
[EINECS(EC#)]

208-918-5
[Molecular Formula]

C12H22O11
[MDL Number]

MFCD00006606
[Molecular Weight]

342.3
[MOL File]

547-25-1.mol
Chemical PropertiesBack Directory
[Appearance]

White Powder
[Melting point ]

170 °C (dec.)(lit.)
[alpha ]

D20 +27.3° +75.8° (c = 4 in water)
[Boiling point ]

397.76°C (rough estimate)
[density ]

1.4149 (rough estimate)
[refractive index ]

75.5 ° (C=4, H2O)
[storage temp. ]

-20°C Freezer
[solubility ]

H2O: 0.1 g/mL, clear, colorless
[form ]

Solid
[pka]

12.67±0.10(Predicted)
[color ]

White
[Water Solubility ]

Soluble in water and methanol.
[Merck ]

14,9821
[BRN ]

93771
[CAS DataBase Reference]

547-25-1(CAS DataBase Reference)
[EPA Substance Registry System]

D-Fructose, 3-O-.alpha.-D-glucopyranosyl- (547-25-1)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[F ]

3-10
[TSCA ]

Yes
[HS Code ]

29400000
Hazard InformationBack Directory
[Chemical Properties]

White Powder
[Uses]

D-Turanose is used as a carbon source by bacteria, fungi, and other organisms. It is involved in intracellular sugar signaling in plant cells.
[Definition]

ChEBI: A glycosylfructose isolated from Daphnia magna.
[Purification Methods]

Crystallise D(+)-turanose from H2O by addition of EtOH (its solubility is 5.3% in 95% EtOH). Form m 157o is obtained by crystallisation from hot MeOH, and mutarotates from +27.3o to [] 20D +88o (c 4, H2O). The phenylosazone crystallises from 15 parts of 95% EtOH with m 200-205o, [] D 24.5o mutarotating to +33o[24hours, c 0.82, pyridine/EtOH (4:6)]. [Pascu Methods in Carbohydrate Chemistry I 353 1962, Academic Press, Beilstein 17/7 V 213.] In D2O at 36o 1H NMR showed the following ratios: -pyranose (<4), -pyranose (39), -furanose (20) and -furanose (41)[Angyal Adv Carbohydr Chem 42 15 1984].
Spectrum DetailBack Directory
[Spectrum Detail]

D-(+)-TURANOSE(547-25-1)IR1
D-(+)-TURANOSE(547-25-1)IR2
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

D-Turanose, 98%(547-25-1)
[Sigma Aldrich]

547-25-1(sigmaaldrich)
[TCI AMERICA]

D-(+)-Turanose(547-25-1)
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