Identification | Back Directory | [Name]
DIBENZYLPHOSPHORYL CHLORIDE | [CAS]
538-37-4 | [Synonyms]
DBPCl 95%,inbenzene10%w/v Dibenzyl chlorophosphate Benzyl phosphorochloridate Dibenzyl chlorophosphonate Dibenzyl=chlorophosphonate DIBENZYLPHOSPHORYL CHLORIDE dibenzyl phosphorochloridate dibenzylphosphinoyl chloride CHLOROPHOSPHORIC ACID DIBENZYL ESTER Bis(phenylmethyl) phosphorochloridate Phosphorochloridic acid dibenzyl ester Dibenzylphosphoryl chloride, in benzene Phosphorochloridic acid bis(phenylmethyl) ester Dibenzylphosphoryl Chloride, [95%], in benzene - 10% w/v | [Molecular Formula]
C14H14ClO3P | [MDL Number]
MFCD01074633 | [MOL File]
538-37-4.mol | [Molecular Weight]
296.69 |
Chemical Properties | Back Directory | [Boiling point ]
428.2±34.0 °C(Predicted) | [density ]
1.283 | [storage temp. ]
Hygroscopic, -20°C Freezer, Under Inert Atmosphere | [solubility ]
Benzene (Soluble), Chloroform (Sparingly) | [form ]
Colourless to Yellow Solution | [Stability:]
Store in freezer at -20°C |
Hazard Information | Back Directory | [Chemical Properties]
[95%] in Benzene - 10% w/v | [Uses]
In solutions with inert solvents such as chloroform, carbon tetrachloride, benzene and ether for the phosphorylation of nucleosides and amino acids. | [Uses]
Please note that this product is shipped in a cooler | [Preparation]
Oxidative halogenation of dibenzyl phosphite using Cl2 or N-chlorosuccinimide
yields dibenzyl phosphorochloridate (BPC). The reaction of dibenzyl hydrogen phosphate with PCl5 is also
used. The latter procedure is employed for the preparation of p-substituted benzyl derivatives such as p-nitrobenzyl and p-chlorobenzyl. These substituted benzyl phosphates are crystalline and more stable than
BPC but have reactivities similar to the parent chloridate. | [storage]
Dibenzyl phosphorochloridate may be stored in the cold but preferably
prepared just prior to use. Distillation of the chloridate may cause violent decomposition. |
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