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ChemicalBook--->CAS DataBase List--->5350-57-2

5350-57-2

5350-57-2 Structure

5350-57-2 Structure
IdentificationMore
[Name]

Benzophenone hydrazone
[CAS]

5350-57-2
[Synonyms]

BENZOPHENONE HYDRAZONE
BENZOPHENONE HYDROZONE
diphenyldiazomethane precursor
DIPHENYLMETHANONE HYDRAZONE
HYDRAZINE OF BENZOPHENONE
TIMTEC-BB SBB007642
Benzophenoneimine N-amino-
diphenylketohydrazone
diphenylketonehydrazone
diphenyl-methanonhydrazone
Benzophenone hydrazone, 98+%
Methanone, diphenyl-, hydrazone
Di(phenyl)methylidenehydrazine
(Diphenylmethylene)hydrazine
(α-Phenylbenzylidene)hydrazine
1-(Diphenylmethylene)hydrazine
1-Benzhydrylidenehydrazine
α-Phenylbenzylidenehydrazine
[EINECS(EC#)]

226-321-8
[Molecular Formula]

C13H12N2
[MDL Number]

MFCD00007624
[Molecular Weight]

196.25
[MOL File]

5350-57-2.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

95-98 °C (lit.)
[Boiling point ]

225-230 °C/55 mmHg (lit.)
[density ]

1.1
[refractive index ]

1.5014 (estimate)
[Fp ]

146°C
[storage temp. ]

0-6°C
[solubility ]

Soluble in ether, benzene, chloroform and other organic solvents.
[form ]

Crystalline Needles or Crystalline Powder
[pka]

1.44±0.70(Predicted)
[color ]

White to yellow
[BRN ]

1910177
[InChIKey]

QYCSNMDOZNUZIT-UHFFFAOYSA-N
[CAS DataBase Reference]

5350-57-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Methanone, diphenyl-, hydrazone(5350-57-2)
[EPA Substance Registry System]

5350-57-2(EPA Substance)
Questions And AnswerBack Directory
[Synthesis]

Benzophenone hydrazone was synthesised by Benzophenone and hydrazine hydrate stirred in ionic liquid for 0.5-6h at 0~140℃.
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[RTECS ]

PC4954487
[TSCA ]

Yes
[HS Code ]

29280090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sulfuric acid-->Hydrazinium hydroxide solution-->Hydrazine hydrate-->HYDRAZINE-->Benzophenone
[Preparation Products]

Pyridaben-->Acetaminophen-->1,1-Dimethylhydrazine-->Basic Yellow 24-->3-METHYL-2-BENZOTHIAZOLINONE HYDRAZONE HYDROCHLORIDE-->Diphenyldiazomethane-->Pyraclofos-->DIPHENYLKETENE-->2,2-Diphenylacetic acid-->2-Diazopropane-->DIPHENYLDIAZOMETHANE-->BENZOPHENONE AZINE-->Butanoic acid, 4-chloro-, 2-(diphenylMethylene)hydrazide-->BENZOPHENONE PHENYLHYDRAZONE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Benzophenone hydrazone(5350-57-2).msds
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powde
[Uses]

An important compound in organic photochemistry and perfumery as well as in organic synthesis. Used in the antibiotics synthesis of 6-APA and 7-ACA of the carboxyl protecting groups and other organic compounds. Used as organic pigment and medical intermediate. It is used as a photoinitiator of UV-curing applications in inks, adhesive, coatings and optical fiber.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 72, p. 2890, 1950 DOI: 10.1021/ja01163a024
Organic Syntheses, Coll. Vol. 3, p. 351, 1955
Spectrum DetailBack Directory
[Spectrum Detail]

Benzophenone hydrazone(5350-57-2)MS
Benzophenone hydrazone(5350-57-2)1HNMR
Benzophenone hydrazone(5350-57-2)13CNMR
Benzophenone hydrazone(5350-57-2)IR1
Benzophenone hydrazone(5350-57-2)IR2
Benzophenone hydrazone(5350-57-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Benzophenone hydrazone, 98+%(5350-57-2)
[Alfa Aesar]

Benzophenone hydrazone, 98+%(5350-57-2)
[Sigma Aldrich]

5350-57-2(sigmaaldrich)
[TCI AMERICA]

Benzophenone Hydrazone,>96.0%(T)(5350-57-2)
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