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ChemicalBook--->CAS DataBase List--->532-31-0

532-31-0

532-31-0 Structure

532-31-0 Structure
IdentificationMore
[Name]

SILVER BENZOATE
[CAS]

532-31-0
[Synonyms]

BENZOIC ACID SILVER SALT
SILVER BENZOATE
SILVER(I) BENZOATE
Benzoic acid, silver(1+) salt
benzoicacid,silver(1++)salt
Silver benzoate (AgOBz)
Silver(1+) benzoate
Silver benzoate hydrate
BENZOIC ACID SILVER
Silver(I) benzoate, 98+%
AgOBz
Benzoic acid silver(I) salt
[EINECS(EC#)]

208-533-2
[Molecular Formula]

C7H5AgO2
[MDL Number]

MFCD00013030
[Molecular Weight]

228.98
[MOL File]

532-31-0.mol
Chemical PropertiesBack Directory
[Appearance]

Off-White Crystalline Powder
[Melting point ]

>188°C (dec.)
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[solubility ]

cold water: soluble385 part(lit.)
[form ]

Powder
[color ]

White to cream or gray
[Water Solubility ]

Insoluble in water.
[Sensitive ]

Light Sensitive
[InChIKey]

CLDWGXZGFUNWKB-UHFFFAOYSA-M
[CAS DataBase Reference]

532-31-0(CAS DataBase Reference)
[EPA Substance Registry System]

Benzoic acid, silver(1+) salt (532-31-0)
Safety DataBack Directory
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[TSCA ]

Yes
[HS Code ]

28432900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Silver nitrate-->Sodium benzoate
Hazard InformationBack Directory
[Chemical Properties]

Off-White Crystalline Powder
[Application]

Silver benzoate was used in the synthesis of triphenyltinbenzoate. It is an efficient catalytic system for the reaction of carbon dioxide with various ketones.
[Uses]

Silver benzoate was used in the synthesis of triphenyltinbenzoate.
[Uses]

Silver benzoate is an aromatic salt that is used as a catalyst to prepare β-amino acids (such as N-Acetyl-β-alanine [A168070]) from α-amino acids (such as D-Alanine [A480995]). Silver benzoate is also used as a catalyst in Wolff rearrangement reactions.
[Reactions]

Silver benzoate reacts with bromine in CCl4 refluxing to form C6H5Br This reaction is called Hunsdiecker reaction.
[General Description]

Silver benzoate along with 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD) is an efficient catalytic system for the reaction of carbon dioxide with various ketones.
[Synthesis]

Silver benzoate can be obtained by reacting silver nitrate and sodium benzoate:
AgNO3 + PhCOONa → PhCOOAg↓ + NaNO3
Reaction: Mix an equimolar amount of silver nitrate solution with sodium benzoate solution to precipitate silver benzoate. Washed with water and dried in a vacuum desiccator.
Spectrum DetailBack Directory
[Spectrum Detail]

Silver benzoate(532-31-0)1HNMR
Silver benzoate(532-31-0)13CNMR
Silver benzoate(532-31-0)IR1
Silver benzoate(532-31-0)IR2
Silver benzoate(532-31-0)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Silver benzoate, 99%(532-31-0)
[Alfa Aesar]

Silver benzoate hydrate(532-31-0)
[Sigma Aldrich]

532-31-0(sigmaaldrich)
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